Chemical Kinetics Class 12 Important Extra Questions Chemistry Chapter 4

Here we are providing Class 12 Chemistry Important Extra Questions and Answers Chapter 4 Chemical Kinetics. Class 12 Chemistry Important Questions are the best resource for students which helps in Class 12 board exams.

Class 12 Chemistry Chapter 4 Important Extra Questions Chemical Kinetics

Chemical Kinetics Important Extra Questions Very Short Answer Type

Question 1.
Define rate of a reaction. (CBSE Delhi 2010)
Answer:
The rate of a reaction is the change of concentration in any one of the reactants or products per unit time.

Question 2.
Define order of a reaction. (CBSE Delhi 2010, CBSE 2011)
Answer:
The sum of the powers of the concentration terms of the reactants in the rate law expression is called the order of that chemical reaction. For example, if rate law expression is
rate = K[A]p[B]q[C]r
Order of reaction = p + q + r

Question 3.
For a chemical reaction R → P, the variation in the concentration (R) vs. time (t) plot is given as
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 1
(i) Predict the order of the reaction.
(ii) What is the slope of the curve? (CBSE 2014)
Answer:
(i) Zero order reaction
(ii) Slope = – k

Question 4.
Define ‘activation energy’ of a reaction. (CBSE Delhi 2011)
Answer:
Activation energy is the minimum energy that the reactants must possess for the conversion into the products during their collisions.
It is equal to difference between the threshold energy needed for the reaction and the average kinetic energy of the molecules.

Question 5.
Identify the order of a reaction if the units of its rate constant are:
(i) L-1 mol s-1
(ii) L mol-1 s-1 (CBSE All India 2011)
Answer:
(i) Zero order
(ii) Second order

Question 6.
For a reaction: A + B → P, the rate law is given by, r = k [A]1/2 [B]2 .
What is the order of reaction? (CBSE All India 2013)
Answer:
Order = \(\frac{1}{2}\) + 2 = 2\(\frac{1}{2}\) or 2.5.

Question 7.
In the Arrhenius equation, what does the factor e-E0/RT correspond to?
(CBSE Sample Paper 2017-18)
Answer:
e-E0/RT corresponds to the fraction of molecules having kinetic energy greater than Ea.

Chemical Kinetics Important Extra Questions Short Answer Type

Question 1.
For a reaction,
C2H4(g) + H2(g) → C2H6(g),
rate = 5.5 × 10-14 [C2H4].
(a) Write the unit of rate constant.
(b) Calculate its half-life (t1/2). (CBSE 2019)
Answer:
(a) Hydrogenation of ethene is an example of first order reaction so the unit of rate constant is s-1 or time-1.

(b) t1/2 = \(\frac{0.693}{k}=\frac{0.693}{5.5 \times 10^{-14}}\)
= 1.26 × 1013s
(or any other unit of time)

Question 2.
For a reaction
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 2
The proposed mechanism is as given below:
(1) H2O2 + I → H2O + IO (slow)
(2) H2O2 + IO → H2O + I + O2 (fast)
(i) Write rate law for the reaction.
(ii) Write the overall order of reaction.
(iii) Out of steps (1) and (2), which one is rate-determining step? (CBSE Delhi 2019)
Answer:
(i) Rate = k[H2O2][I]
(ii) 2
(iii) Step 1 is rate determining.

Question 3.
A reaction is of first order in reactant A and of second order in reactant B. How is the rate of this reaction affected when
(i) the concentration of B alone is increased to three times?
(ii) the concentrations of A as well as B are doubled? (CBSE Delhi 2010)
Answer:
The rate law may be expressed as:
Rate = k[A] [B]2
(i) Rate becomes nine times
(ii) Rate becomes eight times.

Question 4.
What do you understand by the rate law and rate constant of a reaction? Identify the order of reaction if the units of its rate constant are:
(i) L-1 mol s-1
(ii) L mol-1 s-1 (CBSE 2011)
Answer:
Rate law is the representation of rate of reaction in terms of concentration of the reactants.
Rate constant is the rate of reaction when the concentration of reactants is unity. Order of reaction from rate constants
(i) Zero order
(ii) Second order

Question 5.
A reaction is of second order with respect to a reactant. How is the rate of reaction affected if the concentration of the reactant is reduced to half? What is the unit of rate constant for such a reaction? (CBSE 2011)
Answer:
For a second order reaction,
rate = K[A]2
If the concentration of A is reduced to half, rate will become 1 /4 of the original value.
Units of k.
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 3

Question 6.
Distinguish between rate expression and rate constant of a reaction. (CBSE 2011)
Answer:
Rate expression is a mathematical expression which denotes the rate of a reaction in terms of molar concentration of reactants.

Rate constant is the rate of the reaction when the concentration of reactants is unity. It is proportionality constant in the rate law and is independent of initial concentrations of the reactants.

Question 7.
What do you understand by the ‘order of reaction’? Identify the reaction order from each of the following units of reaction rate constant:
(i) L-1 mol s-1
(ii) L mol-1 s-1 (CBSE Delhi 2012)
Answer:
The sum of the powers of the concentrations of reactants in the rate law expression is called order of a reaction. For example, if rate law expression for a reaction is:
rate = K[A]a[B]a[C]c
then order = a + b + c
(i) Zero order
(ii) Second order

Question 8.
(i) For a reaction A + B → P, the rate law is given by,
r = k[A]1/2 [B]2
What is the order of this reaction?
(ii) A first order reaction is found to have a rate constant k = 5.5 × 10-14 s-1. Find the half life of the reaction. (CBSE 2013)
Answer:
(i) Order of reaction 1
= \(\frac{1}{2}\) + 2 = 2.5

(ii) t1/2 = \(\frac{0.693}{k}=\frac{0.693}{5.5 \times 10^{-14}}\)
= 1.26 × 1013s

Question 9.
Write two differences between ‘order of reaction’ and ‘molecularity of reaction. (CBSE Delhi 2014)
Answer:

OrderMolecularity
1. Order is the sum of the powers of the concentration terms in the rate law expression.1. Molecularity is the number of reacting species undergoing simultaneous collisions in the elementary or simple reaction.
2. Order of a reaction is determined experimentally and need not be a whole number, i.e. it can have fractional values also.2. Molecularity is a theoretical concept and has whole number values only, i.e. 1, 2, 3, etc.

Question 10.
The rate constant for a reaction of zero order in A is 0.0030 mol L-1s-1. How long will it take for the initial concentration of A to fall from 0.10 M to 0.075 M? (CBSE 2010)
Answer:
For a zero order reaction,
k = 0.0030 mol L-1s-1
[A]0 = 0.10 M, [A] = 0.075M
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 4
Answer:

Question 11.
The rate of a reaction depends upon the temperature and is quantitatively expressed as k = \(A e^{-E_{a} / R T}\)
(i) If a graph Is plotted between log k and 1/T, write the expression for the slope of the reaction.
(ii) If at under different conditions, Ea1 and Ea2 are the activation energy of two reactions. If Ea1 = 40 J / mol and Ea2 = 80 J / mol which of the two has a larger value of the rate constant? (CBSE Sample Paper 2019)
Answer:
(ii) Arrhenius proposed a quantitative relationship between rate constant
and temperature as k = \(A e^{-E_{a} / R T}\) Taking logarithm,
In k = In A – \(\frac{E_{a}}{R} \times \frac{1}{T}\)
Converting to common logarithm (In X = 2.303 log X), we get
2.303 log k = 2.303 log A – \(\frac{\mathrm{E}_{\mathrm{a}}}{\mathrm{RT}}\).
Dividing each side by 2.303, we get
log k = log A – \(\frac{E_{a}}{2.303 R T}\)
So, it is clear that increasing the temperature or decreasing the activation energy will result in an increase in the rate of reaction.

(i) Slope = – \(\frac{\mathrm{E}_{\mathrm{a}}}{2.303 \mathrm{R}}\)
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 5
Plot of log k versus 1/T to calculate activation energy.

(ii) k1 > k2

Question 12.
The rate constant for a first order reaction is 60 s-1. How much time will it take to reduce the concentration of the reactant to 1/10th of its initial value?
Answer:
For a first order reaction,
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 6

Question 13.
Rate constant ‘k’ of a reaction varies with temperature ‘T’ according to the equation:
log k = log A – \(\frac{E_{a}}{2.303 R}\left(\frac{1}{T}\right)\)
where Ea is the activation energy. When a graph is plotted for log k vs. \(\frac{1}{T}\), a straight line with a slope of – 4250 K is obtained. Calculate ‘Ea’ for the reaction (R = 8.314 JK-1mol-1). (CBSE Delhi 2013)
Answer:
Slope = –\(\frac{E_{a}}{2.303 R}\) = -4250K
Ea = – 2.303 × R × Slope
= – 2.303 × 8.314 JK-1 mol-1 × (-4250 K)
= 81375.3 J mol-1 or 81.375 kJ mol-1.

Question 14.
For the reaction
C12H22O11 + H2O → C6H12O6 + C6H12O6
write:
(i) Rate of reaction expression,
(ii) Rate law equation,
(iii) Molecularity,
(iv) Order of reaction (CBSE Sample paper 2011)
Answer:
(i)
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 7
(ii) Rate law equation:
Rate = k[C12H22O11]
(iii) Molecularity = 2
(iv) Order = 1

Question 15.
Consider the decomposition of hydrogen peroxide in alkaline medium which is catalysed by iodide ions.
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 8
This reaction takes place in two steps as given below:
Step -1 H2O2 + I → H2O + IO (slow)
Step – II H2O2 + IO → H2O + I (fast)
(i) Write the rate law expression and determine the order of reaction w.r.t. H2O2.
(ii) What is the molecularity of each individual step? (C8SE Sample paper 2011)
Answer:
(i) Rate = k[H2O2] [I]
Order w.r.t. H2O2 = 1
(ii) Molecularity: Step I = 2, Step II = 2

Question 16.
For a reaction: A + B → P, the rate law is given as: Rate = k[A][B]2
(i) How is the rate of reaction affected when the concentration of B is doubled?
(ii) What is the order of reaction if A is present in large excess? (CBSE All India 2015)
Answer:
(i) Rate becomes four times
(ii) Order = 2

Question 17.
What is the effect of adding a catalyst on
(i) Activation energy (Ea) and
(ii) Gibbs free energy (∆G) of a reaction? (CBSE All India 2017)
Answer:
(i) Activation energy decreases
(ii) No effect on ∆G because Gibbs free energies of products and reactants remain the same in the presence of catalyst.

Question 18.
For a reaction:
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 9
Rate = k
(i) Write the order and molecularity of this reaction.
(ii) Write the unit of k. (CBSE Sample paper 2018)
Answer:
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 10
Rate = k
(i) Order of reaction: Zero order Molecularity = 2 (bi molecular)
(ii) Unit of k = mol L-1 s-1 or atm s-1

Question 19.
Explain the following terms: (CBSE 2014)
(i) Rate constant (k).
(ii) Half life period of a reaction (t1/2).
Answer:
(i) Rate constant is the rate of the reaction
when the molar concentration of each of the reactants is unity. For example, for a reaction,
A + B → AB
Rate of reaction is
Rate = k[A][B]
where k is the rate constant. When
[A] = 1 and [B] = 1
Rate of reaction = k × 1 × 1 = k
It is also catted specific reaction rate and is independent of the initial concentration of the reactants.

(ii) Half life period of a reaction is the time during which the concentration of a reactant Is reduced to half of its initial concentration. In other words, it is the time during which half of the reaction Is completed. It is denoted as t1/2.

Chemical Kinetics Important Extra Questions Long Answer Type

Question 1.
Show that time required for 99% completion is twice the time required for the completion of 90% reaction. (CBSE Delhi 2013)
Answer:
For the first order reaction,
t = \(\frac{2.303}{k} \log \frac{[\mathrm{A}]_{0}}{[\mathrm{~A}]}\)
Let initial concentration, [A0] = a
For 99% completion of reaction, [A]
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 11
For 90% completion of reaction,
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 12
Dividing equation (i) by (ii)
\(\frac{t_{(99 \%)}}{t_{(90 \%)}}\) = 2
or t(99%) = 2 × t(90%)

Question 2.
The decomposition of NH3 on platinum surface is zero order reaction. If rate constant (k) Is 4 × 10-3 M s-1, how long will it take to reduce the initial concentration of NH3 from 0.1 M to 0.064 M? (CBSE Delhi 2019)
Answer:
k = 4 × 10-3M s-1, [A]0 = 0.1 M, [A] = 0.064 M
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 13

Question 3.
The thermal decomposition of HCO2H is a first order reaction with a rate constant of 2.4 × 10-3 s-1 at a certain temperature. Calculate how long will it take for three fourth of initial quantity of HCO2H to decompose. (log 4 = 0.6021) (CBSE 2011)
Answer:
We know that
t = \(\frac{2.303}{k} \log \frac{[A]_{0}}{[A]}\)
If initial conc. of A is a, then
[A] = a – \(\frac{3}{4}\)a = \(\frac{1}{4}\)a
k = 2.4 × 10-3 s-1
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 14
= \(\frac{2.303}{2.4 \times 10^{-3}}\) × 0.6021 = 578 s

Question 4.
For the reaction:
2N0(g) + Cl2(g) → 2NOCl(g)
the following data were collected. All the measurements were taken at 263 K:

Experiment No.Intial [NO] (M)Intial [Cl2] (M)Intial rate of Cl2 (M/min)
10.150.150.60
20.150.301.20
30.300.152.40
40.250.25?

(i) Write the expression for rate law.
(ii) Calculate the value of rate constant and specify its units.
(iii) What is the initial rate of disappearance of Cl2 In exp. 4? (CBSE 2012)
Answer:
(i) Rate = k[NO]2[Cl2]
(ii) According to experiment 1,
[NO] = 0.15 M; [Cl2] = 0.15 M
Rate = 0.6 M/min.
Rate = k[NO]2[Cl2]
0.6 M/min = k(0.15M)2 (0.15 M)
k = 177.8 M-2 min-1
or
= 177.8 mol-2 L2 min-1
Therefore, units of k are M-2 min-1 or mol-2 L2 min-1.

(iii) In experiment 4, [NO] = 0.25 M; [Cl2] = 0.25 M and k = 177.8 M-2 min-1
Rate = k[NO]2 [Cl2]
= 177.8 M-2 min-1 × (0.25 M)2 × 0.25 M
= 2.78 M min-1.

Question 5.
The following data were obtained during the first order thermal decomposition of
SO2Cl2 at a constant volume:
SO2Cl2(g) → SO2(g) + Cl2(g)

ExperimentTime/s-1Total Pressure/atm
100.4
11000.7

Calculate the rate constant.
(Given: log 4 = 0.6021, log 2 = 0.3010) (CBSE Delhi 2014)
Answer:
SO2Cl2 → SO2 + Cl2
At t = 0 s     0.4 atm            0            0
At t = 100 s (0.4 – x) atm   x atm   x atm
Pt = 0.4 – x + x + x = 0.4 + x
0.7 = 0.4 + x      or    x = 0.3
k = \(\frac{2.303}{t}\) log \(\frac{p_{0}}{2 p_{0}-p_{t}}\)
t = 100 s
∴ k = \(\frac{2.303}{100}\) log \(\frac{0.4}{2 \times 0.4-0.7}\)
= \(\frac{2.303}{100}\) log \(\frac{0.4}{0.1}\)
∴ k = \(\frac{2.303}{100}\) × 0.6021 = 1.38 × 10-2 s-1

Question 6.
The rate constant for the first order decomposition of H2O2 is given by the following equation:
log k = 14.2 – \(\frac{1.0 \times 10^{4} \mathrm{~K}}{\mathrm{~T}}\)
Calculate Ea for this reaction and rate constant k if Its half-life period be 200 minutes. (Given: R = 8.314 JK-1 mol-1) (CBSE Delhi 2016)
Answer:
According to Arrhenius equation,
log k = log A – \(\frac{E_{a}}{2.303 \mathrm{RT}}\) …….. (i)
The given equation is
log k = 14.2 – \(\frac{1.0 \times 10^{4} \mathrm{~K}}{\mathrm{~T}}\) ………. (ii)
Comparing eq. (1) and (ii)
\(\frac{E_{a}}{2.303 \mathrm{RT}}\) = 1.0 × 104
∴ Ea = 1.0 × 104 × 2.303 × 8.314
= 19.147 × 104 J mol-1
Now t1/2 = \(\frac{0.693}{k}\)
or k = \(\frac{0.693}{t_{1 / 2}}\)
= \(\frac{0.693}{200 \mathrm{~min}}\) = 3.465 × 10-3 min -1

Question 7.
The rate of a reaction increases four times when the temperature changes from 300 K to 320 K. Calculate the activation energy of the reaction assuming that it does not change with temperature (R = 8.3 14 JK-1 mol-1). (CBSE All India 2010)
Answer:
T1 = 300 K, T2 = 320 K, R = 8.314 JK-1 mol-1
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 15
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 16

Question 8.
Sucrose decomposes in acid solution into glucose and fructose according to the first order rate law, with t1/2 = 3.00 hours. What fraction of sample of sucrose remains after 8 hours? (CBSE Sample Paper 2011)
Answer:
k = \(\frac{0.693}{t_{1 / 2}}\) = \(\frac{0.693}{3.0}\) = 0.231 hr-1
Let initial cone, of sucrose = 1 M
Cone, after 8 hr. = (1 – x) where x is the amount of sucrose decomposed
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 17
Conc. of sucrose left after 8 hr = 1 – 0.842
= 0.158 M

Question 9.
The rate of a reaction becomes four times when the temperature changes from 293 K to 313 K. Calculate the energy of activation (Ea) of the reaction assuming that it does not change with temperature.
[R = 8.314 J K-1 mol-1, log 4 = 0.6021] (CBSE All India 2013)
Answer:
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 18
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 19

Question 10.
The following data were obtained during the first order thermal decomposition of SO2Cl2 at constant volume.
SO2Cl2(g) → SO2(g) + Cl2(g)

ExperimentTimes/sTotal Pressure/atm
100.5
21000.6

Calculate the rate of reaction when total pressure is 0.65 atm. (CBSE Sample Paper 2011)
Answer:
For the decomposition of SO2Cl2
SO2Cl2(g) → SO2(g) + Cl2(g)
At t = 0          p0 atm              0        0
At time, t      (p0 – x) atm       x        x
pt = p0 – x + x + x = p0 + x
or x = pt – p0
Now at time t, p(SOCl2) = p0 – x
= P0 – (Pt – P0) = 2 p0 – pt
∴ k = \(\frac{2.303}{t}\) log \(\frac{p_{0}}{2 p_{0}-p_{t}}\)
when t = 100 s
k = \(\frac{2.303}{100}\) log \(\frac{0.5}{2 \times 0.5-0.6}\)
= \(\frac{2.303}{100}\) log 1.25 = 2.2316 × 10-3 s-1
When pt = 0.65 atm, i.e. p0 + p = 0.65 atm
p = 0.65 – p0 = 0.65 – 0.50 = 0.15 atm
∴ Pressure of SO2Cl2 at time t = 0.50 – 0.15
= 0.35 atm
Rate = 2.2316 ×10-3 × 0.35
= 7.8 × 10-5 atm s-1

Question 11.
A first order reaction takes 20 minutes for 25% decomposition. Calculate the time when 75% of the reaction will be completed. {CBSE All India 2017)
Answer:
For the first order reaction:
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 20

Question 12.
A first order reaction takes 23.1 minutes for 50% completion. Calculate the time required for 75% completion of this reaction. (log 2 = 0.301, log3 0.4771, log4 = 0.6021) (CBSE All India 2015)
Answer:
For the first order reaction:
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 21

Question 13.
The decomposition of phosphine, PH3, proceeds according to the following equation:
4PH3(g) → P4(g) + 6H2(g)
It is found that the reaction follows the following rate equation:
Rate = k[PH3].
The half-life of PH3 is 37.9 sat 120 C.
(i) How much time is required for 3/4th of PH3 to decompose?
(ii) What fraction of the original sample of PH3 remains behind after 1 minute? (C8SE All India 2010)
Answer:
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 22

Question 14.
Sucrose decomposes in acid solution into glucose and fructose according to the first order rate law with t1/2 = 3 hrs. Calculate the fraction of sucrose which remains after 8 hrs. (CBSE Sample Paper 2011)
Answer:
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 23

Question 15.
Starting from 10 g of a radioactive element, 0.25 g was left after 5 years. Calculate
(i) Rate constant for the decay of the radioactive element.
Answer:
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 24

(ii) The amount left after one year.
Answer:
Amount left after 1 year
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 25

(iii) The time required for half of the element to decay.
Answer:
Time for decay of half of the element
t1/2 = \(\frac{0.693}{k}=\frac{0.693}{0.7379}\) = 0.9392 year

(iv) Average life of the element. (CBSE All India 2011)
Answer:
t = \(\frac{1}{k}=\frac{1}{0.7379}\) = 1.3552 year

Question 16.
In general, It is observed that the rate of a chemical reaction becomes double with every 1o°. rise in temperature. If this generalization holds for a reaction In the temperature range 298 to 308 K, what would be the value of activation energy for this reaction? (R = 8.3 14 JK-1 mol-1) (CBSE Delhi 2000)
Answer:
Arrhenius equation is:
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 26

Question 17.
A first order reaction is 50% completed in 40 minutes at 300 K and in 20 minutes at 320 K. Calculate the activation energy of the reaction.
(Given: log 2 = 0.3010, log 4 = 0.6021, R = 8.3 14 Jk-1 mol-1) (CBSE All India 2018)
Answer:
Let us first calculate k1 and k1 at temperatures 300 K and 320 K. We know that
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 27
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 28

Question 18.
The rate constant of a first order reaction increases from 2 × 10-2 to 6 × 10-2 when the temperature changes from 300 K to 320 K. Calculate the energy of activation. (Given: log 2 = 0.3010, log 3 = 0.4771, log 4 = 0.6021) (CBSE 2019 C)
Answer:
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 29

Question 19.
For the reaction A + B → products, the following initial rates were obtained at various given initial concentrations:

[A] mol / L[B] mol / LIntial rate M/S
1. 0.10.10.05
2. 0.20.10.10
3. 0.10.20.05

Determine the half-life period.
OR
A first order reaction is 50% complete In 50 minutes at 300 K and the same reaction is again 50% complete In 25 minutes at 350 K. Calculate activation energy of the reaction. (CBSE Sample Paper 2019)
Answer:
Rate = k [A]x [B]y
0.05 = k [0.1]x [0.1]y …… (i)
0.10 = k [0.2]x [0.1]y ……. (ii)
0.05 = k [0.1]x [0.2]y …….. (iii)
Dividing equation (ii) by (i)
\(\frac{0.10}{0.05}\) = (2)x
x = 1
Dividing equation (iii) by (i)
\(\frac{0.05}{0.05}\) = (2)y
y = 0
Rate = k [A]1 [B]0
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 30

Question 20.
For a certain chemical reaction variation in concentration [A] vs. time (s) plot as shown in given figure:
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 31
(i) Predict the order of the given reaction?
(ii) What does the slope of the line and intercept indicate?
(iii) What is the unit of rate constant k? (CBSE Sample paper 2018-19)
Answer:
(i) Zero order reaction
(ii) Slope represents k; Intercept represents [R]0
(iii) mol L-1 s-1

Question 21.
The following data were obtained during the first order thermal decomposition of N2O5(g) at a constant volume:
2N2O5(g) → 2N2O4(g) + O2(g)

S.NOTime (sec.)Total pressure (atm)
1.00.5
2.1000.512

Calculate the rate constant.
OR
Two reactions of the same order have equal pre-exponential factors but their activation energies differ by 24.9 kJ mol-1. Calculate the ratio between the rate constants of these reactions at 27°C. (Gas constant R 8.314 J K-1 mol-1) (CBSE 2018)
Answer:
2N2O5(g) → 2N2O4(g) + O2(g)
At t = 0       0.5 atm       0 atm      0 atm
At time t   0.5-2x atm   2x atm    x atm
Pt = PN2O5 + PN2O5 + PO2
= (0.5 – 2x) + 2x + x = 0.5 + x
x = pt – 0.5
PN2O5 = 0.5 – 2x
= 0.5 – 2(pt – 0.5)
= 1.5 – 2pt
At t = 100s; pt = 0.512 atm
PN2O5 = 1.5 – 2 × 0.512 = 0.47 atm
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 32
OR
The Arrhenius equation: k = Ae-Ea/RT
Taking log on both sides:
log k = log A – \(\frac{E_{a}}{2.303 R T}\)
For reaction (i) log k1 = log A – \(\frac{E_{o}(1)}{2.303 R T}\)
For reaction (ii) log k2 = logA – \(\frac{E_{o}(2)}{2.303 R T}\)
Subtracting (i) from (ii)
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 33

Question 22.
(a) Define order of reaction. How does order of a reaction differ from molecularity for a complex reaction?
Answer:
(a) Order of reaction is the sum of the power to which the concentration terms are raised in the rate law equation. Order of a reaction is applicable for the complex reaction but molecularity has no meaning for the complex reaction. 0.693

(b) A first order reaction is 50% complete in 25 minutes. Calculate the time for 80% completion of the reaction.
Answer:
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 34

(a) The decomposition of a hydrocarbon has value of rate constant as 2.5 × 104 s-1 at 27 °C. At what temperature would rate constant be 7.5 × 104 s-1 if energy of activation is 19.147 × 103 J mol-1?
Answer:
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 35
0.1431 T2 = T2 – 300
0.1431 T2 – T2 = 300
0.8569T2 = – 300
T2 = \(\frac{300}{0.8569}\) = 350 k

(b) Write a condition under which a bimolecular reaction is kinetically first order. Give an example of such a reaction.
(Given: log 2 = 0.3010, log 3 = 0.4771, log 5 = 0.6990) (CBSE AI 2019)
Answer:
A bimolecular reaction is kinetically of first order when one of the reactant is in excess. For example, hydrolysis of methyl acetate.
CH3COOCH3 + H2O (excess) → CH3COOH + CH3OH

Question 23.
Nitrogen pentoxide decomposes according to equation:
2N2O5 (g) →4NO2(g) + O2(g)
The first order reaction was allowed to proceed at 40° C and the data below were collected:

[N2O5] (M)Time (min)
0.4000.00
0.28920.0
0.20940.0
0.15160.0
0.10980.0

(i) Calculate the rate constant. Include units with your answer.
Answer:
Since it is a first order reaction,
k = \(\frac{2.303}{t}\) log \(\frac{[\mathrm{A}]_{0}}{[\mathrm{~A}]}\)
k can be calculated as:
at t = 20 min
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 36
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 37
The average value of rate constant,
k = 0.01624 min-1 or = 1.624 × 10-2 min-1

(ii) What will be the concentration of N2O5 after 100 minutes?
Answer:
Concentration of [N2O5] at t = 100 min
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 38

(iii) Calculate the initial rate of reaction. (CBSE 2011)
Answer:
Initial rate of reaction,
rate = k[N2O5]
= 0.01624 × 0.40
= 6.496 × 10-3

Question 24.
(i) Explain the following terms:
(a) Rate of a reaction
Answer:
The rate of reaction is the change of concentration in any one of the reactants or products per unit time. For a reaction, A → B rate may be expressed as
= \(\frac{-d[A]}{d t}\) or \(\frac{d[B]}{d t}\)

(b) Activation energy of a reaction
Answer:
Activation energy is the minimum energy which the reacting molecules should acquire so that they react to give the products. It is also defined as the energy required to form the products.

(ii) The decomposition of phosphine, PH3, proceeds according to the following equation:
4PH3(g) → P4 (g) + 6H2(g)
It Is found that the reaction follows the following rate equation:
Rate = k[PH3]
The half life of PH3 is 37.9 s at 120°C.
(a) How much time is required for 3/4th of PH3 to decompose?
Answer:
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 39

(b) What fraction of the original sample of PH3 remains behind after 1 minute? (CBSE 2010)
Answer:
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 40

Question 25.
Explain the following terms:
(a) Order of a reaction
Answer:
The sum of the powers of the concentration of reactants in the rate law expression is called the order of the reaction.
For example, if rate law expression for a reaction is:
Rate = k[A]a[B]b[C]c
then order of reaction is
order = a + b + c

(b) Molecularity of a reaction
Answer:
Molecularity is the number of molecules taking part in a reaction. For example, for the reaction:
aA + bB → Product
Molecularity is a + b

(ii) The rate of a reaction Increases four times when the temperature changes from 300 K to 320 K. Calculate the energy of activation of the reaction, assuming that it does not change with temperature (R = 8.314 JK-1 mol-1). (CBSE 2010)
Answer:
T1 = 300 k, T2 = 320 k,
R = 8.314 Jk-1 mol-1
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 41

Question 26.
(i) A reaction is second order in A and first order in B.
(a) Write the differential rate equation.
(b) How is the rate affected on Increasing the concentration of A three times?
(C) How is the rate affected when the concentrations of both A and B are doubled?
Answer:
(a) Rate = k[A]2[B]
(b) 9 times
(C) 8 times

(ii) A first order reaction takes 40 minutes for 30% decomposition. Calculate t1/2 for this reaction. (Given log 1.428 = 0.1548)
Answer:
Let initial conc. = a
Conc. after 40 min
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 42

OR

(i) For a first order reaction, show that time required for 99% completion is twice the time required for the completion of 90% of reaction.
Answer:
For a first order reaction,
t = \(\frac{2.303}{k}\) log \(\frac{[\mathrm{A}]_{0}}{[\mathrm{~A}]}\)
Let intial concentration, [A]0 = a
For 99% completion of reaction,
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 43
Dividing equation (i) by (ii)
\(\frac{t_{(99 \%)}}{t_{(90 \%)}}\) = 2 or t(99%) = 2 × t(90%)

(ii) Rate constant ‘k’ of a reaction varies with temperature ‘T’ according to the equation:
log k = log A – \(\frac{E_{a}}{2.303 R}\left(\frac{1}{T}\right)\)
where Ea is the activation energy. When a graph is plotted for log k vs. \(\frac{1}{\mathrm{~T}}\), a straight line with a slope
of – 4250 K is obtained. Calculate ‘Ea’ for the reaction (R = 8.3 14 JK-1 mol-1). (CBSE Delhi 2013)
Answer:
Slope = – \(\frac{E_{a}}{2.303 R}\) = – 4250 k
∴ Ea = 2.303 × 8.314 Jk-1 mol-1 × 4250 k
= 81.375 kJ mol-1

Question 27.
(i) What is rate of reaction? Write two factors that affect the rate of reaction.
Answer:
Rate of reaction is defined as the change in concentration of reactants or products per unit time. Factors that affect rate of a reaction
(a) Concentration of reactant
(b) Temperature

(ii) The rate constant of a first order reaction increases from 4 × 10-2 to 8 × 10-2 when the temperature changes from 27 °C to 37°C. Calculate the energy of activation (Ea).
(log 2 = 0.301, log 3 = 0.4771, log 4 = 0.6021)
Answer:
log \(\frac{k_{2}}{k_{1}}=\frac{E_{a}}{2.303 R}\left[\frac{T_{2}-T_{1}}{T_{1} T_{2}}\right]\)
k1 = 4 × 10-2,
k2 = 8 × 10-2,
T1 = 273 + 27 = 300 K
T2 = 273 + 37 = 310 K,
R = 8.314 JK-1 mol-1
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 44
= 53598 J mol-1
= 53.598 KJ mol-1

OR

(i) For a reaction A + B → P, the rate is given by.
Rate = k [A] [B]2
(a) How is the rate of reaction affected if the concentration of B is doubled?
(b) What is the overall order of reaction if A is present in large excess?
Answer:
Rate = K[A][B]2
(a) becomes four times
(b) Second order

(ii) A first order reaction takes 23.1 minutes for 50% completion. Calculate the time required for 75% completion of this reaction.
(log 2 = 0.301, log 3 = 0.4771, log 4 = 0.6021) (CBSE 2015)
Answer:
For a first order reaction,
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 45
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 46
Class 12 Chemistry Important Questions Chapter 4 Chemical Kinetics 47

Moving Charges and Magnetism Class 12 Important Extra Questions Physics Chapter 4

Here we are providing Class 12 Physics Important Extra Questions and Answers Chapter 4 Moving Charges and Magnetism. Important Questions for Class 12 Physics with Answers are the best resource for students which helps in Class 12 board exams.

Class 12 Physics Chapter 4 Important Extra Questions Moving Charges and Magnetism

Moving Charges and Magnetism Important Extra Questions Very Short Answer Type

Question 1.
Under what condition is the force acting on a charge moving through a uniform magnetic field minimum?
Answer:
When the charge moves parallel to the direction of the magnetic field.

Question 2.
What Is the nature of the magnetic field in a moving coil galvanometer?
Answer:
Radial magnetic field.

Question 3.
State two properties of the material of the wire used for suspension of the coil in a moving coil galvanometer.
Answer:

  1. High tensile strength.
  2. SmalL vaLue of torque per unit twist.

Question 4.
Write one condition under which an electric charge does not experience a force in a magnetic field.
Answer:
When it moves parallel to the direction of the magnetic field.

Question 5.
Mention the two characteristic properties of the material suitable for making the core of a transformer. (CBSE AI 2012)
Answer:

  1. Low retentivity
  2. High permeability

Question 6.
Write the expression, in a vector form, for the Lorentz magnetic force due to a charge moving with velocity \(\vec{V}\) in a magnetic field \(\vec{B}\). What is the direction of the magnetic force? (CBSE Delhi 2014)
Answer:
The expresion is \(\vec{F}\) = q(\(\vec{V}\) × \(\vec{B}\)). The force is perpendicular to both the velcoity and the magentic field vector.

Question 7.
Write the condition under which an electron will move undeflected in the presence of crossed electric and magnetic fields. (CBSE Al 2014C)
Answer:
An electron moves perpendicular to both fields.

Question 8.
What can be the cause of the helical motion of a charged particle? (CBSE Al 2016)
Answer:
The charge enters the magnetic field at any angle except 0°, 180°, and 90°.

Question 9.
Write the underlying principle of a moving coil galvanometer. (CBSE Delhi 2016)
Answer:
A current-carrying loop placed in a magnetic field experiences a torque.

Question 10.
A proton and an electron traveling along parallel paths enter a region of the uniform magnetic field, acting perpendicular to their paths. Which of them will move in a circular path with a higher frequency? (CBSEAI and Delhi 2018)
Answer:
The frequency of revolution is given by
v = \(\frac{B q}{2 \pi m}\) ⇒ v ∝ \(\frac{1}{m}\) .

As for me < mp
therefore ve >vp

Question 11.
Two protons of equal kinetic energies enter a region of the uniform magnetic field. The first proton enters normal to the field direction while the second enters at 30° to the field direction. Name the trajectories followed by them. (CBSEAI and Delhi 2018C)
Answer:
Normal: circular
At an angle of 30°, it will follow a helical path.

Question 12.
Consider the circuit shown here where APB and AQB are semi-circles. What will be the magnetic field at the center C of the circular loop?
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 1
Answer:
Zero, because magnetic fields due to APB and AQB are equal in magnitudes but opposite in directions.

Question 13.
Which one of the following will have a minimum frequency of revolution,
when projected with the same velocity v perpendicular to the magnetic field B: (i) α – particle and (ii) β – particle.
Answer:
Frequency of revolution v = \(\frac{q B}{2 \pi m}\) and \(\frac{q}{m}\) of α – particle is less, hence α – particle will have minimum frequency of revolution.

Question 14.
An ammeter and a milli-ammeter are converted from the same galvanometer. Out of the two, which current-measuring instrument has higher resistance?
Answer:
A milli-ammeter has higher resistance.

Question 15.
Equal currents I and I are flowing through two infinitely long parallel wires. What will be the magnetic field at a point mid-way when the currents are flowing in the same direction?
Answer:
Zero, because fields due to two wires will be equal but opposite.

Question 16.
The figure shows a circular loop carrying current l. Show the direction of the magnetic field with the help of lines of
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 2
Answer:
The magnetic field lines are as shown
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 3
Question 17.
An electron is moving with velocity v along the axis of a long straight solenoid carrying current I. What will be the force acting on the electron due to the magnetic field of the solenoid?
Answer:
Zero, as a force on a charged particle moving in a magnetic field, is F= Bqv sin θ
Here both v and B are along the axis of – solenoid, so θ = 0° between them. Hence F= qvB sin θ = 0.

Moving Charges and Magnetism Important Extra Questions Short Answer Type

Question 1.
A charged particle having a charge q is moving with a speed of v along the X-axis. It enters a region of space where the electric field is \(\overrightarrow{\boldsymbol{E}}(\boldsymbol{E} \hat{\boldsymbol{j}})\) and a magnetic field \(\vec{B}\) are both present. The particle, on emerging from the region, is observed to be moving, along the X-axis only. Obtain an expression for the magnitude of \(\vec{B}\) in terms of v and E. Give the direction of \(\vec{B}\).
Answer:
Since the particle continues to move along the X-axis, therefore, the magnetic force acting on it should be completely balanced by the electric force. Since the electric force acts along the Y-axis, therefore, the magnetic force must be along the Z-axis.
Thus is equilibrium q E = B q v or v = E/B

Question 2.
A stream of electrons traveling with speed v m s-1 at right angles to a uniform magnetic field ‘B’ is reflected in a circular path of radius ‘r’ . Prove that \(\frac{e}{m}=\frac{v}{r B}\)
Answer:
Let a stream of electrons be traveling with speed v at right angles to a uniform magnetic field B then force due to magnetic field provides the required centripetal force which deflects the electron beam along a circular path of radius ‘r’ such that
Bev = \(\frac{m v^{2}}{r}\)
or
\(\frac{e}{m}=\frac{v}{r B}\)
where e = electronic charge and m = mass of the electron.

Question 3.
Which one of the two, an ammeter or a milliammeter, has a higher resistance and why?
Answer:
The shunt resistance connected to convert a galvanometer into an ammeter or a milliammeter is given by the expression S = \(\frac{I_{g} G}{I-l_{g}}\) where S is shunt resistance, G galvanometer resistance, l total current through G and S, and lg galvanometer current. In the case of milliammeter, l is small.

Therefore Smilliammeter > Sammeter . Hence the resistance of a milliammeter is greater than that of an ammeter.

Question 4.
A straight wire of length L carrying a current l stays suspended horizontally in mid-air in a region where there is a uniform magnetic field \(\vec{B}\). The linear mass density of the wire is l. Obtain the magnitude and direction of the magnetic field.
Answer:
The magnetic force acting on the straight wire balances the weight of the wire.
Therefore, in equilibrium we have Mg = BIL, here M = L l, therefore we have L l g = BlL or B = l/ l g
This field acts vertically upwards.

Question 5.
In the figure below, the straight wire AB Is fixed while the loop Is free to move under the influence of the electric currents flowing in them. In which direction does the loop begin to move? Give a reason for your answer.
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 4
Answer:
The loop moves towards the straight wire AB. In the loop in the side nearer to the wire AB current l2 is in the same direction as l1 and hence attractive force acts. However, on the side farther away from the wire AB current l2 is in the opposite direction and the force is repulsive. But as the magnitude of attractive force is greater than the repulsive force, the net force is attractive in nature and hence, the loop moves towards the wire AB.

Question 6.
A coil of ‘N’ turns and radius ‘R’ carries a current ‘l’. It is unwound and rewound to make a square coil of side ‘a’ having the same number of turns (N). Keeping the current ‘l’ same, find the ratio of the magnetic moments of the square coil and the circular coil. (CBSE Delhi 2013C)
Answer:
The magnetic moment of a current loop is given by the relation M = nlA
For the circular loop Mc = NlπR² …(1)

Now when the coil is unwound and rewound to make a square coil, then
2 πR = 4a or a = πR/2

Hence magnetic moment of the square coil is
Ms = Nl a² = Nl (πR/2)² = Nl π²R²/4 …(2)

From (1) and (2) we have
\(\frac{M_{S}}{M_{C}}=\frac{N l \pi^{2} R^{2} / 4}{N l \pi R^{2}}=\frac{\pi}{4}\)

Question 7.
Write the expression for Lorentz magnetic force on a particle of charge ‘q’ moving with velocity v in a magnetic field B. Show that no work is done by this force on the charged particle. (CBSE Al 2011)
Answer:
The expression is \(\vec{F}\) = q(\(\vec{v}\) × \(\vec{B}\)). This force always acts perpendicular to the direction of motion of the charged particle. Therefore the angle between \(\vec{F}\) and \(\vec{r}\) is 90°. Hence work done is W = \(\vec{F}\). r = Fr cos 90° = 0

Question 8.
(a) State Biot-Savart law in vector form expressing the magnetic field due to an element \(\vec{dl}\) carrying current l at a distance \(\vec{r}\) from the element.
Answer:
It states that for a small current element dl the magnetic field at a distance r is given by
\(\overrightarrow{d B}=\frac{\mu_{0}}{4 \pi} \frac{I \overline{(d L} \times \hat{r})}{r^{2}}\).

(b) Write the expression for the magnitude of the magnetic field at the center of a circular loop of radius r carrying a steady current l. Draw the field lines due to the current loop. (CBSE Al 2014C)
Answer:
The magnetic field at the center of a circular loop is given by
B = \(\frac{\mu_{0} l}{2 r}\)

The field lines are as shown.
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 5
Question 9.
Draw the magnetic field lines due to current passing through a long solenoid. Use Ampere’s circuital law, to obtain the expression for the magnetic field due to the current l in a long solenoid having n number of turns per unit length. (CBSE Delhi 2014C)
Answer:
The diagram is as shown.
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 6
Consider a rectangular path abed of length L as shown in the figure below. Let us apply Ampere’s circuital law to this rectangular path so that we have
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 23
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 24
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 25
But by Ampere’s circuital law we have
\(\oint \vec{B} \cdot \vec{d} L\) = μ0Nl = μ0(nL)l …(2)

From equations (1) and (2) we have
BL = μ0nLl
or
B = μ0 n l

But n = N/L, therefore we have
B = μ0 \(\frac{N l}{L}\)

This gives the value of a magnetic field inside a solenoid.

Question 10.
(a) Why do we use a shunt to convert a galvanometer into an ammeter?
Answer:
Since an ammeter is an instrument used to measure the current in the circuit, so it has to be connected in series in the circuit to measure the whole current. Hence its resistance must below. A low shunt resistance makes it suitable for measuring current.

(b) A galvanometer of resistance 15 Ω shows a full-scale deflection on the meter scale for a current of 6 mA. Calculate the value of the shunt resistance required to convert the galvanometer into an ammeter of range 0-6 A. (CBSE 2019C)
Answer:
Given G = 15 Ω, lg = 6 mA = 6 × 10-3 A, l = 6 A, S = ?
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 7
Question 11.
An electron beam projected along + X-axis experiences a force due to a magnetic field along the + Y-axis. What is the direction of the magnetic field?
Answer:
The direction of the magnetic field is along  Z-axis. This is because the direction of motion, the magnetic field, and the force are perpendicular to one other as an electron carries a negative charge.

Question 12.
A current is set up in a long copper pipe. Is there a magnetic field
(i) inside,
Answer:
There is no magnetic field inside the pipe.

(ii) outside the pipe?
Answer:
There is a magnetic field outside the pipe.

Question 13.
Which one of the following will experience a maximum force, when projected with the same velocity V perpendicular to the magnetic field (i) alpha particle and (ii) beta particle?
Answer:
The force experienced by a charged particle is given by the expression F = B q v. Since an alpha particle has a moving charge than the beta particle, therefore the alpha particle will experience more force.

Question 14.
An electron and a proton moving parallel to each other in the same direction with equal momenta enter into a uniform magnetic field which is at right angles to their velocities. Trace their trajectories in the magnetic field.
Answer:
Because both electron and proton have the same charge and momentum, therefore they will describe circles of equal radii as shown.
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 8
Question 15.
Is the steady electric current the only source of the magnetic field? Justify your answer. (CBSE Delhi 2013C)
Answer:
No, the magnetic field is also produced by alternating current.

Question 16.
A deuteron and an alpha particle having the same momentum is in turn allowed to pass through a magnetic field B, acting normal to the direction of motion of the particles. Calculate the ratio of the radii of the circular paths described by them. (CBSE Delhi 2019)
Answer:
Pd = Pα
Now r = \(\frac{mv}{Bq}\) ⇒ r ∝ \(\frac{1}{q}\)

Therefore, \(\frac{r_{d}}{r_{\alpha}}=\frac{q_{\alpha}}{q_{d}}=\frac{2 e}{e}\) = 2

Question 17.
Two wires of equal length are bent in the form of two loops. One of the loops is square-shaped and the other is circular. These are suspended in a uniform magnetic field and the same current is passed through them. Which loop will experience a greater torque? Give reasons.
Answer:
Torque experienced by a current-carrying loop placed in a uniform magnetic field is given by the expression τ = BlnA. In other words, torque is directly proportional to the area of the loop. Since a circular wire has more area than a square wire for the same dimension, therefore the circular wire experiences more torque than the square wire.

Question 18.
Which one of the following will have a minimum frequency of revolution, when projected with the same velocity v perpendicular to the magnetic field B: (i) alpha particle and (ii) beta particle?
Answer:
The frequency of revolution of a charged particle in a magnetic field is given by Bq
v = \(\frac{Bq}{2πm}\).

The ratio of q/m for an alpha particle is less than that for a beta particle; therefore, the alpha particle will have a minimum frequency of revolution.

Question 19.
Using the concept of force between two infinitely long parallel current-carrying conductors, define one ampere of current. (CBSE AI 2014)
Answer:
One ampere is that much current which when flowing through each of the two infinitely long straight conductors held 1 meter apart in space, produce a force of F= 2 × 10-7 N per meter of their length.

Question 20.
(a) Write the expression for the force \(\vec{F}\) , acting on a charged particle of charge ‘q’, moving with a velocity v in the presence of both electric field \(\vec{E}\) and magnetic field \(\vec{B}\) . Obtain the condition under which the particle moves undeflected through the fields.
Answer:
(a) The required expression is \(\vec{F}=q \vec{E}+q(\vec{v} \times \vec{B})\)

The particle will move undeflected if the force acting on it due to the electric field balances the force acting on it due to the magnetic field. Thus qE = Bqv or v=E/B

(b) A rectangular loop of size l × b carrying a steady current I is placed in a uniform magnetic field \(\vec{B}\) . Prove that the torque τ acting on the loop is given by \(\vec{τ}\) = \(\vec{m}\) × \(\vec{B}\) , where m is the magnetic moment of the loop. (CBSE AI 2012, Delhi 2013)
Answer:
The figure below shows a rectangular loop of wire with length ‘a’ and breadth ‘b’. A line perpendicular to the plane of the loop (i.e. a normal to the plane) makes an angle Φ with the direction of the magnetic field B, and the loop carries a current / as shown. Let the forces acting on the various sides of the loop be \(\vec{F}_{1}\), \(\vec{F}_{2}\), \(\vec{F}_{3}\) and \(\vec{F}_{4}\) as shown.

It follows from the expression for the force experienced by a conductor in a magnetic field that force on arm AB is
\(\vec{F}_{1}=I(\overrightarrow{\mathrm{AB}} \times \vec{B})\) …(1)
(in the plane of the paper and is directed upwards as shown).

The force on arm CD is given by \(\vec{F}_{2}=l(\overrightarrow{\mathrm{CD}} \times \vec{B})\) …(2)
(in the plane of the paper and is directed downwards as shown.)

Since these two forces are equal and opposite and have the same line of action therefore they cancel out each other’s effect and their resultant effect on the coil is zero.

Now the force on arm BC is
\(\vec{F}_{3}=l(\overrightarrow{\mathrm{BC}} \times \vec{B})\) …(3)
(acts perpendicular to the plane of the paper and is directed outwards as shown) Finally the force on arm DA is
\(\vec{F}_{4}=I(\overrightarrow{\mathrm{DA}} \times \vec{B})\) …(4)
(acts perpendicular to the plane of the paper and is directed inwards as shown in figure).

Both forces F3 and F4 make an angle of 90° with the direction of the magnetic field. Therefore, in magnitude, these forces are given by
F3 = F4 = laB sin90° = laB …(5)

The lines of action of both these forces are perpendicular to the plane of the paper. The two forces F3 and F4 lie along different lines and each give rise to a torque about the X-axis. The two torques produce a resultant torque in + X direction. The arm of the couple (perpendicular distance between the lines of action of the two forces) from the figure below is given by
An arm of couple = b Sin Φ …(6)

Therefore, by the definition of torque we have
Torque = either force × arm of couple Using equations (5) and (6) we have
Torque = l B a × b Sin Φ
But a b = A, area of the coil, therefore τ = l B A Sin Φ
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 48
Question 21.
Show that a force that does no work must be a velocity-dependent force. (NCERT Exemplar)
Answer:
We know that work is the dot product of force and displacement, therefore
dW = \(\vec{F} \cdot d \vec{l}\) = 0
Or
dW = \(\vec{F}\) .\(\vec{v}\)dt = 0
Or
\(\vec{F} \cdot \vec{v}\) = 0

Thus F must be velocity dependent which implies that the angle between F and v is 90°. If v changes direction then the direction of F should also change so that the above condition is satisfied.

Question 22.
Five long wires A, B, C, D, and E, each carrying current l is arranged to form edges of a pentagonal prism as shown in the figure. Each carries current out of the plane of the paper.
(a) What will be magnetic induction at a point on axis 0? Axis is at a distance R from each wire.
(b) What will be the field if the current in one of the wires (say A) is switched off?
(c) What if the current in one of the wires (say) A is reversed? (NCERT Exemplar)
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 9
Answer:
(a) Zero Mn I
(b) \(\frac{\mu_{0}}{2 \pi} \frac{1}{R}\) perpendicular to AO towards left
(c) \(\frac{\mu_{0}}{\pi} \frac{1}{R}\) perpendicular to AO towards left

Moving Charges and Magnetism Important Extra Questions Long Answer Type

Question 1.
(a) A particle of charge ‘q’ and mass ‘m’, moving with velocity \(\vec{v}\) is subjected to a uniform magnetic field \(\vec{B}\) perpendicular to its velocity. Show that the particle describes a circular path. Obtain an expression for the radius of the circular path of the particle.
Answer:
Let a charged particle of charge q and mass m be moving with velocity \(\vec{v}\) right angle to the field (i.e. in the plane of the paper), then magnetic force \(\vec{F}\) acting on the charge q will be
\(\vec{F}=q(\vec{v} \times \vec{B})\)
or
F = qvB sin 90°
or
F = qvB … (1)
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 10
As this forces fact at a right angle to the velocity V of the charged particle, the slot is unable to change the velocity but can make the charged particle move In a circular path.

If r is the radius of the circle, then the centripetal force required by the charged particle will be
\(F_{c}=\frac{m v^{2}}{r}\)

This centripetal force Is provided by the magnetic force acting on the charged particle.
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 11
(b) Explain, how its path will be affected if the velocity \(\vec{v}\) makes an angle (θ ≠ 90°) with the direction of the magnetic field. (CBSE 2019C)
Answer:
If (θ ≠ 90°), the velocity \(\vec{v}\) of the moving charge can be resolved into two components v cos θ, in the direction of the magnetic field and make it v sin θ, in the direction perpendicular to the magnetic field. The charged particle under the combined effect of the two components of velocities wilt cover linear as well as a circular path, i.e. helical path whose axis is parallel to the magnetic field.

Question 2.
(a) Obtain the conditions under which an electron does not suffer any deflection while passing through a magnetic field.
Answer:
No deflection suffered by the electron if it moves parallel or anti-parallel to the magnetic field.

(b) Two protons P and Q moving with the same speed pass through the magnetic fields \(\vec{B}_{1}\) and \(\vec{B}_{2}\) respectively, at right angles to the field directions. If \(\left|\vec{B}_{2}\right|>\left|\vec{B}_{1}\right|\), which of the two protons will describe the circular path of smaller radius? Explain. (CBSEAI 2019)
Answer:
The radius of the circular path traveled by a charged particle in a magnetic field is given by
r = \(\frac{mv}{Bq}\)

Therefore, \(\frac{r_{1}}{r_{2}}=\frac{B_{2}}{B_{1}}\)

As \(\left|\vec{B}_{2}\right|>\left|\vec{B}_{1}\right|\) therefore, r2 < r1

Question 3.
A straight wire of length L is bent into a semi-circular loop. Use Biot-Savart law to deduce an expression for the magnetic field at its center due to the current l passing through it. (CBSE Delhi 2011C)
Answer:
Consider a straight wire of length L. Let it be bent into a semicircular arc of radius r as shown,
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 12
Then πr = L or r = L/π

Let a current I be passed through it. Divide the semi-circular loop into a large number of elements; consider one such element PQ of length dl. Then the small magnetic field cfB produced at the point O is

dB = \(\frac{\mu_{0}}{4 \pi} \frac{l d l \sin 90^{\circ}}{r^{2}}=\frac{\mu_{0}}{4 \pi} \frac{l d l}{r^{2}}\) outwards at point O.

Therefore total magnetic field at point O is
B = \(\int_{0}^{\pi r} \frac{\mu_{0}}{4 \pi} \frac{l d l}{r^{2}}=\frac{\mu_{0} l}{4 r}=\frac{\mu_{0} l \pi}{4 L}\)

Question 4.
A circular coil of N turns and radius R carries a current l. It is unwound and rewound to make another coil of radius R/2, current l remaining the same. Calculate the ratio of the magnetic moments of the new coil and the original coil. (CBSE AI 2012)
Answer:
The magnetic moment of a current-carrying coil is given by
M = n lA = n l πR²

When the coil is unwound and wound into another coil of radius R/2, the number of turns will double, i.e. n = 2
Therefore, n1 = 1, n2 = 2, R1 = R, R2 = R/2, hence

Therefore \(\frac{M_{2}}{M_{1}}=\frac{n_{2} / \pi R_{2}^{2}}{n_{1} / \pi R_{1}^{2}}=\frac{2}{4}=\frac{1}{2}\)

Question 5.
Two identical coils P and Q each of radius R are lying in perpendicular planes such that they have a common center. Find the magnitude and direction of the magnetic field at the common center when they carry currents equal to l and \(\sqrt{3}\) l respectively. (CBSE Al 2019)
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 13
Answer:
Magnetic field at the common centre due to coil P
\(B_{1}=\frac{\mu_{o} l}{2 R}\)

Magnetic field at the common centre due to coil Q
\(B_{2}=\frac{\mu_{0} \sqrt{3} l}{2 R}\)
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 14
The two fields are mutually perpendicular, therefore, the resultant field at the common centre is
B = \(\sqrt{B_{1}^{2}+B_{2}^{2}}=\sqrt{\left(\frac{\mu_{o} l}{2 R}\right)^{2}+\left(\frac{\mu_{0} \sqrt{3} 1}{2 R}\right)^{2}}\)
= \(\frac{\mu_{o} l}{R}\)

Let the resultant field make an angle θ with magnetic field B<sub>2</sub> as shown
tan θ = \(\frac{B_{1}}{B_{2}}=\frac{1}{\sqrt{3}}\) ⇒ θ = 30°

Question 6.
Find the condition under which the charged particles moving with different speeds in the presence of electric and magnetic field vectors can be used to select charged particles of a particular speed. (CBSE A! 2017)
Answer:
Consider crossed electric and magnetic fields. Let the particle enter perpendicular to both these fields. Due to this, the electric and magnetic forces are in opposite directions. Suppose, we adjust the value of E and B such that the magnitudes of the two forces are equal. Then, the total force on the charge is zero and the charge will move in the fields undeflected.

This happens when, or qE = qvB or v = E/B

This condition can be used to select charged particles of a particular velocity out of a beam containing charges moving at different speeds (irrespective of their charge and mass). The crossed E and B fields, therefore, serve as a velocity selector. Only particles with speed E/B pass undeflected through the region of crossed fields.

Question 7.
(a) Define the SI unit of current in terms of the force between two parallel current-carrying conductors.
Answer:
One ampere is that much current which when flowing through each of the two infinitely long straight conductors held 1 meter apart in space, produces a force of F = 2 × 10-7 N per meter of their length.

(b) Two long straight parallel conductors carrying steady currents la and lb along the same direction are separated by a distance d. How does one explain the force of attraction between them? If a third conductor carrying a current l in the opposite direction is placed just in the middle of these conductors, find the resultant force acting on the third conductor. (CBSE AI, Delhi 2018C)
Answer:
The magnetic field produced by one current applies a force on the other current-carrying conductor. By Fleming’s left-hand rule the forces acting on each due to other is directed towards each other. This shows attraction.

Force on C conductor due to conductor A
Fca = \(\frac{\mu_{0} l_{a} l_{c}}{\pi d}\) repulsive

Force on C conductor due to conductor B
Fcb = \(\frac{\mu_{0} l_{b} l_{c}}{\pi d}\)

\(F_{\mathrm{ac}}-F_{\mathrm{bc}}=\frac{\mu_{0} l_{\mathrm{c}}}{\pi d}\left(l_{a}-l_{b}\right)\)

Question 8.
ExplaIn how will you convert a galvanometer into a voltmeter to read a maximum potential of ‘V’ volt. Can one use a voltmeter to measure the emf of a cell? Justify your answer.
Answer:
Suppose a galvanometer having resistance G is to be converted into a voltmeter, which can measure the potential difference from O to V volt. Let a high resistance R be joined in senes with the galvanometer for this purpose. Its value is so chosen that when the galvanometer with the resistance is connected between two points having a potential difference of V volt, the gaLvanometer gives full-scale deflection. It is clear from the figure below that
V = lg (R + G)
or
R = \(\frac{v}{l_{g}}\) – G
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 15
On connecting the above high resistance in series with a galvanometer, the galvanometer is converted into a voltmeter of range V volt.

A voltmeter cannot measure the emf of the cell as it draws current from the cell while measuring the potential differences.

Question 9.
Explain how will you convert a galvanometer into an ammeter to read a maximum current of ‘l’ ampere. An ammeter is always connected in series with a circuit. Why? (CBSE AI 2019)
Answer:
Suppose a galvanometer of resistance G is to be converted into an ammeter having range 0 to l ampere. Let lg be the current,
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 16
which gives full-scale deflection in the galvanometer. Suppose S is the appropriate shunt required for this purpose, i.e. when shunt S Is used, current ‘g passes through the galvanometer and the remaining (l – lg) passes through the shunt as shown in the figure below. Since the shunt and the galvanometer are connected In parallel therefore the potential differences across both wilL be the same. Hence
lg G = (l – lg) S ….(1)

S = \(\frac{l_{s} G}{l-l_{s}}\) ….(2)

An ammeter is used to measure current; therefore, it is connected in senes so that the entire current passes through it. Moreover, an ammeter is a low resistance device.

Question 10.
A steady current (l1) flows through a long straight wire. Another wlrè carrying steady current (l2) In the same direction is kept close and parallel to the first wire. Show with the help of a diagram how the magnetic field due to the current l1 exerts a magnetic force on the second wire. Write the expression for this force. (CBSE AI 2011)
Answer:
The diagram is as shown below.
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 17
Magnetic field B1 is produced by the wire carrying current l1 on a wire carrying current l2. Thus the second current-carrying wire is placed in the magnetic field produced by the first as a result it experiences a force is given by F = \(\frac{\mu_{0} l_{1} l_{2}}{2 \pi r}\) per unit length.

Question 11.
(a) State Ampere’s circuital law expressing it in the integral form.
(b) Two long coaxial insulated solenoids S1 and S2 of equal lengths are wound one over the other as shown in the figure. A steady current ‘l’ flows through the inner solenoid S1 to the other end B, which is connected to the outer solenoid S2 through which the same current ‘l’ flows in the opposite direction so as to come out at end A. If n1 and n2 are the numbers of turns per unit length, find the magnitude and direction of the net magnetic field at a point
(i) inside on the axis and
(ii) outside the combined system. (CBSE Delhi 2014)
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 18
Answer:
(a) The line integral of B around any closed path equals µol, where l is the total steady current passing through any surface bounded by the closed path.” Mathematically
\(\oint \vec{B} \cdot \overrightarrow{d L}=\mu_{0} I\)

(b) (i) The magnetic field due to a current-carrying solenoid:
B = µon l

where n = number of turns per unit length
l = current through the solenoid

Now, the magnetic field due to solenoid S1 will be in the upward direction and the magnetic field due to S2 will be in the downward direction (by right-hand screw rule).
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 19
In the upward direction

(ii) The magnetic field is zero outside a solenoid.

Question 12.
Three long straight parallel wires are kept as shown in the Figure. The wire (3) carries a current l
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 20
(i) The direction of flow of current l in wire (3) is such that the net force, on a wire (1), due to the other two wires, is zero.
(ii) By reversing the direction of l, the net force on the wire (2), due to the other two wires, becomes zero. What will be the direction of current l, in the two cases? Also obtain the relation between the magnitudes of currents l1, l2, and l. (CBSE Delhi 2016C)
Answer:
Case 1: The direction of flow of current in the wire (3) will be opposite to the direction of flow of current in the wire (1), i.e. downwards.
Also \(\frac{\mu_{0} l_{1} l}{2 \pi(2 a)}=\frac{\mu_{0} l_{1} l_{2}}{2 \pi a}\)
or
l = 2l2

Case 2: The direction of flow of current in wire (3) will be same as the direction of flow of current in wire (1), i.e. upwards. For zero force on wire (2) we have
\(\frac{\mu_{0} l_{1} l_{2}}{2 \pi a}=\frac{\mu_{0} l l_{2}}{2 \pi a}\)
or
l = l1
Therefore l = l1 = 2 l2

Question 13.
Show mathematically that the cyclotron frequency does not depend upon the speed of the particle.
Answer:
Due to the presence of the perpendicular magnetic field the particle moves in a circle of radius r given by
r = \(\frac{m v}{q B}\) ….(1)

The path of the particles in the dees is a semicircle and the time the particle spends in each dees is length of the semi circular path velocity
t = \(\frac{\text { length of the semi circular path }}{\text { velocity }}\)
= \(\frac{\pi r}{v}=\frac{\pi m}{B q}\) …(2)

using equation (1)
The above time is independent of the radius of the path and the velocity of the charged particle. Now the time period of the cyclotron is twice the time spent by the particle in each dee. Thus

T = 2t = \(\frac{2 \pi m}{B q}\) …(3)

Hence cyclotron frequency or the magnetic resonance frequency is given by
v = \(\frac{1}{T}=\frac{B q}{2 \pi m}\) …(4)

which is independent of the speed of the particle.

Question 14.
State the principle of a cyclotron. Show that the time period of revolution of particles in a cyclotron is independent of their speeds. Why is this property necessary for the operation of a cyclotron? (CBSE Al 2016)
Answer:
Principle of cyclotron: It is based on the principle that the positive ions can be accelerated to high energies with a comparatively smaller alternating potential difference by making them cross the electric field again and again, by making use of a strong magnetic field.

The necessary centripetal force required by charged particle to revolve in a circular path in magnetic field is provided by force due to magnetic field, i.e.
\(\frac{m v^{2}}{r}\) = Bqv
or
v = \(\frac{\text { Bqr }}{m}\)

So, the frequency of revolution is then given by
T = \(\frac{2 \pi r}{v}=2 \pi r \times \frac{m}{B q r}=\frac{2 \pi m}{B q}\)

It is clear from the expression that T is Independent of speed.

If this condition is not met the charged particle will very soon go out of step with the applied electricity and will not be accelerated.

Question 15.
(a) Write the expression for the magnetic force acting on a charged particle moving with velocity v in the presence of magnetic field B.
Answer:
\(\vec{F}\) = q\((\vec{v} \times \vec{B})\)

(b) A neutron, an electron and an alpha particle moving with equal velocities enter a uniform magnetic field going into the plane of the paper as shown. Trace their paths in the field and justify your answer. (CBSE Delhi 2016)
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 21
Answer:
The path area is shown.
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 22
The radius of the circular path traveled by each particle is given by the expression
r = \(\frac{m v}{B q}\) since B and v is the same therefore

we have r ∝ \(\frac{m}{q}\). Since neutron does not have a charge therefore it passes straight without deflection. The ratio m/q for an alpha particle is greater for an alpha particle therefore its path will be less curved.

Also by Fleming’s left-hand rule the alpha particle and the electron will experience a force in the direction as shown.

Question 16.
A long solenoid of length ‘L’ having N turns carries a current l. Deduce the expression for the magnetic field in the interior of the solenoid. (CBSE AI 2011C)
Answer:
Consider a rectangular path abed of length L as shown in the figure below. Let us apply Ampere’s circuital law to this rectangular path so that we have
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 23
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 24
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 25
But by Ampere’s circuital law we have
\(\oint \vec{B} \cdot \vec{d} L\) = μ0Nl = μ0(nL)l …(2)

From equations (1) and (2) we have
BL = μ0nLl
or
B = μ0 n l

But n = N/L, therefore we have
B = μ0 \(\frac{N l}{L}\)

This gives the value of a magnetic field inside a solenoid.

Question 17.
Using Biot-Savart’s law, derive an expression for the magnetic field intensity at the center of a current-carrying circular coil.
Answer:
Consider a circular loop of radius r carrying a current l and having a center at O as shown in the figure below.
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 26
Consider a small current element dL on the loop. Then by Biot-Savart’s law the magnitude of the magnetic field at the center of the loop due to the current element we have
dB = \(\frac{\mu_{0}}{4 \pi} \frac{l d L \sin \theta}{r^{2}}\) …(1)

In this case, the angle between the current element dL and the radius vector is 90° therefore equation (1) can be written as
dB = \(\frac{\mu_{0}}{4 \pi} \frac{l d L}{r^{2}}\) ….(2)

The circular loop can be considered to be consisting of such small elements placed side by side, and then the magnetic intensities of these elements will be in the same direction. Thus, the net intensity of B at the center of the loop is given by
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 27
Question 18.
A charged particle q is moving in the presence of a magnetic field B which is inclined to an angle 300 with the direction of the motion of the particle. Draw the trajectory followed by the particle In the presence of the field and explain how the particle describes this path. (CBSE Delhi 2019)
Answer:
Two components of velocity vector V are responsible for the helical motion. Force on the charged particle due to the component normal to the magnetic field acts perpendicular to the velocity and the magnetic field and makes the particle follow a circular path. The component of velocity which is along the magnetic field does not cause any force on the particle, hence the particle continues to move in a straight line path due to this component so, the resultant path will be helical.

The path is as shown.
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 28
Question 19.
Two parallel coaxial circular costs of equal radius ‘R’ and an equal number of turns ‘N’, carry equal currents ‘I’ in the same direction and are separated by a distance ‘2R’. Find the magnitude and direction of the net magnetic field produced at the mid-point of the line joining their centers.
Answer:
The magnetic field at a distance R from a circular coil is given by the expression
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 29
Both are directed in the same direction, therefore the resultant magnetic field at the center is
B = \(\frac{\mu_{0} N l R^{2}}{\left(2 R^{2}\right)^{1 / 2}}\)

Question 20.
(a) State Biot-Savart’s law. Using this law, derive the expression for the magnetic field due to a current-carrying circular loop of radius ‘R’, at a point which is at a distance ‘x’ from Its center along the axis of the loop.
Answer:
It states that for a small current element the small magnetic field is given by the expression Biot-Savart’s law for a small current element \(\overrightarrow{d B}=\frac{\mu_{0}}{4 \pi} \frac{I \overline{(d L} \times \hat{r})}{r^{2}}\).

(b) Two small identical circular loops, marked (1) and (2), carrying equal currents, are placed with the geometrical axes perpendicular to each other as shown in the figure. Find the magnitude and direction of the net magnetic field produced at point O.
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 30
Answer:
The magnetic field at O due to the circular loop 1 is B1 = \(\frac{\mu_{0} l R^{2}}{2\left(x^{2}+R^{2}\right)^{1 / 2}}\) directed towards left.

The magnetic field at O due to the circular loop is B1 = \(\frac{\mu_{0} l R^{2}}{2\left(x^{2}+R^{2}\right)^{1 / 2}}\) directed upwards.

The net magnetic field is therefore
B = \(\sqrt{B_{1}^{2}+B_{2}^{2}}=\sqrt{2} B_{1}=\frac{\mu_{0} l R^{2}}{\sqrt{2}\left(x^{2}+R^{2}\right)^{3 / 2}}\)

The direction of the net magnetic field is 45° with the axis of the loop as shown in the figure below.
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 31

Question 21.
Derive an expression for the magnetic field along the axis of an air-cored solenoid, using Ampere’s circuital law. Sketch the magnetic field lines for a finite solenoid. Explain why the field at the exterior mid-point Is weak while at the interior it is uniform and strong.
Answer:
A solenoid is a coil of wire with a Length, which is Large as compared with its diameter.

Consider an ideaL soLenoid carrying current l and having n turns per unit length.
(a) Consider a rectangular path abed of length L as shown in the figure below. Let us apply Ampere’s circuital law to this rectangular path so that we have
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 23
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 24
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 25
But by Ampere’s circuital law we have
\(\oint \vec{B} \cdot \vec{d} L\) = μ0Nl = μ0(nL)l …(2)

From equations (1) and (2) we have
BL = μ0nLl
or
B = μ0 n l

But n = N/L, therefore we have
B = μ0 \(\frac{N l}{L}\)

This gives the value of a magnetic field inside a solenoid.

(b) The sketch Is as shown below.
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 32
The magnetic field gets added inside the solenoid whereas it is not added outside the solenoid.

Question 22.
(a)Using Ampere’s circuital law, obtain the expression for the magnetic field due to a long solenoid at a point inside the solenoid on its axis.
Answer:
Consider a rectangular path abed of length L as shown in the figure below. Let us apply Ampere’s circuital law to this rectangular path so that we have
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 23
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 24
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 25
But by Ampere’s circuital law we have
\(\oint \vec{B} \cdot \vec{d} L\) = μ0Nl = μ0(nL)l …(2)

From equations (1) and (2) we have
BL = μ0nLl
or
B = μ0 n l

But n = N/L, therefore we have
B = μ0 \(\frac{N l}{L}\)

This gives the value of a magnetic field inside a solenoid.

(b) In what respect is a toroid different from a solenoid? Draw and compare the pattern of the magnetic field lines in the two cases.
Answer:
(b) In a toroid magnetic field is uniform whereas in a solenoid it is different at the two ends and the center.
The magnetic field lines around the two are as shown.
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 33
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 34
(c) How is the magnetic field inside a given solenoid made strong? (CBSE Al 2011)
Answer:
(i) By inserting a ferromagnetic substance inside the solenoid.
(ii) By increasing the amount of current through the solenoid.

Question 23.
(a) Explain, giving reasons, the basic difference in converting a galvanometer into
(i) a voltmeter
Answer:
A voltmeter is always connected in parallel with the section of the circuit whose potential difference has to be measured. Further, it must draw a small current, otherwise, the voltage measurement will disturb the original setup by an amount that is very large. Thus a large resistance is connected to the galvanometer in series so as to minimize this effect.

(ii) an ammeter
Answer:
An ammeter measures current and is to be connected in series in a circuit. A galvanometer has a large resistance, therefore a shunt is connected to it in order to decrease its resistance such that the current in the circuit is not altered.

(b) Two long straight parallel conductors carrying steady currents l1 and l2 are separated by a distanced’. Explain briefly, with the help of a suitable diagram, how the magnetic field due to one conductor acts on the other. Hence deduce the expression for the force acting between the two conductors. Mention the nature of this force. (CBSE At 2012)
Answer:

Consider two long, straight parallel wires separated by a distance ‘a’ and carrying currents l1 and l2 in the same direction as shown. We can easily determine the force on one wire due to the magnetic field set-up by the other wire. Wire 2, which carries a current l2, sets up a magnetic field B2 at the position of wire 1.
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 40
The direction of B2 is perpendicular to the wire, as shown in figure. Now the magnetic force on length L of wire 1 is
\(\vec{F}_{1}=l_{1}\left(\vec{L} \times \vec{B}_{2}\right)\)

Since L is perpendicular to B2, the magnitude of F, is given by F1 = l1 L B2 …(1)
But the field due to wire 2 is given by the relation
B2 = \(\frac{\mu_{0} l_{2}}{2 \pi a}\) ….(2)

Therefore, from equations 1 and 2 we have
F1= l1 L B2 = l1 L\(\left(\frac{\mu_{0} l_{2}}{2 \pi a}\right)=\frac{L \mu_{0} l_{1} l_{2}}{2 \pi a}\)

We can rewrite it in terms of force per unit length as
\(\frac{F_{1}}{L}=\frac{\mu_{0} l_{1} l_{2}}{2 \pi a}\) ….(3)

The direction of F1 is downward, towards wire 2, since \(\vec{L} \times \vec{B}\) is downwards. If one considers the field set up at wire 2 due to wire 1, the force F2 is found to be equal and opposite to F1 which is in accordance with Newton’s third law of motion. When the currents are in opposite directions, the forces are reversed and the wires repel each other. Hence we find that the force per unit length of wire between two parallel current-carrying wires is given by
F = \(\frac{\mu_{0} l_{1} l_{2}}{2 \pi a}\)

Therefore, two conductors carrying current in the same direction attract each other whereas two conductors carrying current in the opposite directions repel each other.

The above expression can be used to define ampere, the SI unit of current.
Let l1 = l2 = 1 ampere, a = 1 m then F = 2 × 10-7 Nm-1

Thus we have
One ampere is that much current which when flowing through each of the two infinitely long straight conductors held 1 meter apart in space, produce a force of F = 2 × 10-7 N per meter of their length.

Question 24.
(a) State the underlying principle of a moving coil galvanometer.
Answer:
A current-carrying coil placed in a magnetic field experiences a torque.

(b) Give two reasons to explain why a galvanometer cannot as such be used to measure the value of the current in a given circuit.
Answer:

  1. A galvanometer is a very sensitive device; it gives a full-scale deflection for a current of the order of a few pA.
  2. The resistance of the galvanometer is not very small, hence it will change the value of current in the circuit branch when connected in series in that branch.

(c) Define the terms:
(i) voltage sensitivity and
(ii) current sensitivity of a galvanometer. (CBSE Delhi 2019)
Answer:

  • Voltage sensitivity: Voltage sensitivity is defined as the deflection per unit potential difference applied.
  • Current sensitivity: It is defined as the deflection per unit current.

Question 25.
(a) State Biot-Savart law. Deduce the expression for the magnetic field due to a circular current carrying loop at a point lying on its axis.
Answer:
It states that for a small current element the small magnetic field is given by the expression Biot-Savart’s law for a small current element \(\overrightarrow{d B}=\frac{\mu_{0}}{4 \pi} \frac{I \overline{(d L} \times \hat{r})}{r^{2}}\).

(b) Two long parallel wires carry currents l1 and l1 flowing in the same direction. When a third current-carrying wire is placed parallel and coplanar in between the two, find the condition when the third wire would experience no force due to these two wires. (CBSE AI 2012C)
Answer:
Two current-carrying wires carrying current in the same direction attract and those carrying current in the opposite direction repel. The current in the third wire at the center should be opposite to the current in the two wires.

The conditions should be

  • The center wire should carry current in the opposite direction to the two wires and
  • The center wire should be closer to the wire carrying lesser current.

Question 26.
(a) Derive the expression for the torque on a rectangular current-carrying loop suspended in a uniform magnetic field.
Answer:
The figure below shows a rectangular loop of wire with length ‘a’ and breadth ‘b’. A line perpendicular to the plane of the loop (i.e. a normal to the plane) makes an angle Φ with the direction of the magnetic field B, and the loop carries a current / as shown. Let the forces acting on the various sides of the loop be \(\vec{F}_{1}\), \(\vec{F}_{2}\), \(\vec{F}_{3}\) and \(\vec{F}_{4}\) as shown.

It follows from the expression for the force experienced by a conductor in a magnetic field that force on arm AB is
\(\vec{F}_{1}=I(\overrightarrow{\mathrm{AB}} \times \vec{B})\) …(1)
(in the plane of the paper and is directed upwards as shown).

The force on arm CD is given by \(\vec{F}_{2}=l(\overrightarrow{\mathrm{CD}} \times \vec{B})\) …(2)
(in the plane of the paper and is directed downwards as shown.)

Since these two forces are equal and opposite and have the same line of action therefore they cancel out each other’s effect and their resultant effect on the coil is zero.

Now the force on arm BC is
\(\vec{F}_{3}=l(\overrightarrow{\mathrm{BC}} \times \vec{B})\) …(3)
(acts perpendicular to the plane of the paper and is directed outwards as shown) Finally the force on arm DA is
\(\vec{F}_{4}=I(\overrightarrow{\mathrm{DA}} \times \vec{B})\) …(4)
(acts perpendicular to the plane of the paper and is directed inwards as shown in figure).

Both forces F<sub>3</sub> and F4 make an angle of 90° with the direction of the magnetic field. Therefore, in magnitude, these forces are given by
F3 = F4 = l a B sin90° = l a B …(5)

The lines of action of both these forces are perpendicular to the plane of the paper. The two forces F3 and F4 lie along different lines and each give rise to a torque about the X-axis. The two torques produce a resultant torque in the + X direction. The arm of the couple (perpendicular distance between the lines of action of the two forces) from the figure below is given by
The arm of couple = b Sin Φ …(6)

Therefore, by the definition of torque we have
Torque = either force × arm of couple Using equations (5) and (6) we have
Torque = l B a × b Sin Φ
But a b = A, area of the coil, therefore τ = l B A Sin Φ
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 48
(b) A proton and a deuteron having equal momenta enter in a region of the uniform magnetic field at a right angle to the direction of the field. Depict their trajectories in the field. (CBSE Delhi 2013)
Answer:
The radius of the curved path which will be followed by the two particles is given by the expression r = \(\frac{m v}{B q}\)

As md > mp it will follow the path of a bigger radius.
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 35

Question 27.
State Biot-Savart law, expressing it in the vector form. Use it to obtain the expression for the magnetic field at an axial point, distance ‘d’ from the center of a circular coil of radius ‘a’ carrying current ‘l’. Also, find the ratio of the magnitudes of the magnetic field of this coil at the center and at an axial point for which d = a \(\sqrt{3}\) (CBSE Delhi 2013C)
Answer:
(a) It states that the magnetic field due to a current element dl at a distance r from it is given by the expression

dB = \(\frac{\mu_{0}}{4 \pi} \frac{l d l \sin \theta}{r^{2}}\). In vector form it is written as
\(\overrightarrow{d B}=k_{m} \frac{l mid \overrightarrow{d L} \times \hat{r}}{r^{2}}\)

Consider a circular loop of wire of radius R located in the YZ plane and carrying a steady current / as shown in the figure below. Let us calculate the magnetic field at an axial point P a distance x from the center of the loop. From the figure it is clear that any element dL is perpendicular to r, furthermore, all the elements around the loop are at the same distance r from P, where r2 = X2 + R2. Hence by Biot-Savart’s law, the magnetic field at point P due to the current element dL is given by
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 44
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 45
The direction of the magnetic field dB due to the eLement dL is perpendicular to the plane formed by r and dL as shown in the figure above. The vector dB can be resolved into components dB aLong the X-axis and dB which is perpendicular to the X-axis. When the components perpendicular to the X-axis are assumed over the whole loop, the result is zero. That is, by symmetry any element on one side of the loop will set up a perpendicular component that cancels the component setup by an element diametrically opposite it. Therefore, it is obvious that the resultant magnetic field at P will be along the X-axis. This result can be obtained by integrating the components dBx = dB cos θ.
Therefore, we have
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 46
where the integral is to be taken over the entire loop since θ,x and R are constants for all elements of the loop and since
cos θ = \(\frac{R}{\sqrt{x^{2}+R^{2}}}\)

B = \(\frac{\mu_{0} l R}{4 \pi\left(x^{2}+R^{2}\right)^{3 / 2}} \oint d L=\frac{\mu_{0} l R^{2}}{2\left(x^{2}+R^{2}\right)^{1 / 2}}\)

To find the magnetic field at the centre of the loop setting x = O in equation the above equation we have B = \(\frac{\mu_{0} l}{2 R}\)

Now magnetic field at the centre of a circular coil is
\(B_{C}=\frac{\mu_{0} l}{2 a}\) …(1)

Also magnetic field on the axial line when
d = a\(\sqrt{3}\) is
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 36
From (1) and (2) we have
\(\frac{B_{C}}{B_{\text {axial }}}=\frac{\mu_{0} l}{2 a} \times \frac{16 a}{\mu_{0} l}\) = 8

Question 28.
A straight wire carrying a current of 12 A is bent into a semi-circular arc of radius 2.0 cm as shown in figure (a) Consider the magnetic field B at the center of the arc
(a) What is the magnetic field due to the straight segments?
(b) In what way the contribution to B from the semicircle differs from that of a circular loop and in what way does it resemble?
(c) Would your answer be different if the wire were bent into a semi-circular arc of the same radius but in the opposite way as shown in figure (b)? (NCERT)
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 37
Answer:
(a) dl and r for each element of the straight segments are parallel. Therefore \(d \vec{L} \times \hat{r}\) =0. Straight segments do not contribute to the magnetic field at the center of the semicircular arc.

(b) For all segments of the semicircular arc \(d \vec{L} \times \hat{r}\) are all parallel to, each other (into the plane of the paper). All such contributions add up in magnitude. Hence the direction of B for a semicircular arc is given by the right-hand rule and magnitude is half that of a circular loop. Thus
B = \(\frac{1}{2} \frac{\mu_{0} l}{2 r}=\frac{4 \pi \times 10^{-7} \times 12}{4 \times 2 \times 10^{-2}}\) = 9 × 10-4 T normal to the plane of the paper going into it.

(c) Same magnitude of B but opposite in direction to that in (b)

Question 29.
A long straight wire carrying a current of 25 A rests on a table as shown in the figure. Another wire PQ of length 1 m, mass 2.5 g carries the same current but in the opposite direction. The wire PQ is free to slide up and down. To what height will PQ rise? (NCERT Exemplar)
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 38
Answer:
Given l1 = l1 = 25 A, L = 1 m, m = 2.5 g = 2.5 × 10-3 kg
The repulsive force between PQ and the wire on the table will balance the weight of wire PQ. Let this happen when PQ is at a height h above the wire, then
F = mg
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 39
Question 30.
Two straight parallel conductors carry steady currents l1 and l2 separated by a distance d. if currents are flowing in the same direction, show how the magnetic field set-up in one produces an attractive force on the other. Obtain the expression for force. Hence define one ampere. (CBSE Delhi 2016)
Answer:
Consider two long, straight parallel wires separated by a distance ‘a’ and carrying currents l1 and l2 in the same direction as shown. We can easily determine the force on one wire due to the magnetic field set-up by the other wire. Wire 2, which carries a current l2, sets up a magnetic field B2 at the position of wire 1.
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 40
The direction of B2 is perpendicular to the wire, as shown in figure. Now the magnetic force on length L of wire 1 is
\(\vec{F}_{1}=l_{1}\left(\vec{L} \times \vec{B}_{2}\right)\)

Since L is perpendicular to B2, the magnitude of F, is given by F1 = l1 L B2 …(1)
But the field due to wire 2 is given by the relation
B2 = \(\frac{\mu_{0} l_{2}}{2 \pi a}\) ….(2)

Therefore, from equations 1 and 2 we have
F1= l1 L B2 = l1 L\(\left(\frac{\mu_{0} l_{2}}{2 \pi a}\right)=\frac{L \mu_{0} l_{1} l_{2}}{2 \pi a}\)

We can rewrite it in terms of force per unit length as
\(\frac{F_{1}}{L}=\frac{\mu_{0} l_{1} l_{2}}{2 \pi a}\) ….(3)

The direction of F1 is downward, towards wire 2, since \(\vec{L} \times \vec{B}\) is downwards. If one considers the field set up at wire 2 due to wire 1, the force F2 is found to be equal and opposite to F1 which is in accordance with Newton’s third law of motion. When the currents are in opposite directions, the forces are reversed and the wires repel each other. Hence we find that the force per unit length of wire between two parallel current-carrying wires is given by
F = \(\frac{\mu_{0} l_{1} l_{2}}{2 \pi a}\)

Therefore, two conductors carrying current in the same direction attract each other whereas two conductors carrying current in the opposite directions repel each other.

The above expression can be used to define ampere, the SI unit of current.
Let l1 = l2 = 1 ampere, a = 1 m then F = 2 × 10-7 Nm-1

Thus we have
One ampere is that much current which when flowing through each of the two infinitely long straight conductors held 1 meter apart in space, produce a force of F = 2 × 10-7 N per meter of their length.

Question 31.
(a) In a moving coil galvanometer, why is the magnetic field required to be radial?
Answer:
The radial field is always normal to the surface of the coil in all positions of the coil, i.e. θ = 0. The radial field ensures a linear relation between 0 and l in a moving coil galvanometer.

(b) A 100 turn closely wound circular coil of radius 10 cm carries a current of 3.2 A.
Calculate (i) the magnetic field at the centre of the coil, and
(ii) its magnetic moment. (CBSE2019C)
Answer:
Here N = 100, r = 10 cm = 0.1 m,
l = 3.2 A, B = ?, p = ?
(i) At the centre of the coil
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 41
(ii)Magnetic moment
p = NIA
= 100 × 3.2 × π × (0.1 )2 ≃ 10 Am2

Question 32.
State Ampere’s circuital law. Use this law to find a magnetic field due to a straight infinite current-carrying wire. How are the magnetic field lines different from the electrostatic field lines? (CBSE Al 2016)
Answer:
Statement: “The line integral of B around any closed path equals μ0 l, where l is the total steady current passing through any surface bounded by the closed path.”

Consider a long circular wire of radius ‘a’ carrying a steady current (dc) that is uniformly distributed along the cross-section of the wire as shown in the figure. Let us calculate the magnetic field in the regions r ≥ a and r < a. In region 1 let us choose a circular path of radius r centered at the wire. From symmetry, we find that B is perpendicular to dL at every point on the circular path.
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 42
Since total current linked with the circular path is l0, therefore by Ampere’s law we have
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 43

for r ≥ a
Magnetic field lines form closed loops while electrostatics field lines do not.

Question 33.
(a) State Biot-Savart law in vector form.
Answer:
It states that for a small current element the small magnetic field is given by the expression Biot-Savart’s law for a small current element \(\overrightarrow{d B}=\frac{\mu_{0}}{4 \pi} \frac{I \overline{(d L} \times \hat{r})}{r^{2}}\).

(b) Deduce the expression for the magnetic field at a point on the axis of a current-carrying circular loop of radius ‘R’, distant V from the center, hence write the magnetic field at the center of a loop. (CBSE AI 2015, Delhi 2018C)
Answer:
Consider a circular loop of wire of radius R located in the YZ plane and carrying a steady current / as shown in the figure below. Let us calculate the magnetic field at an axial point P a distance x from the center of the loop. From the figure it is clear that any element dL is perpendicular to r, furthermore, all the elements around the loop are at the same distance r from P, where r2 = X2 + R2. Hence by Biot-Savart’s law, the magnetic field at point P due to the current element dL is given by
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 44
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 45
The direction of the magnetic field dB due to the element dL is perpendicular to the plane formed by r and dL as shown in the figure above. The vector dB can be resolved into components dB along the X-axis and dB which is perpendicular to the X-axis. When the components perpendicular to the X-axis are assumed over the whole loop, the result is zero. That is, by symmetry any element on one side of the loop will set up a perpendicular component that cancels the component setup by an element diametrically opposite it. Therefore, it is obvious that the resultant magnetic field at P will be along the X-axis. This result can be obtained by integrating the components dBx = dB cos θ.
Therefore, we have
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 46
where the integral is to be taken over the entire loop since θ,x and R are constants for all elements of the loop and since
cos θ = \(\frac{R}{\sqrt{x^{2}+R^{2}}}\)

B = \(\frac{\mu_{0} l R}{4 \pi\left(x^{2}+R^{2}\right)^{3 / 2}} \oint d L=\frac{\mu_{0} l R^{2}}{2\left(x^{2}+R^{2}\right)^{1 / 2}}\)

To find the magnetic field at the centre of the loop setting x = O in equation the above equation we have B = \(\frac{\mu_{0} l}{2 R}\)

Question 34.
Derive an expression for the maximum force experienced by a straight conductor of length 1, carrying current I and kept in a uniform magnetic field, B.
Answer:
Consider a straight segment of a conducting wire; with length L and cross-section at area A, the current is from bottom to top as shown In the figure below. The wire is in a uniform magnetic field B perpendicular to the plane of the diagram and directed into the plane. Let us assume that the moving charges are positive.

The drift velocity is upward, perpendicular to B. The average force experienced by each charge is
\(\vec{f}=q\left(\vec{v}_{d} \times \vec{B}\right)\) …..(1)

Directed to the left as shown in the figure
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 47
Since \(\vec{V}_{d}\) and \(\vec{B}\) are perpendicular, the magnitude of the force is given by
f = q vd B …(2)

Let n be the number density of charges, i.e. number of charges per unit volume. A segment of the conductor with length L has volume V = A L and contains a number of charges N given by
N = n A L …(3)

Now the total force F on all the charges moving in this segment is
F = N f = (n A L) q vd B = (n q vd A) (L B)

But n q vd A = l, therefore the above equation becomes
F = B l L …(4)

Question 35.
Derive an expression for the torque on a rectangular coil of area A, carrying a current l and placed in a magnetic field B, the angle between the direction of 8 and the vector perpendicular to the plane of the coil is θ. (CBSE Delhi 2019)
Answer:
The figure below shows a rectangular loop of wire with length ‘a’ and breadth ‘b’. A line perpendicular to the plane of the loop (i.e. a normal to the plane) makes an angle Φ with the direction of the magnetic field B, and the loop carries a current / as shown. Let the forces acting on the various sides of the loop be \(\vec{F}_{1}\), \(\vec{F}_{2}\), \(\vec{F}_{3}\) and \(\vec{F}_{4}\) as shown.

It follows from the expression for the force experienced by a conductor in a magnetic field that force on arm AB is
\(\vec{F}_{1}=I(\overrightarrow{\mathrm{AB}} \times \vec{B})\) …(1)
(in the plane of the paper and is directed upwards as shown).

The force on arm CD is given by \(\vec{F}_{2}=l(\overrightarrow{\mathrm{CD}} \times \vec{B})\) …(2)
(in the plane of the paper and is directed downwards as shown.)

Since these two forces are equal and opposite and have the same line of action therefore they cancel out each other’s effect and their resultant effect on the coil is zero.

Now the force on arm BC is
\(\vec{F}_{3}=l(\overrightarrow{\mathrm{BC}} \times \vec{B})\) …(3)
(acts perpendicular to the plane of the paper and is directed outwards as shown) Finally the force on arm DA is
\(\vec{F}_{4}=I(\overrightarrow{\mathrm{DA}} \times \vec{B})\) …(4)
(acts perpendicular to the plane of the paper and is directed inwards as shown in figure).

Both forces F3 and F4 make an angle of 90° with the direction of the magnetic field. Therefore, in magnitude, these forces are given by
F3 = F4 = l a B sin90° = l a B …(5)

The lines of action of both these forces are perpendicular to the plane of the paper. The two forces F3 and F4 lie along different lines and each give rise to a torque about the X-axis. The two torques produce a resultant torque in the + X direction. The arm of the couple (perpendicular distance between the lines of action of the two forces) from the figure below is given by
The arm of couple = b Sin Φ …(6)

Therefore, by the definition of torque we have
Torque = either force × arm of couple Using equations (5) and (6) we have
Torque = l B a × b Sin Φ
But a b = A, area of the coil, therefore τ = l B A Sin Φ
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 48
Question 36.
Draw a schematic sketch of a cyclotron. State its working principle and write its two uses. (CBSE 2019C)
Answer:
Cyclotron
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 49
Working Principle: It is based on the principle that a positively charged particle can acquire very large energy with the small alternating potential difference if the particle is made to cross again and again the electric field produced by alternating potential difference applied and a strong perpendicular magnetic field is applied.

Uses:
(a) It is used to accelerate positively charged particles to very high energies.
(b) Cyclotrons are a source of high-energy beams for nuclear physics experiments.

Question 37.
(a) Draw a schematic sketch of a moving coil galvanometer and describe briefly its working.
Answer:
Principle: It is based on the principle that the positive ions can be accelerated to high energies with a comparatively smaller alternating potential difference by making them cross the electric field again and again, by making use of a strong magnetic field.
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 51
Construction: It consists of two D-shaped, hollow metal dees D1 and D2. The dees are placed with a small gap in between them. The dees are connected to a source of high frequency alternating potential difference. The dees are evacuated in order to minimize energy losses resulting from collisions between the ions and air molecules. The whole apparatus is placed between the poles of an electromagnet as shown in the figure below. The magnetic field is perpendicular to the plane of the dees.

Working: In a cyclotron, particles of mass m and charge q move inside an evacuated chamber in a uniform magnetic field B that is perpendicular to the plane of their paths. The alternating potential difference applied between the hollow electrodes D1 and D2 create an electric field in the gap between them which changes precisely twice in each revolution so that the particles get a push each time they cross the gap.

The pushes increase their speed and kinetic energy, boosting them into paths of larger radius. The electric field increases the speed and the magnetic field makes the particles move in circular paths. Due to the presence of the perpendicular magnetic field the particle moves in a circle of radius r given by
r = \(\frac{m v}{q B}\) …(1)

The path of the particles in the dees is a semicircle and the time the particle spends in each dee is semi-circular
τ = \(\frac{\text { length of the semi-circular path }}{\text { velocity }}=\frac{\pi r}{v}=\frac{\pi m}{B q}\) by using equation (1)

The above time is independent of the radius of the path and the velocity of the charged particle. Hence the charged particle spends the same time in each dee and encounters a dee of opposite polarity whenever it comes into the gap between the dees and thus is continuously accelerated.

(b) “Increasing the current sensitivity of a galvanometer does not necessarily increase the voltage sensitivity.” Justify’ this statement. (CBSE Delhi 2014C)
Answer:
Voltage and current sensitivities are related as VS = \(\frac{CS}{R}\) .

An increase in current sensitivity may lead to an increase in the resistance of the coil. Thus the factor CS/R may not be affected.

Question 38.
Explain with the help of a labeled diagram the underlying principle, construction, and working of a moving coil galvanometer.
Answer:
It is an instrument used to detect weak currents in a circuit.

Principle: It is based on the principle that, whenever a loop carrying current is placed in a magnetic field, it experiences a torque, which tends to rotate it.

Construction: It consists of a rectangular or circular coil made by winding a fine insulated copper wire on an aluminum frame. A thin phosphor bronze strip from a torsion head, which is connected to a terminal screw, suspends this coil. The lower end of the coil is connected to a fine spring which is connected to another terminal screw. The coil hangs in space between the pole pieces of a powerful horseshoe magnet NS as shown in the figure below. The pole pieces are made concave cylindrical.

This provides a radial magnetic field. Since the field is radial, therefore the plane of the coil remains parallel to the magnetic field in all the orientations of the coil. In between the pole pieces, within the coil, lies a soft iron cylindrical piece called ‘core’. The core does not touch the coil anywhere. The whole arrangement is enclosed in a non-magnetic box to protect it from air currents. Three leveling screws are provided at the base.
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 50
Question 39.
Explain with the help of a labeled diagram the underlying principle, construction, and working of a cyclotron. (CBSE Delhi 2019)
Answer:
Principle: It is based on the principle that the positive ions can be accelerated to high energies with a comparatively smaller alternating potential difference by making them cross the electric field again and again, by making use of a strong magnetic field.
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 51
Construction: It consists of two D-shaped, hollow metal dees D1 and D2. The dees are placed with a small gap in between them. The dees are connected to a source of high frequency alternating potential difference. The dees are evacuated in order to minimize energy losses resulting from collisions between the ions and air molecules. The whole apparatus is placed between the poles of an electromagnet as shown in the figure below. The magnetic field is perpendicular to the plane of the dees.

Working: In a cyclotron, particles of mass m and charge q move inside an evacuated chamber in a uniform magnetic field B that is perpendicular to the plane of their paths. The alternating potential difference applied between the hollow electrodes D1 and D2 create an electric field in the gap between them which changes precisely twice in each revolution so that the particles get a push each time they cross the gap. The pushes increase their speed and kinetic energy, boosting them into paths of larger radius. The electric field increases the speed and the magnetic field makes the particles move in circular paths. Due to the presence of the perpendicular magnetic field the particle moves in a circle of radius r given by
r = \(\frac{m v}{q B}\) …(1)

The path of the particles in the dees is a semicircle and the time the particle spends in each dee is semi-circular
τ = \(\frac{\text { length of the semi-circular path }}{\text { velocity }}=\frac{\pi r}{v}=\frac{\pi m}{B q}\) by using equation (1)

The above time is independent of the radius of the path and the velocity of the charged particle. Hence the charged particle spends the same time in each dee and encounters a dee of opposite polarity whenever it comes into the gap between the dees and thus is continuously accelerated.

Question 40.
The figure below shows a long straight wire of circular cross-section (radius a) carrying steady current l. The current is uniformly distributed across this cross-section. Calculate the magnetic field in the region r < a and r > a. Draw a graph showing the variation of a magnetic field for the above two cases.
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 52
Answer:
Consider a long circular wire of radius ‘a’ carrying a steady current (dc) that is uniformly distributed along the cross-section of the wire as shown in the figure. Let us calculate the magnetic field in the regions r ≥ a and r < a. In region 1 let us choose a circular path of radius r centered at the wire. From symmetry, we find that B is perpendicular to dL at every point on the circular path. Since total current linked with the circular path 1 is l0, therefore by Ampere’s law we have
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 53
for r ≥ a

Now consider the interior of the wire, i.e. region 2 where r < a. In this, the current l enclosed by the path is less than l<sub>0</sub>. Since the current is assumed to be uniform over the area of the wire,
Therefore
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 54

Now applying Ampere’s circuital rule to region 2 we have
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 55
The magnetic field versus r for this system is as shown in the figure below.
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 56
Question 41.
Draw the magnetic field lines due to a circular loop of area \(\vec{A}\) carrying current I. Show that it acts as a bar magnet of magnetic moment \(\vec{m}=I \vec{A}\). (CBSE Al 2015)
Answer:
The magnetic field lines are as shown
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 57
Magnetic field due to circular loop on its axis at far off points
B = \(\frac{\mu_{0}}{4 \pi} \frac{2 I A}{X^{3}}\)

Magnetic field due to a bar magnet at its axial point is
B = \(\frac{\mu_{0}}{4 \pi} \frac{2 m}{x^{3}}\)

Comparing the above two we have m = IA

Question 42.
(a) State Ampere’s circuital law. Use this law to obtain the expression for the magnetic field inside an air-cored toroid of average radius ‘r, having ‘n’ turns per unit length and carrying a steady current.
(b) An observer to the left of a solenoid of N turns each of cross-section area ‘A’ observes that a steady current I in it flows in the clockwise direction. Depict the magnetic field lines due to the solenoid specifying its polarity and show that it acts as a bar magnet of magnetic moment m = NIA. (CBSE Delhi 2015)
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 58
Answer:
(a) “The line integral of 8 around any closed path equal μ0l, where l is the total steady current passing through any surface bounded by the closed path.” Consider a toroidal solenoid. Let N be the number of turns and l be the current passed through it. For a solenoid whose coils are closely spaced, the field inside the solenoid is tangent to the dotted circular path as shown in the figure and is the same at all points lying on the dotted line.
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 59
Therefore we have
\(\oint \vec{B} \cdot d \vec{L}\) = B ∮dL = B (2 π r) …(1)

By Ampere’s circuital law we have ∮\(\overrightarrow{\mathbf{B}} \cdot d \vec{L}\) = μ0Nl …(2)

From equations 1 and 2 we have
B (2 π r) = μ0NI
or
B = \(\frac{\mu_{0} N I}{2 \pi r}\) but
\(\frac{N}{2 \pi r}\) = n

i. e. number of turns per unit length Therefore we have B = μ0 n I

This gives the field inside a toroidal solenoid.

(b) The magnetic field lines and the polarity of the solenoid is as shown.
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 60
Magnetic field due to the coil on its axis at far off points
B = \(\frac{\mu_{0}}{4 \pi} \frac{2 N I A}{x^{3}}\)

Magnetic field due to a bar magnet at its axial point is
B = \(\frac{\mu_{0}}{4 \pi} \frac{2 m}{x^{3}}\)

Comparing the above two we have m = NIA

Question 43.
(a) Use Biot-Savart law to derive the expression for the magnetic field due to a circular coil of radius R having N turns at a point on the axis at a distance ‘x’ from its center.
Draw the magnetic field lines due to this coil.
(b) A current l enters a uniform loop of radius R at point M and flows out at point N as shown in the figure. Obtain the net magnetic field at the center of the loop. (CBSE Delhi 2015C)
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 61
Answer:
(a) According to Biot-Savart law:
The magnitude of magnetic field d \(\vec{B}\) , is due to a current element d \(\vec{l}\), is proportional to current l and element length, dl.

inversely proportional to the square of the distance r.

Its direction is perpendicular to the plane containing d \(\vec{l}\) and \(\vec{r}\) .

In vector notation,
\(\overrightarrow{d B}=\frac{\mu_{0}}{4 \pi}, \frac{d \vec{l} \times \vec{r}}{r^{3}}\)

Using Biot-Savart law, obtain the expression for the magnetic field due to a circular coil of radius r, carrying a current I at a point on its axis distant x from the centre of the coil. (CBSE Delhi 2018C)
Answer:
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 69
we have \(\overrightarrow{d B}=\frac{\mu_{0}}{4 \pi} I \frac{|d \vec{i} \times \vec{r}|}{r^{3}}\)
r² = x² + R²

∴ dB = \(\frac{\mu_{0} I}{4 \pi} \frac{d l}{\left(X^{2}+R^{2}\right)^{3 / 2}}\)

Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 70
The magnetic fieLd Lines are as shown.
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 62
(b) At point O, the net magnetic field is the sum of fields due to two current segments carrying currents /1 and l2. If the potential difference between points A and B be V, then
V = I1 R1 = I2R2
where R, is the resistance of segment subtending an angle 90° at O and R2 is the resistance of segment subtending an angle (360° – 90°) at O.
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 63
Now R1 = \(\frac{\pi / 2}{2 \pi} R=\frac{R}{4}\)
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 64
Now field B1, at O due to smaller segment is
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 65
directed inwards.

Now field B2 at 0 due to larger segment is
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 66
directed outwards

Hence net magnetic field in the center is
B1 – B2 = \(\frac{3 \mu_{0} I}{32 r}-\frac{3 \mu_{0} I}{32 r}\) = 0

(ii) The velocity of the particle inside a cyclotron is given by v = \(\frac{B q r}{m}\) , which again depends upon the q/m ratio. The q/m ratio of an a particle is less than that of a proton, therefore a proton will come out with higher velocity.

Question 44.
(a) Define the SI unit of current in terms of the force between two parallel current-carrying conductors.
(b) Two long straight parallel conductors carrying steady currents la and lb along the same direction are separated by a distance d. How does one explain the force of attraction between them? If a third conductor carrying a current lc in the opposite direction is placed just in the middle of these conductors, find the resultant force acting on the third conductor. (CBSE Delhi 2018C)
Answer:
(a) The ampere is the value of that steady current which, when maintained in each of the two very long, straight, parallel conductors of negligible cross¬section, and placed one meter apart in vacuum, would produce on each of these conductors a force equal to 2 × 10-7 newton per meter of length.
(b) The wire (ii) experiences a force due to the magnetic field caused by the current flowing in wire (i).
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 67
The magnetic field at any point on the wire (b) due to the current in the wire (a) is perpendicular to the plane of two wires and pointing inwards and hence force on it will be towards wire (a). Similarly, the force on the wire (a) will be towards wire (b). Hence two wires carrying currents in the same direction attract each other.
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 68
Force on wire (3) due to wire (1)
\(\frac{\mu_{0} l_{a} l_{c}}{2 \pi\left(\frac{d}{2}\right)}\) towards right

Force on wire 3 due to wire 2
\(\frac{\mu_{0} l_{b} l_{c}}{2 \pi\left(\frac{d}{2}\right)}\) towards Left

Net force on wire 3
\(\frac{\mu_{0} I_{c}}{\pi d}\left[I_{a}-I_{b}\right]\) towards right nd °

Also accept
\(\frac{\mu_{0} I_{c}}{\pi d}\left[I_{b}-I_{a}\right]\) towards left

Question 45.
(a) State Biot-Savart law and express it in the vector form.
Answer:
(a) According to Biot-Savart law:
The magnitude of magnetic field d \(\vec{B}\) , is due to a current element d \(\vec{l}\), is proportional to current l and element length, dl.

inversely proportional to the square of the distance r.

Its direction is perpendicular to the plane containing d \(\vec{l}\) and \(\vec{r}\) .

In vector notation,
\(\overrightarrow{d B}=\frac{\mu_{0}}{4 \pi}, \frac{d \vec{l} \times \vec{r}}{r^{3}}\)

(b) Using Biot-Savart law, obtain the expression for the magnetic field due to a circular coil of radius r, carrying a current I at a point on its axis distant x from the centre of the coil. (CBSE Delhi 2018C)
Answer:
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 69
we have \(\overrightarrow{d B}=\frac{\mu_{0}}{4 \pi} I \frac{|d \vec{i} \times \vec{r}|}{r^{3}}\)
r² = x² + R²

∴ dB = \(\frac{\mu_{0} I}{4 \pi} \frac{d l}{\left(X^{2}+R^{2}\right)^{3 / 2}}\)

Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 70
Question 46.
Derive an expression for the velocity y0 of a positive ion passing undeflected through a region where crossed uniform electric field E and magnetic field B are simultaneously present. Draw and justify the trajectory of identical positive ions whose velocity has a magnitude less than \(\left|v_{c}\right|\).
OR
A particle of mass m and charge q is in motion at speed Y parallel to a long straight conductor carrying current I as shown below.
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 71
Find the magnitude and direction of the electric field required so that the particle goes undefeated. (CBSE Sample Paper 2018-19)
Answer:
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 72
If the ion passes undeflected, therefore the magnetic and electric forces acting on the ion must be equal and opposite.
Therefore
qE = Bqvc
vc = \(\frac{E}{B}\)

The trajectory would be as shown. Justification: For positive ions with speed v < vc. Force due to electric field wilt remains the same as It does not depend upon Vc.

But force due to the magnetic field will become Less than the initial value. This unbalances the two, electric and magnetic, forces hence, the ion will experience a net electric force. This will accelerate the ion along the direction of the electric field. Since initiaL velocity is perpendicular to E, the trajectory would be parabolic.
OR
For the charged particle to move undeflected

Electric force = magnetic force
qE = Bq v
or
E=Bv

Now magnetic field at a distance r from the long straight conductor is
B = \(\frac{\mu_{0} I}{2 \pi r}\)

This magnetic force Will act towards the wire.

Hence electric field is

E = \(\frac{\mu_{0} l v}{2 \pi r}\)

This electric field should act away from the wire.
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 73
Numerical Problems:

Formulae for solving numerical problems

  • Magnetic field due to a small current element dB = \(\frac{\mu_{0}}{4 \pi} \frac{l mid d L \sin \theta}{r^{2}}\)
  • Magnetic field due to an infinitely long straight conductor B = \(\frac{\mu_{0}}{4 \pi} \frac{2l}{a}\)
  • Magnetic field at the centre of a circular coil B = \(\frac{\mu_{0}}{4 \pi} \frac{2 \pi l}{r}\)
  • Force on a charge moving in a magnetic field F = Bq v Sin θ
  • The magnetic field inside a solenoid B = µ0 n I
  • Force on a current-carrying conductor placed in a magnetic field F = BIL Sin θ
  • Force between two current carrying conductors \(\frac{F_{1}}{L}=\frac{\mu_{0} l_{1} l_{2}}{2 \pi a}\)
  • Torque on a current loop τ = BI n A sin θ
  • Current in a galvanometer l = \(\frac{C}{n B A}\) sin θ
  • Shunt required S = \(\frac{l_{8} G}{l-I_{g}}\)
  • Resistance required R = \(\frac{v}{l_{g}}\) – G
  • Radius of a charged particle in a magnetic field r = \(\frac{m v}{B q}=\frac{\sqrt{2 m E}}{B q}\)

Question 1.
A proton and an alpha particle having the same kinetic energy are in turn allowed to pass through a uniform magnetic field perpendicular to their direction of motion. Compare the radii of the paths of the proton and the alpha particle.
Answer:
Given Eα = Ep, mα = 4 mp, qα = 2qp, B is same for both. Now the radius of the path followed is given by the expression
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 74
Question 2.
A circular coil of 30 turns and radius 8.0 cm carrying a current of 6.0 A is suspended vertically in a uniform horizontal magnetic field of magnitude 1.0 T. The field lines make an angle of 60° with the normal to the coil. Calculate the magnitude of the counter-torque that must be applied to prevent the coil from turning.
Answer:
Given n = 30, r = 8.0 cm = 8 × 10-2 m,
l = 6.0 A, B = 1.0 T, θ = 60°, τ = ?
Using the formula for torque
τ = BlnA

we have τ = Blnπr² sin θ
τ = 1 × 6 × 30 × 3.14 × (8 × 10-2)2 × sin 60°
= 3.1 N m

Question 3.
How can a moving coil galvanometer be converted into an ammeter? To increase the current sensitivity of a moving coil galvanometer by 50%, its resistance is increased so that the new resistance becomes twice its initial resistance. By what factor does its voltage sensitivity change?
Answer:
Voltage sensitivity
= \(\frac{\alpha}{V}=\frac{\alpha}{I R}=\frac{\text { current sensitivity }}{R}\)

When the current sensitivity increases by 50 % resistance becomes 2R.

New voltage sensitivity
= \(\frac{1+0.5}{2}\) = 0.75

Hence the voltage sensitivity decreases and becomes 75% of its original value.

Question 4.
A long straight conductor PQ carrying a current of 75 A is fixed horizontally. Another long conductor XY is kept parallel to PQ at a distance of 5 mm, in air. Conductor XY is free to move and carries a current l. Calculate the magnitude and direction of current l for which the magnetic repulsion just balances the weight of conductor XY (Mass per unit length for conductor XY is 10-2 kg m-1.)
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 75
Answer:
Given l1 = 75 A, r = 5 mm = 5 × 10-3 m, l2 = ? mass per unit length = 10-2kg m-1.

The force between the two wires should be repulsive and should balance the weight of the wire XY. Thus the current in wire XY will be opposite to that in wire PQ.

The force between the two current-carrying conductors is given by
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 76
Question 5.
A galvanometer has a resistance of 30 Ω. It gives full-scale deflection with a current of 2 mA. Calculate the value of the resistance needed to convert it into an ammeter of range 0-0.3 A.
Answer:
Given G = 30 Ω, lg = 2 mA= 2 × 10-3 A, S = ?, I = 0.3 A
Using the formula S = \(\frac{I_{g} G}{I-I_{g}}\)

we have
S = \(\frac{I_{g} G}{I-I_{g}}\) = \(\frac{30 \times 2 \times 10^{-3}}{0.3-2 \times 10^{-3}}\) = 0.20 Ω

Question 6.
An infinitely long straight current-carrying wire produces a magnetic field 8, at a point distant ‘a’ from it. What must be the radius of a circular loop, so that, for the same current through it, the magnetic field at (i) its center equals B/2 and (ii) an axial point, distant equal to the radius of the loop, equals B?
Answer:
The magnetic field at a distance ‘a’ from an infinitely long straight conductor is
B = \(\frac{\mu_{0} I}{2 \pi a}\)

(i) Given Bc = B/2. Let r be the radius of the circular coil for which the magnetic field is B/2.

Magnetic field at the centre of a circular coil is \(B=\frac{\mu_{0} I}{2 \pi a}\) Therefore
\(\frac{\mu_{0} l}{2 r}=\frac{1}{2} \times \frac{\mu_{0} l}{2 \pi a}\) or r = 2 π a

(ii) Magnetic field at the axial line of a loop is
B = \(\frac{\mu_{0} l R^{2}}{2\left(x^{2}+R^{2}\right)^{1 / 2}}\)

Here x = R radius of the loop.
Therefore \(\frac{\mu_{0} I}{2 \pi a}=\frac{\mu_{0} I R^{2}}{2\left(R^{2}+R^{2}\right)^{3 / 2}}\)

solving for R we have R = \(\frac{\pi a}{\sqrt{8}}\)

Question 7.
Calculate the value of resistance needed to convert a galvanometer of resistance 120 ft, which gives a full-scale deflection for a current of 5 mA, into a voltmeter of 0 – 50 V range.
Answer:
Given G = 120 Ω, lg = 5 × 10-3A, V= 50 V, R =?

Using the relation R = \(\frac{v}{l_{g}}\) – G we have
R = \(\frac{50}{5 \times 10^{-3}}\) -120 = 9880 Ω

Question 8.
Two infinitely long straight wires A1 and A2 carrying currents l1 and l2 flowing in the same directions are kept distance apart. Where should a third straight wire A3 carrying current 1.5 l be placed between A1 and A2 so that it experiences no net force due to A1 and A2? Does the net force act on A3 depend on the current flowing through it? (CBSE Delhi 2019)
Answer:
The diagram is as shown.
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 77
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 78
If no force is experienced by the conductor A3, then
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 79
The net force on A3 does not depend upon the current flowing through it.

Question 9.
An ammeter of resistance 0.80 Ω can measure current up to 1.0 A.
(a) What must be the value of shunt resistance to enable the ammeter to measure current up to 5.0 A?
Answer:
Given G = 0.80 Ω, /g = 1.0 A, l = 5.0 A, S = ?, R<sub>A</sub> = ?
(a) Using the expression
S = \(\frac{I_{g} G}{I-I_{0}}=\frac{1 \times 0.8}{5-1}=\frac{0.8}{4}\) = 0.2 Ω

(b) What is the combined resistance of the ammeter and the shunt? (CBSE Delhi 2013)
Answer:
Now RA = \(\frac{G S}{G+S}=\frac{0.8 \times 0.2}{0.8+0.2}\) = 0.016 Ω

Question 10.
A wire AB is carrying a steady current of 12 A and is lying on the table. Another wire CD carrying 5A is held directly above AB at a height of 1 mm. Find the mass per unit length of the wire CD so that it remains suspended at its position when left free. Give the direction of the current flowing in CD with respect to that in AB. (Take the value of g = 10 m s-2) (CBSE AI 2013)
Answer:
Given l1 = 12 A, r = 1 mm = 1 × 10-3 m, l2 = 5 A, mass per unit length = ?

The force between the two wires should be repulsive and should balance the weight of the wire CD. Thus the current in wire CD will be opposite to that in wire AB.

The force between the two current¬carrying conductors is given by
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 80

Question 11.
A square loop of side 20 cm carrying a current of I A is kept near an infinitely long straight wire carrying a current of 2 A in the same plane as shown in the figure.
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 81
Calculate the magnitude and direction of the net force exerted on the loop due to the current carrying conductor. (CBSEAI 2015C)
Answer:
Here, PQ = 20 cm = 20 × 10-2 m,
PS = 20 cm = 10 × 10-2 m

Distance of PQ from AB,
r1 = 10 cm = 10 × 10-2 m

Distance of RS from AB,
r2 = (10 + 20) = 30 cm = 30 × 10-2 m
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 82
Current through long wire AB, l1 = 2 A
Current through rectangular loop, l2 = 1 A

Force on the arm PQ,

F1 = \(\frac{\mu_{0} I_{1} I_{2}}{2 \pi a}\) × length PQ

F2 = \(\frac{2 \times 10^{-7} \times 2 \times 1 \times 20 \times 10^{-2}}{10 \times 10^{-2}}\) = 8 × 10-7 N
= 8 × 10-7 N (towards AB)

Force on the arm RS,
F1 = \(\frac{\mu_{0} I_{1} I_{2}}{2 \pi a}\) × length RS

F2 = \(\frac{2 \times 10^{-7} \times 2 \times 1 \times 20 \times 10^{-2}}{30 \times 10^{-2}}\) =2.66 × 10-7

= 2.66 × 10-7 N (away from AB)

Effective force on the Loop,
F= F1 – F2
=8 × 10-7 – 2.66 × 10-7
= 5.34 × 10-7 N (towards AB)

Question 12.
A square-shaped plane coil of area 100 cm2 of 200 turns carries a steady current of 5A. It is placed in a uniform magnetic field of 0.2 T acting perpendicular to the plane of the coil. Calculate the torque on the coil when its plane makes an angle. of 60° with the direction of the field. In which orientation will the coil be in stable equilibrium? (CBSE Al 2015C)
Answer:
Given A= 10-2 m², n = 200, l = 5 A, θ = 60°, B = 0.2 T, τ = ?
Using the expression τ = B I n A sin θ we have
τ = 0.2 × 5 × 200 × 10-2 × sin 60° = 20 Nm
Stable equilibrium, when the magnetic field is in the direction of the coil.

Question 13.
A straight wire of mass 200 g and length 1.5 m carries a current of 2 A. It is suspended in mid-air by a uniform horizontal magnetic field B (figure). What is the magnitude of the magnetic field? (NCERT)
Class 12 Physics Important Questions Chapter 4 Moving Charges and Magnetism 83
Answer:
For the wire to be suspended in mid-air, it must experience an upward force F of magnitude F = B I L to balance its weight W= mg
Therefore, BI L = mg
B = \(\frac{m g}{1 L}=\frac{0.2 \times 9.8}{2 \times 1.5}\) = 0.65 T

Question 14.
A cyclotron’s oscillator frequency is 10 MHz. What should be the operating magnetic field for accelerating proto is? If the radius of its dees is 60 cm what is the kinetic energy (in m MeV) of the proton beam produced by the accelerator (e =1.60 × 10-19 C, mp = 1.67 × 10-27 kg, 1 MeV = 1.6 × 10-13 J) (NCERT)
Answer:
The oscillator frequency should be the same as the proton’s cyclotron frequency, i.e. 10 MHz = 107 Hz.
Therefore
B = \(\frac{2 \pi m v}{q}\)

= \(\frac{2 \times 3.14 \times 1.67 \times 10^{-27} \times 10^{7}}{1.6 \times 10^{-19}}\) = 0.66 T

Final velocity of protons is
V = r × 2πv = 0.6 × 6.3 × 107 = 3.78 × 107 m s-1.

E = 1/2mv² = 1.67 × 10-27 × 14.3 × 1014 / (2 × 1.6 × 10-13) = 7 MeV

Question 15.
A solenoid of length 0.5 m has a radius of 1 cm and is made up of 500 turns. Does it carry a current of 5 A. What is the magnitude of the magnetic field inside the solenoid? (NCERT)
Answer:
Given n = 500/0.5 = 1000 turns per unit length. l = 5 A
The length L = 0.5 m and radius r = 0.01 m. Thus, L/a = 50,
Hence we have
B = μonl = 4π x 10-7 × 1000 × 5 = 6.28 × 10-3 T

Question 16.
A circular coil of wire consisting of 100 turns, each of a radius 8.0 cm, carries a current of 0.40 A. What is the magnitude of the magnetic field B at the center of the coil? (NCERT)
Answer:
Given n = 100, r = 8.0 cm = 8.0 × 10-2 m,
l = 0.40 A,B = ?

Using the expression B = \(\frac{\mu_{0} n l}{2 r}\)
we have
B = \(\frac{\mu_{0} n l}{2 r}=\frac{4 \pi \times 10^{-7} \times 100 \times 0.40}{2 \times 8.0 \times 10^{-2}}\)

Question 17.
A horizontal overhead power line carries a current of 90 Ain the east to west direction. What is the magnitude and direction of the magnetic field due to the current 1.5 m below the line? (NCERT)
Answer:
Given l = 90 A, r = 1.5 m, B = ?
Using the expression B = \(\frac{\mu_{0} l}{2 \pi r}\) we have

B = \(\frac{\mu_{0} l}{2 \pi r}=\frac{4 \pi \times 10^{-7} \times 90}{2 \times \pi \times 1.5}\) = 1.2 × 10-5 T
The magnetic field will be towards the south.

Question 18.
A square coil of side 10 cm consists of 20 turns and carries a current of 12 A The coil is suspended vertically and the normal to the plane of the coil makes an angle of 30° with the direction of a uniform horizontal magnetic field of magnitude 0.80 T. What is the magnitude of torque experienced by the coil? (NCERT)
Answer:
Given L= 10 cm=0.1 m, A = (0.1)² = 0.01 m², n = 20 , l = 12 A, θ = 30°, B = 0.80T, τ = ?

Using the expression τ = B l n A sin θ we have
τ = 0.80 × 12 × 20 × 0.01 × sin 30° = 0.96 Nm

Question 19.
A straight horizontal conducting rod of length 0.45 m and mass 60 g is suspended by two vertical wires at its ends. A current of 5.0 A is set up in the rod through the wires.
(i) What magnetic field should be set up normally to the conductor in order that the tension in the wires is zero?
(ii) What will be the total tension in the wires if the direction of the current is reversed keeping the magnetic field the same as before? (Ignore the mass of the wires.) g = 9.8 ms-2 (NCERT)
Answer:
Given L = 0.45 m, m = 60 g, I = 5.0 A, B = ?
(i) The tension in the wires will be zero if the weight of the rod is balanced by the force on it due to the magnetic field.
Therefore we have
B I L = mg
B = \(\frac{m g}{I L}=\frac{0.06 \times 9.8}{5.0 \times 0.45}\) = 0.26 T

Thus a horizontal magnetic field of magnitude 0.26 T normal to the conductor should be applied in such a direction that Fleming’s left-hand rule gives a magnetic force in the upward direction.

(ii) The tension will become twice the weight of the wire i.e.,
T = B / L + mg = mg + mg = 2 mg
Or
T= 2 × 0.06 × 9.8 = 1.176 N

Question 20.
A galvanometer coil has a resistance of 12 ohms and the meter shows full-scale deflection for a current of 3 mA. How will you convert the meter into a voltmeter of range 0 to 18 V? (NCERT)(CBSE 2019C)
V= 18 V, R = ?
We will connect a resistance R = \(\left(\frac{V}{l_{g}}-G\right)\) in series with the galvanometer.

Therefore R = \(\frac{18}{3 \times 10^{-3}}\) – 12 = 5988 Ω

Question 21.
A galvanometer coil has a resistance of 15 ohms and the meter shows full-scale deflection for a current of 4 mA. How will you convert the meter into an ammeter of range 0 to 6A? (NCERT)
Answer:
Given G = 15 Ω, lg = 4 mA = 4 × 10-3 A, l = 6 A, S = ?

We will connect a resistance S = \(\frac{l_{s} G}{l-l_{s}}\) in parallel with the galvanometer.
Therefore S = \(\frac{4 \times 10^{-3} \times 15}{6-\left(4 \times 10^{-3}\right)}\) = 0.01 Ω
Or
S = 10 mΩ

Electrochemistry Class 12 Important Extra Questions Chemistry Chapter 3

Here we are providing Class 12 Chemistry Important Extra Questions and Answers Chapter 3 Electrochemistry. Class 12 Chemistry Important Questions are the best resource for students which helps in Class 12 board exams.

Class 12 Chemistry Chapter 3 Important Extra Questions Electrochemistry

Electrochemistry Important Extra Questions Very Short Answer Type

Question 1.
Write the name of the cell which Is generally used in hearing aids. Write
the reactions taking place at the anode and the cathode of this cell. (CBSE AI 2017)
Answer:
Mercury cell
Class 12 Chemistry Important Questions Chapter 3 Electrochemistry 1
At Cathode: HgO + H2O + 2e → Hg (I) + 2OH

Question 2.
Write the name of the cell which is generally used in transistors. Write the reactions taking place at the anode and the cathode of this cell. (CBSE Al 2017)
Answer:
Dry cell
Anode: Zn (s) → Zn2+ + 2e
Cathode: MnO2 + NH4+ + e → MnO(OH) + NH3

Question 3.
Write the name of the cell which is generally used in inverters. Write the reactions taking place at the anode and the cathode of this cell. (CBSE Al 2017)
Answer:
Lead storage battery
Anode: Pb (s) + SO42-(aq) → PbSO4(s) + 2e
Cathode: PbO2 + SO42-(aq) + 4H+ + 2e → PbSO4(s) + 2H2O(l)

Question 4.
From the given cells:
Lead storage cell, Mercury cell, Fuel cell and Dry cell Answer the following:
(i) Which cell is used in hearing aids?
(ii) Which cell was used in Apollo Space Programme?
(iii) Which cell is used in automobiles and inverters?
(iv) Which cell does not have long life? (CBSE Delhi 2016)
Answer:
(i) Mercury cell
(ii) Fuel cell
(iii) Lead storage cell
(iv) Dry cell

Question 5.
What happens if external potential applied becomes greater than E°el, of electrochemical cell? (CBSE Al 2016)
Answer:
If E°cell (external) is greater than E°cell, the cell starts acting as an electrolytic cell. In this case, electrical energy is used to carry out non-spontaneous chemical reaction.

Question 6.
Using the E° values of A and B, predict which one is better for coating the surface of iron [E°(Fe2+/Fe) = – 0.44V] to prevent corrosion and why?
Given: E°(A2+|A) = -2.37 V and E°(B2+|B) = – 0.14 V (CBSE Al 2016)
Answer:
‘A’ will prevent iron from rusting. So, we can coat the iron surface with metal A because it has more negative value.

Question 7.
Given that the standard electrode potentials (E°) of metals are:
K+/K = – 2.93V, Ag+/Ag = 0.80V, Cu2+/Cu = 0.34V, Mg2+/Mg = – 2.37V, Cr3+/Cr = – 0.74V and Fe2+/Fe = – 0.44V. (CBSE Al 2010)
Arrange the metals in the increasing order of their reducing power.
Answer:
Ag+/Ag < Cu2+/Cu < Fe2+/Fe < Cr3+/Cr < Mg2+/Mg < K+/K.

Question 8.
What is change in free energy for
(a) galvanic cell and
(b) electrolytic cell?
Answer:
(a) For a galvanic cell, free energy decreases, i.e. ΔG < 0.
(b) For electrolytic cell, free energy increases, i.e. ΔG > 0.

Question 9.
What is role of ZnCl2 in a dry cell?
Answer:
ZnCl2 combines with NH3 produced to form the complex [Zn(NH3)2Cl2], otherwise the pressure developed due to NH3 would crack the seal of the cell.

Question 10.
When the silver electrode having reduction potential 0.80 V is attached to NHE, will it act as anode or cathode?
Answer:
It will act as cathode.

Question 11.
What is the effect of carbon dioxide in water on corrosion?
Answer:
The presence of carbon dioxide in water increases rusting of iron. Water containing CO2 acts as an electrolyte and increases the flow of electrons from one place to another.

Question 12.
Why is it not possible to measure the voltage of an isolated half reaction?
Answer:
It is not possible to measure the voltage of an isolated half reaction because neither the oxidation nor the reduction can occur by itself. Therefore, we can only calculate the relative electrode potential by connecting it to some standard electrode.

Question 13.
Why does a dry cell become dead after a long time, even if it has not been used?
Answer:
A dry cell becomes dead after a long time because the acidic NH4Cl corrodes the zinc container.

Question 14.
Why does the cell potential of mercury cell remain constant throughout its life? (CBSE AI 2015)
Answer:
This is because the overall cell reaction does not involve any ion in the solution whose concentration changes during its life time.

Question 15.
How can you increase the reduction potential of an electrode?
Answer:
By increasing the concentration of the ions

Question 16.
The E° values of MnO4, Ce4+ and Cl2 are 1.507, 1.61 and 1.358 V respectively. Arrange these in order of increasing strength as oxidising agent.
Answer:
Cl2 < MnO4 < Ce4+.

Question 17.
E° values for Fe3+/Fe2+ and Ag+/Ag are respectively 0.771 V and 0.800 V. Is the reaction:
Fe3+ + Ag → Fe2+ + Ag+ spontaneous or not?
Answer:
E° for the reaction is 0.771 – 0.800 = – 0.029 V.
Therefore, the reaction is not spontaneous.

Question 18.
What is the use of platinum foil in the hydrogen electrode?
Answer:
It is used for inflow and outflow of electrons.

Question 19.
What is meant by limiting molar conductivity? (CBSE 2010)
Answer:
The molar conductivity at infinite dilution or when concentration approaches zero is called limiting molar conductivity.

Question 20.
Express the relation among the conductivity of solution in the cell, the cell constant and the resistance of solution in the cell. (CBSE Delhi 2011)
Answer:
The conductivity (K), cell constant (G°) and resistance (R) of the solution are related as:
K = G° × 1/R
Class 12 Chemistry Important Questions Chapter 3 Electrochemistry 3

Question 21.
Explain the relation between conductivity and molar conductivity of a solution held in a ceil. (CBSE Delhi 2011)
Answer:
Conductivity (κ) and molar conductivity are related as:
m = \(\frac{\kappa \times 1000}{M}\)
where M is the molarity of the solution.

Question 22.
Is it safe to stir 1 M AgNO2 solution with a copper spoon?
Given E° (Ag+/Ag) = 0.80 V, E° (Cu2+/Cu) = 0.34 V. Explain.
Answer:
No, copper spoon will dissolve as Cu2+ ions because copper has more tendency to get oxidised than silver.

Question 23.
The e.m.f. of the cell:
Zn | Zn2+ (1M) || H+ (1M) | H2 (1 atm),
Pt is 0.76 V. What is the electrode potential of Zn2+/Zn electrode?
Answer:
cell = E°(H+/H2) – E°(Zn2+/Zn)
0. 76 = 0 – E°(Zn2+/Zn)
∴ E°(Zn2+/Zn) = – 0.76 V.

Question 24.
Write relationship between
(i) standard free energy change and e.m.f. of a cell.
(ii) standard free energy change and equilibrium constant.
Answer:
(i) ∆G° = – nFE°cell
(ii) ∆G° = – RT In Kc

Question 25.
Give the units of specific conductance and molar conductance.
Answer:
Specific conductance: ohm-1 cm-1
Molar conductance: ohm-1 cm2 mol-1

Question 26.
Give one example each of primary cell and secondary cell.
Answer:
Primary cell: Dry cell
Secondary cell: Lead storage battery

Question 27.
How are cell constant and specific conductance related to one another?
Answer:
Specific conductance = Cell constant × Conductance.

Question 28.
Why is the equilibrium constant K related to only E°cell and not Ecell?
Answer:
This is because at equilibrium Ecell = 0.

Question 29.
What is the effect of decreasing concentration on the molar conductivity of weak electrolytes?
Answer:
With the decrease in concentration of weak electrolytes, the molar conductivity increases.

Question 30.
Why is it not possible to determine the potential of a single electrode?
Answer:
Oxidation and reduction cannot occur alone. Therefore, it is not possible to measure single electrode. Moreover, it is a relative tendency and can be measured with respect to a reference electrode only.

Question 31.
Suggest a metal which can be used for cathodic protection of iron?
Answer:
Zinc.

Question 32.
Write the overall cell reaction for lead storage battery.
Answer:
The overall cell reaction is:
Pb (s) + PbO2 (s) + 4H+ (aq) + 2SO42- (aq) → 2PbSO4 (s) + 2H2O.

Electrochemistry Important Extra Questions Short Answer Type

Question 1.
The resistance of a conductivity cell containing 0.001 M KCI solution at 298 K is 1500 Ω. What is the cell constant if the conductivity of 0.001 M KCl solution at 298 K is 0.146 × 10-3 S cm-1? (CBSE AI 2008; CBSE Delhi 2007, 2008, 2012)
Ans.
Conductivity, K = 0.146 × 10-3 S cm-1
Resistance, R = 1500 ohm
Class 12 Chemistry Important Questions Chapter 3 Electrochemistry 3
= Conductivity (κ) × Resistance (R)
∴ Cell constant = 0.146 × 10-3 ohm-1 cm-1 × 1500 ohm = 0.219 cm-1.

Question 2.
The conductivity of 0.20 M KCl solution at 298 K is 0.025 S cm-1. Calculate its molar conductivity.
Answer:
Molar conductivity
m = \(\frac{\kappa \times 1000}{\mathrm{C}}\)
k = 0.025 cm-1, C = 0.20 M
∴ ∧m = \(\frac{0.025 \times 1000}{0.20}\) = 125.0 S cm2 mol-1

Question 3.
Resistance of a conductivity cell filled wIth 0.1 M KCl solution is 100. If the resistance of the same cell when filled with 0.02 M KCl solution is 520Ω, calculate the conductivity and molar conductivity of 0.02 M KCl solution. (The conductivity of 0.1 M KCl solution is 1.29 S m-1.) (CBSE AI 2006, CBSE Delhi 2014)
Answer:
Step 1. Let us first calculate the cell constant.
Cell constant, G* = Conductivity (κ) × Resistance (R)
Resistance of 0.1 M KCl solution = 100 Ω
Conductivity of 0.1 M KCl solution = 1.29 S m-1
∴ Cell constant = 1.29 (S m-1) × 100Ω = 129 m-1
or = 1.29 cm-1

Step II. Calculation of conductivity of 0.02 M KCl soLution.
Resistance of solution = 520 Ω
Cell constant (G*) = 1.29 cm-1
Class 12 Chemistry Important Questions Chapter 3 Electrochemistry 4

Step III. Calculation of molar conductivity.
m = \(\frac{1000 \times \kappa}{C}\)
C = 0.02 M, κ = 0.248 × 10-2 S cm-1
∴ ∧m = \(\frac{1000 \times 0.248 \times 10^{-2}}{0.02}\) – 124 S cm2 mol-1

Question 4.
The electrical resistance of a column of 0.05 M NaOH+ solution of diameter 1 cm and length 50 cm is 5.55 × 103 ohm. Calculate its
(i) resistivity
(ii) conductivity, and
(iii) molar conductivity. (CBSE AI 2012)
Answer:
Cell constant, G* = \(\frac{1}{a}\)
l = 50 cm, diameter = 1 cm
∴ radius = 0.5 cm
Area of cross-section, a = πr2
= 3.14 × (0.5)2 = 0.785 cm2
∴ G* = \(\frac{50}{0.785}\) = 63.694 cm-1

(i) Resistivity,
Class 12 Chemistry Important Questions Chapter 3 Electrochemistry 5

(ii) Conductivity,
κ = \(\frac{1}{\rho}=\frac{1}{87.135}\) = 1.48 × 10-2 cm-1

(iii) Molar conductivity,
m = \(\frac{\kappa \times 1000}{\mathrm{C}}\)
c = 0.05 M
∴ ∧m = \(\frac{1.148 \times 10^{-2} \times 1000}{0.05}\) = 229.6 s cm2 mol-1

Question 5.
The molar conductivities at infinite dilution for sodium acetate, hydrochloric acid and sodium chloride are 91.0, 425.9 and 126.4 S cm2 mol-1 respectively at 298 K. Calculate the molar conductivity of acetic acid at infinite dilution. (CBSE Delhi 2010)
Answer:
Molar conductivity at infinite dilution for acetic acid can be calculated as:
∧° (CH3COOH ) = λ°H+ + ∧°CH3COO
= λCH3COO + λ°Na+ + λ°H+ + λ°cl – λ°Na+ – λ°cl
∧°(CH3COOH+) = ∧°(CH3COONa) + ∧° (H+Cl) – ∧° (NaCl)
∧°(CH3COONa) = 91.0 S cm2 mol-1
∧°(H+Cl) = 425.9 S cm2 mol-1
∧°(NaCl) = 126.4 S cm2 mol-1
∴ ∧°(CH3COOH+) = 91.0 + 425.9 – 126.4 = 390.5 S cm2 mol-1.

Question 6.
(a) Write the reaction that occurs at anode on electrolysis of concentrated H2SO4 using platinum electrodes.
(b) What is the effect of temperature on ionic conductance? (CBSE Al 2019)
Answer:
(a) At anode:
2SO42-(aq) → S2O82-(aq) + 2e
(b) Ionic conductance will increase with increase in temperature.

Question 7.
Write anode and cathode reactions that occur in dry cell. How does a dry cell differ from a mercury cell? (CBSE Al 2019)
Answer:
Anode: Zn → Zn2+ + 2e
Cathode:
NH4+(aq) + MnO2(s) + e → MnO(OH) + NH3
The potential of a dry cell decreases slowly but continuously, while the potential of mercury cell remains constant throughout its life.

Question 8.
Calculate the limiting molar conductivity of CaS04 if limiting molar conductivities of calcium and sulphate ions are 119.0 and 106.0 S cm2 mol-1 respectively. (CBSE Sample Paper 2012)
Answer:
∧°m (CaSO4) = λm (Ca2+) + λ°m (SO42-)
= 119.0 + 106.0
= 225.0 S cm2- mol-1.

Question 9.
Arrange the following solutions in the decreasing order of specific conductance.
(i) 0.01M NaCl (ii) 0.05M NaCl (iii) 0.1M NaCl (iv) 0.5M NaCl
Ans.
(iv) 0.5M NaCl > (iii) 0.1M NaCl > (ii) 0.05M NaCl > (i) 0.01M NaCl

Question 10.
Write the Nernst equation and calculate the e.m.f. of the following cell at 298 K:
Cu(s) | Cu2+ (0.130 M) | | Ag+ (1.0 × 10-4 M)) | Ag (s)
Given: E(Cu2+/Cu) = + 0.34V and E(Ag2+/Ag) = + 0.80V (CBSE Al 2004)
Answer:
The electrode reactions and cell reaction are:
Class 12 Chemistry Important Questions Chapter 3 Electrochemistry 7

Question 11.
Calculate Ecell, for the following reaction at 298K:
2Cr(s) + 3Fe2+ (0.01 M) → 2Cr3+ (0.01M) + 3Fe(s)
(Given: Ecell = 0.261v)                (CBSE AI 2016)
Answer:
Class 12 Chemistry Important Questions Chapter 3 Electrochemistry 8
Class 12 Chemistry Important Questions Chapter 3 Electrochemistry 9

Question 12.
For the reaction:
2AgCl (s) + H2 (g) (1atm) → 2Ag(s) + 2H+ (0.1M) + 2Cl (0.1M)
ΔG° = – 43600 J at 25°C
Calculate the e.m.f of the cell. (CBSE AI 2018)
Answer:
Class 12 Chemistry Important Questions Chapter 3 Electrochemistry 10

Question 13.
Write the name of two fuels other than hydrogen used in fuel cell. Write two advantages of fuel cell over an ordinary cell. (CBSE Al 2019)
Answer:
Methane, oxygen
Advantages of fuel cells:
(i) Fuel cells have greater efficiency than ordinary cells.
(ii) These do not produce any harmful by-product and therefore, do not cause any pollution.

Question 14.
Define conductivity and molar conductivity for the solution of an electrolyte. Why does the conductivity of solution decrease with dilution? (CBSE 2019C)
Answer:
Conductivity of a solution at any given concentration is the conductance of one unit volume of solution kept between two platinum electrodes with unit area of cross section and at a distance of unit length.

Molar conductivity of a solution at a given concentration is the conductance of the volume V of solution containing one mole of electrolyte kept between two electrodes with area of cross section A and distance of unit length. Therefore,
m = \(\frac{\mathrm{κA}}{\mathrm{l}}\)
Since l = 1 and A = V (Volume containing 1 mole of electrolyte).
m = κV
Conductivity always decreases with decrease in concentration both for weak and strong electrolytes. It is because the number of ions per unit volume that carry the current in solution decreases on dilution.

Question 15.
Express the relation among cell constant, resistance of the solution in the cell and conductivity of the solution. How is molar conductivity of a solution related to its conductivity? (CBSE AI 2012)
Answer:
The conductivity (κ), cell constant (G*) and resistance (R) of solution are related as:
Class 12 Chemistry Important Questions Chapter 3 Electrochemistry 11
Molar conductivity (∧m) is related to conductivity (κ) as:
m = \(\frac{\kappa \times 1000}{M}\)

Question 16.
The molar conductivity of a 1.5 M solution of an electrolyte is found to be 138.9 S cm2 mol-1. Calculate the conductivity of this solution. (CBSE AI 2012)
Answer:
m = 138.9 S cm2 mol-1, M = 1.5 M
138.9 = \(\frac{\kappa \times 1000}{1.5}\)
∴ κ = \(\frac{138.9 \times 1.5}{1000}\) = 0.208 ohm-1 cm-1.

Electrochemistry Important Extra Questions Long Answer Type

Question 1.
(a) Following reaction takes place in the cell:
Zn (s) + Ag2O (s) + H2O (l) → Zn2+ (aq) + 2Ag (s) + 20H (aq)
Calculate ΔrG° of the reaction.
[Given: E°(Zn2+/Zn) = – 0.76 V,
(Ag2+/Ag) = 0.80 V, 1 F = 96,500 C mol-1]
Answer:
cell = E°(Ag2+/Ag) – E°(Zn2+/Zn)
= 0.80 – (-0.76) = 1.56V
ΔG° = -nFE°cell          (Here n = 2)
= – 2 × 96500 × 1.56
= – 301080 J mol-1
or = – 301.080 kJ mol-1

(b) How can you determine limiting molar conductivity (∧m°,) for strong electrolyte and weak electrolyte? (CBSE Al 2019)
Answer:
For strong electrolytes ∧m° can be obtained as intercept from the plot of Am vs C-1/2 graph. For weak electrolytes ∧m° can be obtained from Kohlrausch law.

Question 2.
(i) Explain the following:
(a) CO2 is always present in natural water. Explain its effect (increases, stops or no effect) on rusting of iron.
(b) Rusting of iron is quicker in saline water than in ordinary water. Explain.
Answer:
(i) (a) Presence of CO2 in natural water increases rusting of iron. It dissolves in water to form H2CO3 which gives H+ ions. The H+ ions accelerate the process of corrosion.
In rusting of iron, Fe oxidises to Fe2+ ions
Fe (s) → Fe2+ (aq) + 2e (anode)
The released electrons go to the cathode and reduce oxygen in the presence of H+ ions (obtained from H2CO3). The reaction occurs at cathode. Thus, CO2 increases rusting.
O2 (g) + 4H+(aq) + 4e → 2H2O (l)

(b) Rusting of iron is quicker in saline water (salt water) than in ordinary water. This is mainly due to the fact that saline water increases the electrical conduction of electrolyte solution formed on the metal surface. Therefore, rusting becomes more serious problem where salt water is present.

(ii) Discuss electrical protection for preventing rusting of iron pipes in underground water.
Answer:
In this method iron articles which are in contact with water such as underground water pipes are protected from rusting. The article of iron is connected with more active metals like magnesium or zinc. This prevents its tendency to lose electrons and therefore, corrosion is prevented. The cathodes of magnesium of zinc can be fixed to the surface of iron or burned in sub-soil water near by the pipes.

Question 3.
Give the construction and working of hydrogen standard electrode potential?
Answer:
The standard hydrogen electrode consists of platinum wire sealed in a glass tube and has a platinum foil attached to it. The foil is coated with finely divided platinum and acts as platinum electrode. It is dipped into an acid solution containing H+ ions in 1 M concentration (1 M HCl). Pure hydrogen gas at 1 atmosphere pressure is constantly bubbled into the solution at constant temperature of 298 K. The surface of the foil acts as a site for the reaction. This is shown in figure.
The following reactions occur in this half cell depending upon whether it acts as an anode or as a cathode:
Class 12 Chemistry Important Questions Chapter 3 Electrochemistry 12
If S.H.E. acts as anode:
H2(g) → 2H+ + 2e
If S.H.E. acts as cathode:
2H+ + 2e → H2(g)
The electrode potential of an electrode can be determined by connecting this half cell with a standard hydrogen electrode. The electrode potential of the standard hydrogen electrode is taken as zero.

Measurement of the standard electrode potential (E°): The standard electrode potential of a metal electrode is measured with respect to a standard hydrogen electrode. A cell is prepared in which the metal electrode constitutes one half cell and the S.H.E. as the other half cell (anode). The electrons released by the metal in the oxidation half cell are accepted by the H+ ions of the acid in the reduction half cell.
The cell may be represented as:
Pt(s) | H2(g, 1 atm) | H+ (aq, 1 M) || Mn+ (aq, 1M) | M
Now, e.m.f. of cell
e.m.f. = ER – EL
Since the potential of S.H.E. has been fixed to be zero, i.e. EL = 0 so that
e.m.f. = ER – 0
or ER = e.m.f.
From the knowledge of e.m.f. of the cell, the electrode potential of the electrode can be calculated. For example, if we wish to determine the electrode potential of zinc electrode in 1 M solution of ZnSO4, it is combined with S.H.E. The e.m.f. of the cell is found to be – 0.76 V so that
e.m.f. = EL – EL
– 0.76 = ER – 0
or ER = – 0.76 V.

Question 4.
What are fuel cells? Discuss briefly hydrogen-oxygen fuel cell?
Answer:
Fuel cells. These are voltaic cells in which the reactants are fed continuously to the electrodes. These are designed to convert the energy from the combustion of fuel such as H2, CO, CH4, etc. directly into electrical energy. The common example is hydrogen-oxygen fuel cell as described below:
Class 12 Chemistry Important Questions Chapter 3 Electrochemistry 13
Fig. A simple H2 – O2 fuel cell.

In this cell, hydrogen and oxygen are bubbled through a porous carbon electrode into concentrated aqueous sodium hydroxide as shown in figure. The diffusion rates of the gases into the cell are carefully regulated to get maximum efficiency. In the anode compartment hydrogen is oxidised while oxygen in the cathode compartment is reduced. The net reaction is the same as burning of hydrogen and oxygen to form water.
The reactions are given below:
At anode:
2 [H2 (g) + 2OH(aq) → 2H2O (l) + 2e]

At cathode:
O2 (g) + 2H2O (l) + 4e → 4OH(aq)

Overall reaction:
2H2 (g) + O2(g) → 2H2O (l)
The catalysts (Pt, Ag or Co) are also added.
This cell runs continuously as long as the reactants are fed. These fuel cells are more efficient than conventional methods of generating electricity on a large scale by burning hydrogen, carbon fuels because these fuel cells convert the energy of the fuel directly into electricity.
The cell has been used for electric power in the Apollo space programme.

Question 5.
What is corrosion? What are the factors which affect corrosion?
Answer:
Corrosion. It is a process of eating away of metals when exposed to the atmosphere surrounding it. Many metals when exposed to the atmosphere, react with air or water in the environment to form undesirable compound on their surface. In case of iron, the corrosion is called rusting. The red or orange coating that forms on the surface of iron when exposed to air and moisture is called rust. Chemically, rust is a hydrated form of ferric oxide, Fe2O3 . xH2O.
Factors which affect corrosion. The main factors which affect corrosion are:
1. Position of metals in e.m.f. series: The reactivity of a metal depends upon its position in the electrochemical series. More the reactivity of the metal, more will be the possibility of the metal getting corroded.

2. Presence of impurities in metals: The impurities help in setting up a voltaic cell, which increases the speed of corrosion.

3. Presence of electrolytes: Presence of electrolytes in water also increases the rate of corrosion. For example, corrosion of iron in sea water takes place to larger extent than in distilled water.

4. Presence of CO2 in water. Presence of CO2 in natural water increases rusting of iron. Water containing CO2 acts as an electrolyte and increases the flow of electrons from one place to another.

5. Presence of protective coatings. When the iron surface is coated with layers of metals more active than iron, then the rate of corrosion is retarded. For example, coating of zinc on iron prevents rustings.

Question 6.
What type of battery is lead storage battery? Write the anode and the cathode reactions and the overall reaction occurring in a lead storage battery. (CBSE 2011)
Answer:
It is a secondary cell.
Anode reaction:
Pb (s) + SO42- (aq) → PbSO4 (s) + 2e

Cathode reaction:
PbO2 (s) + 4H+ (aq) + SO42- (aq) + 2e → PbSO4 (s) + 2H2O (l)

Overall reaction:
Pb (s) + PbO2 (s) + 2H2S04 → 2PbSO4 (s) + 2H2O (l)

Question 7.
The chemistry of corrosion of iron is essentially an electrochemical phenomenon. Explain the reactions occurring during the corrosion of iron in the atmosphere. (CBSE 2011)
Answer:
The chemistry of corrosion of iron is an electrochemical theory which involves oxidation and reduction reactions. According to this theory it is believed that non-uniform surface of metal or impurities present in iron behave like small electric cells (called corrosion couples) in the presence of water containing dissolved oxygen or carbon dioxide. A film of moisture with dissolved CO2 acts as electrolytic solution covering the metal surface at various places. This is shown in Fig. In these small electrolytic cells, pure iron acts as anode while cathodes are impure portions. The overall rusting involves the following steps:
Oxidation occurs at the anode of each electrochemical cell. Therefore, at each anode iron is oxidised to Fe2+ ions.

At anode:
Fe (s) → Fe2+ (aq) + 2e …… (i)
Thus, the metal atoms in the lattice pass into the solution as ions, leaving electrons on the metal itself. These electrons move towards the cathode region through the metal.

At the cathode of each cell, the electrons are taken up by hydrogen ions (reduction takes place). The H+ ions are obtained either from water or from acidic substance in water:
H2O ⇌ H+ + OH …… (ii)
or CO2 + H2O → H+ + H+CO3 …… (iii)

At cathode:
H+ + e → H+ …… (iV)
Thus, hydrogen atoms on the iron surface reduce dissolved oxygen.
4H + O2 → 2H2O ……..(v)
Therefore, the overall reaction at cathode of different electrochemical cells may be written as:
4H+(aq) + O2 (g) + 4e → 2H2O (l) ……. (vi)
The overall redox reaction may be written by multiplying reaction at anode Eq. (i) by 2 and adding reaction at cathode Eq. (iv) to equalise number of electrons lost and gained, i.e. Oxidation half reaction:
Fe (s) → Fe2+ (aq) + 2e × 2

Reduction half reaction:
4H+(aq) + O2 (g) + 4e → 2H2O (l)

Overall cell reaction:
2Fe (s) + 4H+(aq) + O2 (g) → 2Fe2+(aq) + 2H2O (l)
The ferrous ions are oxidised further by atmospheric oxygen to Fe3+ (as Fe2O3) and form rust
4Fe2+ + O2 (g) + 4H2O → 2Fe2O3 + 8H+
and Fe2O3 + xH2O → Fe2O3. xH2O
The H+ ions produced above are also used for reaction (iv).
Class 12 Chemistry Important Questions Chapter 3 Electrochemistry 14

Mechanism of rusting of air.

Question 8.
State Kohlrausch law of independent migration of ions. Why does the conductivity of a solution decrease with dilution? (CBSE 2014)
Answer:
Kohlrausch law of independent migration of ions states that at infinite dilution when the dissociation is complete, each ion makes a definite contribution towards molar conductivity of the electrolyte irrespective of the nature of the other ion with which it is associated. Kohlrausch law also means that the limiting molar conductivity of an electrolyte is sum of the individual contributions of the ions of the electrolyte.

Conductivity (κ) of the electrolyte solution decreases with dilution because the number of ions per unit volume furnished by an electrolyte decreases with dilution.

Question 9.
(i) Following reactions occur at cathode during the electrolysis of aqueous silver chloride
solution:
Ag+(aq) + e → Ag(s)        E° = + 0.80 V
H+(aq) + e → \(\frac{1}{2}\)H2(g)         E ° = 0.00 V
On the basis of their standard electrode potential (E°) values which reaction is feasible at the cathode and why?
(ii) Define limiting molar conductivity. Why does conductivity of an electrolyte solution decrease with the decrease in concentration? (CBSE Delhi 2015)
Answer:
(i) The reaction, Ag+(aq) + e → Ag(s) (E° = + 0.80 V) is feasible at cathode because its reduction potential is higher than other reaction (H+ + e → \(\frac{1}{2}\) H2; E° = 0.0 V)

(ii) The molar conductivity of the solution when the concentration approaches zero (infinite dilution) is called limiting molar conductivity. Conductivity is the conductance of one centimeter cube of the solution. Upon diluting the solution, the concentration of ions per centimeter cube decreases and hence conductivity decreases with dilution.

Question 10.
(i) Following reactions occur at cathode during the electrolysis of aqueous sodium chloride
solution:
Na+(aq) + e → Na(s)        E° = -2.71V
H+(aq) + e → H2(g)         E ° = 0.00 V
On the basis of their standard reduction electrode potential (E°) values, which reaction is feasible at the cathode and why?
Answer:
(i) The reaction: H(aq) + e → H2(g) (E° = 0.00 V) is feasible at cathode because its reduction
potential is higher than the other electrode reaction.

(ii) Why does the cell potential of mercury cell remain constant throughout its life? (CBSE 2015)
Answer:
The cell potential of mercury cell remains constant because the overall reaction does not involve any ion in the solution whose concentration changes during its life time.

Question 11.
Zinc rod is dipped in 0.01 M solution of zinc sulphate when temperature is 298 K. Calculate the electrode potential of zinc.
(Given: E°zn2+/Zn = – 0.76 V; log 10 = 1) (CBSE 2019 C)
Answer:
Class 12 Chemistry Important Questions Chapter 3 Electrochemistry 15

Question 12.
Write Nernst equation and calculate e.m.f. of the following cells at 298 K:
(i) Mg (s) | Mg2+ (0.001 M) | | Cu2+ (0.0001 M) | Cu (s)
Given: EMg2+/Mg = -2.37 V, ECu2+/Cu = 0.34V
Answer:
(i) The electrode reactions and cell reactions are:
Class 12 Chemistry Important Questions Chapter 3 Electrochemistry 16
Since the reaction involves 2 moles of electrons and therefore, n = 2 and the Nernst equation for the cell at 298 K is:
Class 12 Chemistry Important Questions Chapter 3 Electrochemistry 17
Class 12 Chemistry Important Questions Chapter 3 Electrochemistry 18

(ii) Fe (s) | Fe2+ (0.001 M) | | H+ (1M) | H2 (1 atm) | Pt
Given: EFe2+/Fe = -0.44V (CBSE Delhi 2013)
Answer:
Fes | Fe2+ (0.001 M) || H+ (1 M) | H2 (1 atm) | Pt
The electrode reactions and overall cell reactions are:
Class 12 Chemistry Important Questions Chapter 3 Electrochemistry 20
Since the reaction involves 2 moles of electrons, therefore, n = 2 and the Nernst equation at 298 K
Class 12 Chemistry Important Questions Chapter 3 Electrochemistry 19

(iii) Sn (s) | Sn2+ (0.050 M) | | H+ (0.020 M) | H2 (1 atm) | Pt
Given: ESn2+/Cn = – 0.14V (CBSE Al 2018)
Answer:
The cell is:
Sn(s) | Sn2+(0.050M) | | H+(0.020 M) | H2(1 atm) | Pt
The electrode reactions and cell reactions are:
Class 12 Chemistry Important Questions Chapter 3 Electrochemistry 21
The reaction involves 2 moles of electrons, therefore, n = 2 and the Nernst equation is:
Class 12 Chemistry Important Questions Chapter 3 Electrochemistry 22

Question 13.
(a) The e.m.f. of the following cell at 298 K is 0.1745 V:
Fe (s) | Fe2+ (0.1 M) | | H+ (x M) | H2 (g) (1 bar) | Pt (s)
Given: E°Fe2+Fe = – 0.44 V
Calculate the H+ ions concentration of the solution at the electrode where hydrogen is being produced.
Answer:
(a)
Class 12 Chemistry Important Questions Chapter 3 Electrochemistry 23

(b) Aqueous solutions of copper sulphate and silver nitrate are electrolysed by 1 ampere current for 10 minutes in separate electrolytic cells. Will the mass of copper and silver deposited on the cathode be same or different? Explain your answer.
Answer:
The mass of copper and silver deposited at the cathode will be different.
Faraday’s second law of electrolysis: It states that when same quantity of electricity is passed through different electrolytic solutions connected in series, the weights of the substances produced at the electrodes are directly proportional to their chemical equivalent weights.

For example, when same current is passed through two electrolytic solutions, containing copper sulphate (CuSO4) and silver nitrate (AgNO3) connected in series, the weights of copper and silver deposited are:
Class 12 Chemistry Important Questions Chapter 3 Electrochemistry 24

OR

(a) Calculate the degree of dissociation of 0.0024 M acetic acid if conductivity of this solution is 8.0 × 10-5 S cm-1.
Given λ°H+ = 349.6 S cm2 mol-1; λ°CH3COO = 40.9 S 2 mol-1
Answer:
(a)
Class 12 Chemistry Important Questions Chapter 3 Electrochemistry 25
Electrolyte B is a strong electrolyte.

(b) Solutions of two electrolytes ‘A’ and ‘B’ are diluted. The limiting molar conductivity of ‘B’ increases to a smaller extent while that of ‘A’ increases to a much larger extent comparatively. Which of the two is a strong electrolyte? Justify your answer. (CBSE Sample Paper 2019)
Answer:
Limiting molar conductivity increases only to a smaller extent for a strong electrolyte, as on dilution the interionic interactions are overcome. Limiting molar conductivity increases to a larger extent for a weak electrolyte, as on dilution the degree of dissociation increases, therefore the number of ions in total volume of solution increases. Therefore, ‘B’ is a strong electrolyte.

Question 14.
(i) Calculate E°cell for the following reaction at 298 K:
2Cr(s) + 3Fe2+ (0.01 M) → 2Cr3+ (0.01 M) + 3Fe(s)
Given: Ecell = 0.261 V
Answer:
Class 12 Chemistry Important Questions Chapter 3 Electrochemistry 26

(ii) Using the E° values of A and B, predict which one is better for coating the surface of iron [Ee°Fe2+/Fe) = – 0.44 V] to prevent corrosion and why?
Given: E°(A2+/A) = -2.37 V: E°(B2+/B) = – 0.14 V
Answer:
‘A’ will prevent iron from corrosion. So, we can coat the iron surface with metal A because it has more negative E° value.

OR

(i) The conductivity of 0.001 mol L-1 solution of CH3COOH Is 3.905 × 10-5 S cm-1. Calculate its molar conductivity and degree of dissociation (α).
Given λ°(H+) = 349.65 cm2 mol-1 and λ°(CH3COO) = 40.9 S cm2 mol-1.
Answer:
Class 12 Chemistry Important Questions Chapter 3 Electrochemistry 27

(ii) Define electrochemical cell. What happens if external potential applied becomes greater than E°cell of electrochemical cell? (CBSE 2016)
Answer:
Electrochemical cell is a device used for the production of electricity from energy released during spontaneous chemical reaction. Electrochemical cell converts chemical energy into electrical energy.
If E°cell (external) > E°cell, the cell starts acting as an electrolytic cell. In this case, electrical energy is used to carry out non-spontaneous chemical reaction.

Question 15.
(i) Define the following terms:
(a) Limiting molar conductivity
(b) Fuel cell
(ii) Resistance of a conductivity cell filled with 0.1 mol L-1 KCl solution is 100 Ω. If the resistance of the same cell when filled with 0.02 mol L-1 KCl solution is 520 Ω, calculate the conductivity and molar conductivity of 0.02 mol L-1 KCl solution. The conductivity of 0.1 mol L-1 KCl solution is 1.29 × 10-2-1 cm-1.

OR

(i) State Faraday’s first law of electrolysis. How much charge in terms of Faraday is required for the reduction of 1 mol of Cu2+ to Cu.
(ii) Calculate emf of the following cell at 298 K:
Mg(s) | Mg2+(0.1 M) | | Cu2+(0.01)|Cu(s) [Given E°cell = +2.71 V, 1 F = 96500 C mol-1] (CBSE Delhi 2014)
Answer:
(a) The molar conductivity of a solution when concentration approaches zero is called limiting molar conductivity and is expressed as ∧°m.

(b) Fuel cells are voltaic cells in which the reactants are continously supplied to the electrodes and are designed to convert energy from the combustion of fuels such as H2, CO, CH4, etc. directly into electrical energy.

(ii) Let us first calculate cell constant
Cell constant, G* = Conductivity (κ) × Resistance (R)
Resistance of 0.1 M KCl solution = 100 Ω
Conductivity of 0.1 M KCl solution = 1.29 Sm-1
Cell constant = 1.29 (Sm-1) × 100 Ω
= 129 m-1 = 1.29 cm-1
Calculation of conductivity of 0.02 M KCl solution,
Resistance of solution = 520 Ω
Cell constant (G*) = 1.29 cm-1
Class 12 Chemistry Important Questions Chapter 3 Electrochemistry 28

OR

(i) Faraday’s first law of electrolysis states that the amount of any substance deposited or liberated at any electrode is directly proportional to the quantity of electricity passed through the electrolytic solution.
Cu2+ + 2e → Cu(s)
Reduction of 1 mol of Cu2+ ion requires 2F of electricity.

(ii) The electrode reactions and cell reaction are
Mg(s) → Mg2+(aq) + 2e (at anode)
Cu2+(aq) + 2e → Cu(s) at cathode
Mg(s) + Cu2+(aq) → Mg2+(aq) + Cu(s)
Class 12 Chemistry Important Questions Chapter 3 Electrochemistry 29
= 2.71 – 0.0295
= 2.6805 v.

Question 16.
(i) How many moles of mercury will be produced by electrolysing 1.0 M Hg(NO3)2 solution with a current of 2.00 A for 3 hours? [Hg(NO3)2 = 200.6 g mol-1].
Answer:
Hg2+ + 2e → Hg
Quantity of electricity passed = 1 × t(sec)
= 2.0 A × 3.0 × 60 × 60 = 21 600C
2 × 96500 C of electricity produces mercury = 1 mol
21,600 C of electricity will produce mercury
= \(\frac{1}{2 \times 96500}\) × 21600 = 0.112 mol

(ii) A voltaic cell is set up at 25° C with the following half cells:
Al3+ (0.001 M) and Ni2+ (0.50 M).
Write an equation for the reaction that occurs when the cell generates an electric current and determine the cell potential.
(Given: E°Ni2+/Ni = – 0.25 V, E°Ni2+/Ni = – 1.66V) (CBSE 2011)
Answer:
Cell reaction is:
Class 12 Chemistry Important Questions Chapter 3 Electrochemistry 30

Question 17.
(i) What type of battery is lead storage battery? Write the anode and cathode reactions and the overall cell reaction occurring in the operation of a lead storage battery.
Answer:
It is secondary cell.
Anode reaction:
Pb (s) + SO42-(aq) → PbSO4(s) + 2e

Cathode reaction:
PbO2 (s) + 4H+(aq) + SO42-(aq) + 2e → PbSO4(s) + 2H2O (l)

Overall reaction:
Pb (s) + PbO2 (s) + 2H2SO4 → PbSO4(s) + 2H2O (l)

(ii) Calculate the potential for half cell containing 0.1 M K2Cr2O7(aq), 0.20 M Cr3+(aq) and 1.0 × 10-4 M H+(aq). The half cell reaction is
Cr2O72-(aq) + 14 H+(aq) + 6e → 2Cr3+(aq) + 7H2O(l),
and the standard electrode potential is given as E° = 1.33 V. (CBSE 2011)
Answer:
Class 12 Chemistry Important Questions Chapter 3 Electrochemistry 31
Class 12 Chemistry Important Questions Chapter 3 Electrochemistry 32

Question  18.
(i) State Kohlrausch law of independent migration of ions. Write an expression for the molar conductivity of acetic acid at infinite dilution according to Kohlrausch law.
Answer:
Kohlrausch law states that at infinite dilution, each ion makes a definite contribution towards molar conductivity of the electrolyte irrespective of the nature of the other ion with which it is associated. This means that the molar conductivity at infinite dilution for a given salt can be expressed as the sum of the individual contributions from the ions of the electrolyte.

For acetic acid, limiting molar conductvity at infinite dilution can be written as:
∧°(CH3COOH) = λ° (CH3COO) + λ° (H+) ……. (i)
This equation can be obtained by the knowledge of molar conductivity at infinite dilution for some electrolytes. For example, consider the strong electrolytes HCl, NaCl and CH3COONa. From Kohlrausch’s law:
∧°(CH3COONa) = λ°(CH3COO) + A°(Na+) …… (i)
∧°(HCl) = λ°(H+) + λ°(Cl) …….. (ii)
∧° (NaCl) = λ° (Na+) + λ° (Cl) …….. (iii)
It is clear that
λ° (CH3COO) + λ° (H+) = [λ°(CH3COO) + A°(Na+)] + [λ°(H+) + λ°(Cl)] – λ° (Na+) + λ° (Cl)
∧°(CH3COOH) = ∧°(CH3COONa) + ∧°(HCl) – ∧° (NaCl)

(ii) Calculate ∧°m for acetic acid
Given that ∧°m(HCl) = 426 S cm2 mol-1
∧°m(NaCl) = 126 S cm2 mol-1
∧°m(CH3COONa) = 91 S cm2 mol-1 (CBSE Delhi 2010)
Answer:
We know
∧°(CH3COOH) = ∧°(CH3COONa) + ∧°(HCl) – ∧° (NaCl)
= 91 + 426 – 126 = 391 S cm2 mol-1

Question 19.
cell for the given redox reaction is 2.71 V.
Mg(s) + Cu2+(0.01 M) → Mg2+(0.001 M) + Cu(s)
Calculate Ecell for the reaction. Write the direction of flow of current when an external opposite potential applied is
(i) less than 2.71 V and
(ii) greater than 2.71 V
Answer:
Mg(s) + Cu2+(0.01 M) → Mg2+(0.001M) + Cu(s)
Class 12 Chemistry Important Questions Chapter 3 Electrochemistry 35
= 2.71 – 0.0295 log 10-1
= 2.71 + 0.0295
= 2.7395 V or approximately 2.74 V
(i) When Eext < 2.71, current flows from Cu to Mg
(ii) When Eext > 2.71, current flows from Mg to Cu.

OR

(a) A steady current of 2 amperes was passed through two electrolytic cells X and Y connected in series containing electrolytes FeS04 and ZnS04 until 2.8 g of Fe deposited at the cathode of cell X. How long did the current flow? Calculate the mass of Zn deposited at the cathode of cell Y. (Molar mass: Fe = 56 g mol-1, Zn = 65.3 g mol-1, 1F = 96500 C mol-1)
(b) In the plot of molar conductlvtty (∧m) vs square root of concentration (c1/2), the following curves are obtained for two electrolytes A and B:
Class 12 Chemistry Important Questions Chapter 3 Electrochemistry 34
Answer the following:
(i) Predict the nature of electrolytes A and B.
(ii) What happens on extrapolation 0f ∧m to concentration approaching zero for electrolytes A and B? (CBSE Delhi 2019)
Answer:
(a) Cell-X contains FeSO4
FeSO4(aq) → Fe2+ + SO42-
Fe2+ + 2e → Fe (at cathode)
1 mole or 56g of Fe is deposited by 2 × 96500C
2.8g of Fe with be deposited by= 2 × 96500 × 2.8
= 9650 C
Q = I × t
9650 = 2 × t
or t = \(\frac{9650}{2}\) = 4825s
In cell Y
1 mol or 65.3 g of Zn is deposited by 2 × 96500 C
or 2 × 96500 C of electricity will deposit Zn = 65.3 g
9650 C of electricity will deposit Zn = \(\frac{65.3 \times 9650}{2 \times 96500}\) = 3.265 g

(b) (i) Electrolyte A is strong electrolyte.
(ii) Electrolyte B is weak electrolyte.
(iii) For A, the intercept will give ∧°m.
For B, we cannot obtain ∧°m on extrapolation.

Question 20.
(i) Define molar conductivity of a solution and explain how molar conductivity changes with change in concentration of solution for a weak and a strong electrolyte.
Answer:
Molar conductivity is the conducting power of all the ions produced by dissolving one gram mole of an electrolyte in solution. It is expressed as ∧m and is defined as:
m = \(\frac{\kappa \times 1000}{M}\)
where M is the molarity of the solution. Its units are ohm-1 cm2 mol-1.
The molar conductance of an electrolytic solution decreases with increase in concentration. For weak electrolytes, molar conductivity increases sharply with dilution. On the other hand, for strong electrolytes, molar conductivity increases slowly with dilution.

For weak electrolytes, the increase in molar conductivity is due to increase in degree of ionisation with dilution. For strong electrolytes, the increase in molar conductance with dilution is because of decrease in interactions between ions with dilution. The decrease in molar conductivity for weak electrolyte (CH3COOH) and strong electrolyte (KCl) is shown below:
Class 12 Chemistry Important Questions Chapter 3 Electrochemistry 33

(ii) The resistance of a conductivity cell containing 0.001 M KCl solution at 298 K is 1500 Ω. What is the cell constant if the conductivity of 0.001 M KCl solution at 298 K is 0.146 × 10-3 S cm-1 ? (CBSE Delhi 2012)
Answer:
R = 1500 Ω
Molarity = 0.001 M
K = 0.146 × 10-3S cm-1
\(\frac{1}{A}\) = ?
Conductivity (κ) = Conductance (G) × Cell Constant \(\left(\frac{1}{A}\right)\)
or κ = \(\frac{1}{R} \times \frac{l}{A}\)
or Cell constant \(\frac{1}{A}\) = R × κ
= 1500 Ω × 0.146 × 10-3S cm-1
\(\frac{1}{A}\) = 0.219 cm-1

Question 21.
(i) What type of a battery is the lead storage battery ? Write the anode and the cathode reactions and the overall reaction occurring in a lead storage battery when current is drawn from it.
Answer:
It is secondary cell.
Anode reaction:
Pb (s) + SO42-(aq) → PbSO4(s) + 2e

Cathode reaction:
PbO2 (s) + 4H+(aq) + SO42-(aq) + 2e → PbSO4(s) + 2H2O (l)

Overall reaction:
Pb (s) + PbO2 (s) + 2H2SO4 → PbSO4(s) + 2H2O (l)

(ii) In the button cell, widely used in watches, the following reaction takes place
Zn(s) + Ag2O(s) + H2O(l) → Zn2+(aq) + 2Ag(s) + 2OH(aq)
Determine E° and ∆G° for the reaction.
(given: E°Ag2+/Ag = + 0.80V, E°Zn2+/Zn = – 0.76V)
Answer:
Ag2+/Ag = + 0.80V, E°Zn2+/Zn = – 0.76V
cell = E°Ag2+/Ag – E°Zn2+/Zn
cell = + 0.80 – (- 0.76) = 1.56 V
ΔG° = – nFE°
n = 2, F = 96500 C
∴ ΔG° = – 2 × 96500 × 1.56
= – 301080 J = – 301.08 kJ

Solutions Class 12 Important Extra Questions Chemistry Chapter 2

Here we are providing Class 12 Chemistry Important Extra Questions and Answers Chapter 2 Solutions. Class 12 Chemistry Important Questions are the best resource for students which helps in Class 12 board exams.

Class 12 Chemistry Chapter 2 Important Extra Questions Solutions

Solutions Important Extra Questions Very Short Answer Type

Question 1.
What is meant by reverse osmosis? (CBSE 2011)
Answer:
The direction of osmosis can be reversed if a pressure larger than the osmotic pressure is applied to the solution side through the semi-permeable membrane.

Question 2.
Define an ideal solution and write one of its characteristics. (CBSE Delhi 2014)
Answer:
An ideal solution may be defined as the solution which obeys Raoult’s law exactly over the entire range of temperature and pressure. For ideal solution

  • Heat of mixing is zero
  • Volume change of mixing is zero.

Question 3.
(i) Write the colligative property which is used to find the molecular mass of macromolecules.
(ii) In non-ideal solution, what type of deviation shows the formation of minimum boiling azeotropes? (CBSE Delhi 2016)
Answer:
(i) Osmotic pressure
(ii) Minimum boiling azeotropes show positive deviation from Raoult’s law.

Question 4.
What is the relation between normality and molarity of a given solution of sulphuric acid?
Answer:
Normality = 2 × Molarity.

Question 5.
Given below is the sketch of a plant for carrying out a process.
Class 12 Chemistry Important Questions Chapter 2 Solution 1
(i) Name the process occurring in the above plant.
(ii) To which container does the net flow of solvent take place?
(iii) Name one SPM which can be used in this plant.
(iv) Give one practical use of the plant. (CBSE Sample Paper 2007)
Answer:
(i) Reverse osmosis
(ii) To fresh water container
(iii) Film of cellulose acetate
(iv) This can be used as a desalination plant to meet potable water requirements.

Question 6.
A and B liquids on mixing produce a warm solution. Which type of deviation from Raoult’s law is there? (CBSE Sample Paper 2011)
Answer:
Negative deviation.

Question 7.
Define ebullioscopic constant. (CBSE AI 2011)
Answer:
Ebullioscopic constant is the elevation in boiling point of a solution containing 1 mole of solute dissolved in 1000 g of the solvent.

Question 8.
What are isotonic solutions?
Answer:
The solutions having same osmotic pressure at the same temperature are called isotonic solutions. These have equimolar concentrations at same temperature.

Question 9.
Some liquids on mixing form ‘azeotropes’. What are ‘azeotropes’?
Answer:
The solutions (liquid mixtures) which boil at constant temperature and can distil unchanged in composition are called azeotropes or azeotropic mixtures.

Question 10.
Define‘colligative properties’
Answer:
Colligative properties are those properties of solutions which depend only on the number of solute particles and not on the nature of the solute.

Question 11.
Define ‘Molality (m)’.
Answer:
Molality is the number of moles of solute dissolved per 1000 g (or 1 kg) of the solvent.

Question 12.
Define ‘Ideal solution’.
Answer:
The solutions which obey Raoult’s law over the entire range of concentration are called ideal solutions.

Question 13.
Define ‘Abnormal molar mass’.
Answer:
Molar mass of a substance, calculated based on its colligative properties, may not be correct if the solute particles undergo dissociation or association in the solution. Molar mass thus calculated is called abnormal molar mass.

Solutions Important Extra Questions Short Answer Type

Question 1.
State Raoult’s law for a solution containing volatile components. Write two characteristics of the solution which obeys Raoult’s law at all concentrations. (CBSE Delhi 2019)
Answer:
Raoult’s law states that at a given temperature, the partial vapour pressure of any volatile component of a solution is equal to the product of the vapour pressure of the pure component and its mole fraction in the solution.

  • No heat is evolved or absorbed when these components are mixed to form a solution.
  • Volume of the solution is exactly same as the sum of the volumes of the components.

Question 2.
Define the terms ‘osmosis’ and ‘osmotic pressure’. What is the advantage of using osmotic pressure as compared to other colligative properties for the determination of molar masses of solutes in solutions? (CBSE 2010)
Answer:
The flow of solvent from solution of low concentration to higher concentration through a semipermeable membrane is called osmosis.
The excess pressure which must be applied to a solution to prevent the passage of solvent through a semi-permeable membrane is called osmotic pressure. Osmotic pressure measurement is preferred over all other colligative properties because
1. even in dilute solutions, the osmotic pressure values are appreciably high and can be measured accurately.
2. osmotic pressure can be measured at room temperature. On the other hand, elevation in boiling point is measured at high temperature where the solute may decompose. The depression in freezing point is measured at low temperatures.

Question 3.
State the following:
(i) Raoult’s law in its general form in reference to solutions.
(ii) Henry’s law about partial pressure of a gas in a mixture. (CBSE 2011)
Answer:
(i) For a solution of volatile liquids, at a given temperature, the partial vapour pressure of each component in solution is equal to the product of vapour pressure of the pure component and its mole fraction.

(ii) Henry’s law states that the mass of a gas dissolved per unit volume of the solvent at a constant temperature is directly proportional to the pressure of the gas in equilibrium with the solution.

Question 4.
The experimentally determined molar mass for what type of substances is always lower than the true value when water is used as solvent? Explain. Give one example of such a substance and one example of a substance which does not show a large variation from the true value. (CBSE Sample Paper 2019)
Answer:
Ionic compounds when dissolved in water dissociate into cations and anions. When there is dissociation of solute into ions, in dilute solutions, the number of particles increases if we ignore the interionic interactions.

As the value of the colligative properties depends on the number of particles of the solute, the experimentally observed value of colligative property will be higher than the true value. Therefore the experimentally determined molar mass is always lower than the true value.

If we dissolve KCl in water, the experimentally determined molar mass is always lower than the true value. Glucose (non-electrolyte) does not show a large variation from the true value.

Question 5.
What mass of ethylene glycol (molar mass = 62.0 g mol-1) must be added to 5.50 kg of water to lower the freezing point of water from 0 to – 10.0°0 (kf for water = 1.86 K kg mol-1). (CBSE 2010)
Answer:
ΔTf = \(\frac{\mathrm{K}_{f} \times 1000 \times \mathrm{w}_{\mathrm{B}}}{\mathrm{w}_{\mathrm{A}} \times \mathrm{M}_{\mathrm{B}}}\)
Kf = 1.86 K kg mol-1, wA = 5.50 kg = 5500 g
WB = ?
MB = 62.0 g/mol, ΔTf = 0 – (- 10) = 10°C
10 = \(\frac{1.86 \times 1000 \times w_{B}}{5500 \times 62}\)
WB = \(\frac{10 \times 5500 \times 62}{1.86 \times 1000}\) = 1833.3 g = 1.833 kg

Question 6.
15.0 g of an unknown molecular material was dissolved in 450 g of water. The resulting solution was found to freeze at – 0.34°C. What is the molar mass of this material? (kf for water = 1.86 K kg mol-1) (CBSE Delhi 2012)
Answer:
Molecular mass, MB is
MB = \(\frac{\mathrm{K}_{f} \times \mathrm{w}_{\mathrm{B}} \times 1000}{\mathrm{w}_{\mathrm{A}} \times \Delta \mathrm{T}_{f}}\)
ΔTf = 0 – (- 0.34) = 0.34°,
Kf = 1.86 K Kg mol-1, wB = 15.0 g, WA = 450 g
MB = \(\frac{1.86 \times 15.0 \times 1000}{450 \times 0.34}\) = 182.3 g/mol

Question 7.
State Henry’s law and write its two applications. (CBSE Delhi 2019)
Answer:
Henry’s law states that the mole fraction of the gas in the solution is directly proportional to the partial pressure of the gas over the solution.
P = KH.X
Applications of Henry’s law

  • In the production of carbonated beverages.
  • In deep sea diving (scuba diving)

Question 8.
A solution of glycerol (C3H8O3) in water was prepared by dissolving some glycerol in 500 g of water. This solution has a boiling point of 100.42°C while pure water boils at 100°C. What mass of glycerol was dissolved to make the solution?
(Kb for water = 0.512 K kg mol-1)         (CBSE Delhi 2012, CBSE AI 2012)
Answer:
Elevation in boiling point
Tb = \(\frac{\mathrm{K}_{b} \times 1000 \times \mathrm{w}_{\mathrm{B}}}{\mathrm{w}_{\mathrm{A}} \times \mathrm{M}_{\mathrm{B}}}\)
ΔTb = 100.42 – 100 = 0.42°, wA = 500 g
wA = ?, Kb = 0.512 k Kg mol-1
MB = 3 × 12 + 8 × 1 + 3 × 16 = 92 g/mol
0.42 = \(\frac{0.512 \times 1000 \times w_{B}}{92 \times 500}\)
or wB = \(\frac{0.42 \times 500 \times 92}{0.512 \times 1000}\)
= 37.33 g
Mass of glycerol to be added = 37.33 g

Question 9.
A solution prepared by dissolving 1.25 g of oil of winter green (methyl salicylate) in 99.0 g of benzene has a boiling point of 80.31°C. Determine the molar mass of this compound. (B.P. of pure benzene = 80.10°C and Kb for benzene = 2.53 °C kg mol-1) (CBSE Delhi 2010)
Answer:
Class 12 Chemistry Important Questions Chapter 2 Solution 2
kb = 2.53°C kg mol-1
wA = 99.0 g, wB = 1.25 g
MB = \(\frac{2.53 \times 1000 \times 1.25}{0.21 \times 99.0}\)
= 152.1 g mol-1

Question 10.
18 g of glucose, C6H12O6 (molar mass = 180 g mol-1), is dissolved in 1 kg of water in a sauce pan. At what temperature will this solution boil?
(Kb for water = 0.52 K kg mol-1, boiling point of pure water = 373.15 K). (CBSE Delhi 2013)
Answer:
ΔTb = \(\frac{\mathrm{K}_{b} \times 1000 \times \mathrm{w}_{\mathrm{B}}}{\mathrm{w}_{\mathrm{A}} \times \mathrm{M}_{\mathrm{B}}}\)
wB = 18 g, wA = 1000 g, MB = 180 g/mol,
Kb = 0.52 K kg mol-1
∴ ΔTb = \(\frac{0.52 \times 1000 \times 18}{1000 \times 180}\) = 0.052 K
Boiling point of solution
= 373.15 + 0.052 = 373.202 K.

Question 11.
A solution containing 15 g urea (molar mass = 60 g mol-1) per litre of solution in water has the same osmotic pressure (isotonic) as a solution of glucose (molar mass = 180 g mol-1) in water. Calculate the mass of glucose present in one litre of its solution. (CBSE Al 2014)
Answer:
For isotonic solutions,
π (urea) = π (glucose)
Class 12 Chemistry Important Questions Chapter 2 Solution 3

Question 12.
A 1.00 molal solution of trichloroacetic acid (CCl3COOH) is heated to its boiling point. The solution has the boiling point of 100.18°C. Determine the van’t Hoff factor for trichloroacetic acid (Kb for water = 0.512 K kg mol-1). (CBSE Delhi 2012)
Answer:
Observed boiling point elevation,
ΔTb = 100.18 – 100.0 = 0.18°C
Molality of solution = 1.00 m
Calculated boiling point elevation,
ΔTb(calc.) = Kb × m
= 0.512 × 1 = 0.512
van’t Hoff factor,
Class 12 Chemistry Important Questions Chapter 2 Solution 4

Question 13.
Blood cells are isotonic with 0.9% sodium chloride solution. What happens if we place blood cells in a solution containing
(i) 1.2% sodium chloride solution?
(ii) 0.4% sodium chloride solution? (CBSE AI 2016)
Answer:
(i) 1.2% sodium chloride solution is hypertonic with respect to 0.9% sodium chloride solution or blood cells. When blood cells are placed in this solution, water flows out of the cells and they shrink due to loss of water by osmosis.

(ii) 0.4% sodium chloride solution is hypotonic with respect to 0.9% sodium chloride solution or blood cells. When blood cells are placed in this solution, water flows into the cells and they swell.

Question 14.
1.00 g of non-electrolyte solute dissolved in 50 g of benzene lowered the freezing point of benzene by 0.40 K. Find the molar mass of the solute.
(Kf for benzene = 5.12 K kg mol-1). (CBSE AI 2013)
Answer:
Class 12 Chemistry Important Questions Chapter 2 Solution 5

Question 15.
(a) Out of 0.1 molal aqueous solution of glucose and 0.1 molal aqueous solution of KCI, which one will have higher boiling point and why?
Answer:
(a) 0.1 m KCI solution will have higher boiling point. This is because KCl dissociates in water to give two ions (K+ and Cl) whereas glucose does not dissociate. Therefore, number of solute particles is greater in 0.1 m KCl as compared to 0.1 m glucose.

(b) Predict whether van’t Hoff factor
(i) is less than one or greater than one in the following:
(i) CH3COOH dissolved in water
(ii) CH3COOH dissolved in benzene (CBSE AI 2019)
Answer:
(i) i > 1 because CH3COOH dissociates in water.
(ii) i < 1 because CH3COOH associates in benzene.

Question 16.
Urea forms an ideal solution in water. Determine the vapour pressure of an aqueous solution containing 10% by mass of urea at 40°C. (Vapour pressure of water at 40°C = 55.3 mm of Hg) (CBSE AI 2006)
Answer:
wA = 90 g. wB = 10 g
Class 12 Chemistry Important Questions Chapter 2 Solution 6
55.3 – pA = 1.84
∴ pA = 53.46 mm Hg

Question 17.
A solution of chloroform and acetone is an example of maximum boiling azeotrope. Why? (CBSE Sample Paper 2012)
Answer:
The solution of chloroform and acetone has lower vapour pressure than ideal solution because of stronger interactions between chloroform and acetone molecules. As a result, total vapour pressure becomes less than the corresponding ideal solution of same composition (i.e. negative deviations). Therefore, the boiling points of solutions are increased and form maximum boiling azeotropes.

Question 18.
A solution of glucose (C6H12O6) in water is labelled as 10% by weight. What would be the molality of the solution? (CBSEAI 2013)
Answer:
10% by weight means that 10 g of glucose is present in 100 g of solution.
Mass of solvent = 100 – 10 = 90 g 10
Moles of glucose = \(\frac{10}{180}\) = 0.0556 moles
Molality = \(\frac{0.0556}{90}\) × 1000
= 0.618 m.

Question 19.
What is meant by positive deviations from Raoult’s law? Give an example. What is the sign of Δmix H for positive deviation?
OR
Define azeotropes. What type of azeotrope is formed by positive deviation from Raoult’s law? Give an example. (Delhi 2015)
Answer:
When the observed vapour pressure of a liquid solution is higher than the value expected from Raoult’s law, it is called positive deviation from Raoult’s law.
Ptotal > P°A XA + P°B XB
for the two components A and B.
Example: Ethyl alcohol and cyclohexane
ΔHmix is positive.
OR
Liquid mixtures which boil at constant temperature and can distil unchanged in composition are called azeotropes.
The mixture which shows positive deviation from Raoult’s law forms minimum boiling azeotrope.
Example: A mixture of ethanol and water containing 95.4% ethanol forms minimum boiling azeotrope.

Question 20.
Write two differences between an ideal solution and a non-ideal solution. (CBSE Delhi 2019)
Answer:

Ideal solutionNon-ideal solution
(i) Each component of solution obeys Raoult’s Law at all temperatures and concentrations.(i) Their components do not obey Raoult’s law.
(ii) There is no enthalpy change on mixing.
Δmixing H = 0
(ii) There is enthalpy change on mixing.
Δmixing H ≠ 0

Question 21.
Define an ideal solution and write one of its characteristics. (CBSE 2014)
Answer:
An ideal solution may be defined as the solution which obeys Raoult’s law exactly over the entire range of temperature and pressure. For ideal solution

  • Heat of mixing is zero
  • Volume change of mixing is zero.

Question 22.
State Henry’s law. What is the effect of temperature on the solubility of a gas in a liquid? (CBSE 2014)
Answer:
Henry’s law states that the mass of a gas dissolved per unit volume of the solvent at a constant temperature is directly proportional to the pressure of the gas in equilibrium with the solution.

The solubility of a gas decreases with increase in temperature. However, it may be noted that there are certain gases like hydrogen and inert gases whose solubility increases slightly with increase in temperature especially in non-aqueous solvents such as alcohols, acetone, etc.

Question 23.
State Raoult’s law for the solution containing volatile components. What is the similarity between Raoult’s law and Henry’s law? (CBSE 2014)
Answer:
Raoult’s law states that at a given temperature for a solution of volatile liquids, the partial vapour pressure of each component in solution is equal to the product of the vapour pressure of pure component and its mole fraction.
Similarity between Raoult’s law and Henry’s law

  • Both Raoult’s law and Henry’s law apply to volatile component in solution. .
  • Both laws state that the vapour pressure of one component is proportional to the mole fraction of that component.

Solutions Important Extra Questions Long Answer Type

Question 1.
Calculate the freezing point of a solution containing 0.5 g KCI (Molar mass = 74.5 g/ mol) dissolved in 100 g water, assuming KCI to be 92% ionised. Kf of water = 1.86 K kg / mol. (CBSE Sample Paper 2019)
Answer:
Let us consider one mole of KCI whose degree of dissociation is α. The dissociation of KCI can be represented as:
KCI → K+ + Cl
1 – α       α      α
Total number of moles after dissociation
= 1 – α + α + α
= 1 + α
Hence i = \(\frac{1+\alpha}{1}\)
If the solute dissolves in the solvent giving n ions, then here n = 2
i = 1 + (n -1) α
= 1 + (2 – 1) α = 1 + α
Now, ∆Tf = i Kfm
= (1 + 0.92) × 1.86 × \(\frac{0.5 \times 1000}{74.5 \times 100}\)
∆Tf = 0.24
∆Tf = T°f – T’f = 0 – 0.24
T’f = -0.24°C

Question 2.
State Henry’s law. Why do gases always tend to be less soluble in liquids as the temperature is raised?
OR
State Raoult’s taw for the solution containing volatile components. Write two differences between an ideal solution and a non-ideal solution. (CBSE Delhi 2015)
Answer:
Henry’s law states that the mass of a gas dissolved per unit volume of the solvent is directly proportional to the pressure of the gas in equilibrium with the solution.

If m is the mass of the gas dissolved in a unit volume of the solvent and p is the pressure of the gas in equilibrium with the solution, then
m ∝ p
or m = K.p
(where K is the proportionality constant) or “partial pressure of the gas in its vapour phase (p) is directly proportional to the mole fraction of the gas (x) in the solution”.
P = KH.X
The dissolution of a gas in a liquid is exothermic process. Therefore, in accordance with Le Chatelier’s principle, with increase in temperature, the equilibrium shifts in the backward direction. As a result, solubility decreases with increase in temperature.
OR
Raoult’s law states that for a solution of volatile liquids, the partial vapour pressure of each component in solution is equal to the product of the vapour pressure of the pure component and its mole fraction. For a binary solution of two components A and B,
PA = PA° × XA
PB = PB° × XB
Differences between ideal and non-ideal solutions

Ideal solution Non-ideal solution

Ideal solutionNon-ideal solution
1. It obeys Raoult’s law over the entire range of concentration of solution.1. It does not obey Raoult’s law.
2. Solute-solvent interactions are nearly same as in pure solvent.2. Solute-solvent interactions are not same as solute-solute or solvent-solvent interactions.

Question 3.
Calculate the amount of KCI which must be added to 1 kg of water so that the freezing point is depressed by 2 K. (Kf for water = 1.86 K kg mol-1) (CBSE Delhi 2012)
Answer:
ΔTf = 2 K
KCl ⇌ K+ + Cl
i = 2
Kf = 1.86 K kg mol-1
wA = 1 kg = 1000 g
MB = (39 + 35.5) = 74.5 g
wB = ?
Class 12 Chemistry Important Questions Chapter 2 Solution 7

Question 4.
What mass of NaCl must be dissolved in 65.0 g of water to lower the freezing point of water by 7.50°C? The freezing point depression constant (Kf) for water is 1.86°C/m. Assume van’t Hoff factor for NaCl is 1.87 (Molar mass of NaCI = 58.5 g mol-1). (CBSE 2011)
Answer:
Lowering in freezing point,
ΔTf = 7.50°C
Kf = 1.86 °C/m,
Mass of water, WA = 65.0 g
Molar mass of NaCl, MB = 58.5 g
Mass of NaCl, WB = ?
van’t Hoff factor, i = 1.87
Class 12 Chemistry Important Questions Chapter 2 Solution 8

Question 5.
Determine the osmotic pressure of a solution prepared by dissolving 2.5 × 10-2 g of K2SO4 in 2 L of water at 25°C, assuming that it is completely dissociated. (CBSE Delhi 2013)
(R = 0.0821 L atm K-1 mol-1, Molar mass of K2SO4 = 174 g mol-1)
Answer:
Since K2SO4 dissociates completely,
K2SO4 → 2K+ + SO42-
One mole of K2SO4 will give 3 mole particles and therefore, the value of ‘i’ is 3.
Osmotic pressure, π = iCRT
= i\(\frac{\mathrm{W}_{\mathrm{B}}}{\mathrm{M}_{\mathrm{B}} \times \mathrm{V}}\)RT
WB = 2.5 × 10-2 g, V = 2.0 L, MB = 174 g/mol
R = 0.821 L atm mol-1 K-1
∴ π = \(\frac{3 \times 2.5 \times 10^{-2} \times 0.0821 \times 298}{174 \times 2.0}\)
= 5.27 × 10-3 atm

Question 6.
Calculate the mass of compound (molar mass = 256 g mol-1) to be dissolved in 75 g of benzene to lower its freezing point by 0.48 K (Kf = 5.12 K kg mol-1). (CBSE Delhi 2014)
Answer:
ΔTf = 0.48 K, Kf = 5.12 K kg mol-1
M = 256 g mol-1, wA = 75g, wB = ?
Class 12 Chemistry Important Questions Chapter 2 Solution 9

Question 7.
3.9 g of benzoic acid dissolved in 49 g of benzene shows a depression in freezing point of 1.62 K. Calculate the van’t Hoff factor and predict the nature of solute (associated or dissociated).
(Given: Molar mass of benzoic acid = 122 g mol-1, Kf for benzene = 4.9 K kg mol-1) (CBSE Delhi 2015)
Answer:
ΔTf = i Kf × m
= \(\frac{i \times K_{f} \times W_{2} \times 1000}{M_{2} \times W_{1}}\)
W2 = 3.9 g, W1 = 49 g, ΔTf = 1.62 K,
M2 = 122 g mol-1
Kf = 4.9 K kg mol-1
1.62 = \(\frac{i \times 4.9 \times 3.9 \times 1000}{122 \times 49}\)
or i = \(\frac{1.62 \times 122 \times 49}{4.9 \times 3.9 \times 1000}\) = 0.506
Since i is less than 1, the solute is associated.

Question 8.
A solution of glucose (molar mass = 180 g mol-1) in water is labelled as 10% by mass. What would be the molality and molarity of the solution? (Density of solution = 1.2 g mL-1) (Delhi Al 2014)
Answer:
10% (by mass) solution of glucose means that 10 g of glucose is present in 100 g of solution or in 90 g of water.

(i) Calculation of molality
Mass of glucose = 10 g
Moles of glucose = \(\frac{10}{180}\) = 0.0556
(Molar mass of glucose = 180 g/mol)
Mass of water = 90 g
Class 12 Chemistry Important Questions Chapter 2 Solution 10
= \(\frac{0.0556}{90}\) × 1000
= 0.618 m

(ii) Calculation of molarity
Moles of glucose = 0.0556 Mass
Class 12 Chemistry Important Questions Chapter 2 Solution 11

Question 9.
A 4% solution (w/w) of sucrose (M = 342 g mol-1) in water has a freezing point of 271.15 K. Calculate the freezing point of 5% glucose (M = 180 g mol-1) in water. (Given: Freezing point of pure water = 273.15 K)
Answer:
For Sucrose solution,
WB = 4 g, WA = 100 – 4 = 96 g,
ΔTf = 273.15 – 271.5 = 2°C
Class 12 Chemistry Important Questions Chapter 2 Solution 12
Freezing point of solution = 273.15 – 4.8
= 268.35 K

Question 10.
What would be the molar mass of a compound if 6.21 g of it dissolved in 24.0 g of chloroform form a solution that has a boiling point of 68.04°C. The boiling point of pure chloroform is 61.7°C and the boiling point elevation constant, Kb, for chloroform is 3.63 °C/m. (CBSE Delhi 2011)
Answer:
Elevation in boiling point,
ΔTb = 68.04 – 61.7 = 6.34 °C
Mass of substance,
wB = 6.21 g,
Mass of chloroform,
wA = 24.0g
Kb = 3.63 °C/m
Class 12 Chemistry Important Questions Chapter 2 Solution 13

Question 11.
Two elements A and B form compounds having molecular formula AB2 and AB4. When dissolved in 20 g of benzene, 1 g of AB2 lowers the freezing point by 2.3 K, whereas 1.0 g of AB4 lowers it by 1.3 K. The molar depression constant for benzene is 5.1 K kg mol-1. Calculate the atomic mass of A and B. (Delhi Al 2004)
Answer:
Let us first calculate molar masses of AB2 and AB4.
For AB2 compound
MB = \(\frac{\mathrm{K}_{f} \times \mathrm{W}_{\mathrm{B}} \times 1000}{\mathrm{w}_{\mathrm{A}} \times \Delta \mathrm{T}_{f}}\)
ΔTf = 2.3 K, wB = 1.0 g,
wA = 20.0 g
Kf = 5.1 K kg mol-1
MAB2 = \(\frac{5.1 \times 1.0 \times 1000}{20.0 \times 2.3}\)
∴ MAB2 = 110.87
For AB4 compound
ΔTf= 1.3 K, wB = 1.0 g,
wA = 20.0 g
MAB4 = \(\frac{5.1 \times 1.0 \times 1000}{20.0 \times 1.3}\)
∴ MAB4 = 196.15
Let a be the atomic mass of A and b be the atomic mass of B, then
MAB2 = a + 2b = 110.87 …… (i)
MAB4 = a + 4b = 196.15 ……. (ii)
Subtracting eqn. (ii) from eqn. (i)
– 2b = – 85.28
∴ b = 42.64
Substituting the value of b in eqn (i)
a + 2 × 42.64 = 110.87
a = 110.87 – 85.28 = 25.59
Atomic mass of A = 25.59 g
Atomic mass of B = 42.64 g

Question 12.
A solution prepared by dissolving 8.95 mg of a gene fragment in 35.0 mL of water has an osmotic pressure of 0.335 torr at 25°C. Assuming the gene fragment is a non-electrolyte, determine its molar mass. (CBSE Delhi 2011, Delhi Al 2011)
Answer:
Mass of gene fragment = 8.95 mg
= 8.95 × 10-3 g
Volume of water = 35.0 mL
= 35.0 × 10-3 L
Osmotic pressure,
π = 0.335 torr
= 0.335/760 atm
Temperature = 25°C
= 273 + 25 = 298 K
Class 12 Chemistry Important Questions Chapter 2 Solution 14
= 14193.3 g mol-1 or
1.42 × 1o4g mol-1.

Question 13.
Calculate the boiling point of solution when 2 g of Na2SO4 (M = 142 g mol-1) was dissolved in 50 g of water, assuming Na2SO4 undergoes complete ionization. (Kb for water = 0.52 K kg mol-1) [Delhi Al 2016)
Answer:
ΔTb = \(\frac{i \times K_{b} \times w_{B} \times 1000}{M_{B} \times w_{A}}\)
Weight of solute, wB = 2 g
Molar mass = 142 g mol-1
Weight of solvent = 50 g
Kb = 0.52 K kg mol-1
Na2SO4 undergoes complete ionisation as:
Na2SO4 ⇌ 2Na+ + SO42-
One mole of Na2SO4 gives 3 mole particles and therefore,
i = 3
∴ ΔTb = \(\frac{3 \times 0.52 \times 2 \times 1000}{142 \times 50}\) = 0.439
Boiling point of solution = 373 + 0.439
= 373.439 K

Question 14.
Calculate the amount of CaCl2 (molar mass = 111 g mol-1) which must be added to 500 g of water to lower its freezing point by 2 K, assuming CaCl2 is completely dissociated, (Kf for water = 1.86 K kg mol-1) (Delhi Al 2015)
Answer:
CaCl2 undergoes complete dissociation as:
CaCl2 → Ca2+ + 2Cl
One mole of CaCl2 will give 3 mole particles and therefore, the value of T will be equal to 3.
ΔTf = i Kf × m
= \(\frac{i \times K_{f} \times w_{B} \times 100}{M_{B} \times W_{A}}\)
Kf = 1.86 K kg mol-1, wA = 500 g, wB = ?, ΔTf = 2 K, i = 3, MB = 111 g mol-1
2 = \(\frac{3 \times 1.86 \times w_{B} \times 1000}{111 \times 500}\)
∴ WB = \(\frac{2 \times 111 \times 500}{3 \times 1.86 \times 1000}\) = 19.89 g

Question 15.
A solution 0.1 M of Na2SO4 is dissolved to the extent of 95%. What would be its osmotic pressure at 27°C? (R = 0.0821 L atm K-1 mol-1) (CBSE AI 2019)
Answer:
Na2SO4 ⇌ 2Na+ + SO42-
n = 3
If α is the degree of dissociation, then
α = \(\frac{i-1}{n-1}\)
0.95 = \(\frac{i-1}{3-1}\)
0.95 × 2 = i – 1 or i = 1.90 + 1 = 2.90
π = iCRT
= 2.90 × 0.1 × 0.0821 × 300
= 7.143 atm

Question 16.
(i) Out of 1 M glucose and 2 M glucose, which one has a higher boiling point and why?
(ii) What happens when the external pressure applied becomes more than the osmotic pressure of solution? (Delhi Al 2016)
Answer:
(i) The elevation in boiling point is a colligative property and depends upon the number of moles of solute added. Higher the concentration of solute added, higher will be the elevation in boiling point. Thus, 2M glucose solution has higher boiling point than 1 M glucose solution.

(ii) When the external pressure applied becomes more than the osmotic pressure of the solution, then the solvent molecules from the solution pass through the semipermeable membrane to the solvent side. This process is called reverse osmosis.

Question 17.
Which of the following solutions has higher freezing point?
0.05 M Al2(SO4)3, 0.1 M K3[Fe(CN)6] Justify. (CBSE Sample Paper 2017-18)
Answer:
0.05 M Al2(SO4)3 has higher freezing point.
ΔTf ∝ i × concentration
For 0.05 M Al2(SO4)3 i = 5
ΔTf ∝ 5 × 0.05 = 0.25 moles of ions
For 0.1 M K3[Fe(CN)6], i = 4
ΔTf ∝ 4 × 0.1 = 0.40 moles of ions
∴ Depression in freezing point for 0.05 M Al2(SO4)3 will be less and hence freezing point will be higher.

Question 18.
A 10% solution (by mass) of sucrose in water has freezing point of 269.15 K. Calculate the freezing point of 10% glucose in water, if freezing point of pure water is 273.15 K. Given: (Molar mass of sucrose = 342 g mol-1) (Molar mass of glucose = 180 g mol-1) (CBSE AI 2017, CBSE Delhi 2017)
Answer:
For sucrose solution,
Kf = \(\frac{\Delta T_{f} \times w_{A} \times M_{B}}{w_{B} \times 1000}\)
ΔTf = 273.15 – 269.15 = 4.0 k, wB = 10 g
WA = 100 – 10 = 90 g
kf = \(\frac{4.0 \times 90 \times 342}{10 \times 1000}\) = 12.31 km-1
For glucose solution,
wB = 10 g, wA = 100 – 10 = 90 g
MB = 180 g
ΔTf = \(\frac{12.31 \times 10 \times 1000}{90 \times 180}\) = 7.6 k
Freezing point of glucose solution
= 273.15 – 7.6
= 265.55 K

Question 19.
30 g of urea (M = 60 g mol-1) is dissolved in 846 g of water. Calculate the vapour pressure of water for this solution if vapour pressure of pure water at 298 K is 23.8 mm Hg. (CBSE Al 2017)
Answer:
Class 12 Chemistry Important Questions Chapter 2 Solution 15

Question 20.
The vapour pressures of pure liquids A and B are 450 mm and 700 mm of Hg respectively at 350 K. Calculate the composition of liquid mixture if total vapour pressure is 600 mm of Hg. Also find the composition of the mixture in vapour phase.
(CBSE Sample Paper 2010)
Answer:
Let mole fraction of liquid A in solution = xA
Mole fraction of liquid B in solution, xB = 1 – xA
P = PA°XA + PB°XB or = PA°XA + PB°(1 – xA)
p = 600 mm Hg
600 = 450 xA + 700 (1 – xA)
Solving, XA = \(\frac{100}{250}\) = 0.4
Mole fraction of liquid A = 0.4
Mole fraction of liquid B = 1 – 0.4 = 0.6
Calculation of composition of vapour phase
pA = PA°XA = 450 mm × 0.4 = 180 mm
pB = PB°XB = 700 × 0.6 = 420 mm
Ptotal = pA + pB = 180 + 420 = 600 mm
Class 12 Chemistry Important Questions Chapter 2 Solution 16

Question 21.
Calculate the boiling point of a solution prepared by adding 15.00 g of NaCl to
250.0 g of water. (Kb for water = 0.512 K kg mol-1, molar mass of NaCl = 58.44 g) (CBSE Delhi 2011)
Answer:
ΔTb = \(\frac{\mathrm{iK}_{\mathrm{b}} \times 1000 \times \mathrm{W}_{2}}{\mathrm{~W}_{1} \times \mathrm{M}_{2}}\)
NaCl dissociates as:
NaCl → Na+ + Cl
∴ i = 2
W2 = 15.0 g, W1 = 250.0 g, M2 = 58.44 g mol-1
∴ Kb = 0.512 K kg mol-1
∴ ΔTb = \(\frac{2 \times 0.512 \times 1000 \times 15.0}{250.0 \times 58.44}\)
∴ Boiling point of solution = 100 + 1.05
= 101.5°C

Question 22.
(i) Define the following terms:
(a) Mole fraction
(b) van’t Hoff factor
(ii) 100 mg of a protein is dissolved in enough water to make 10.0 mL of a solution. If this solution has an osmotic pressure of 13.3 mm Hg at 25°C, what is the molar mass of protein? (R = 0.0821 L atm. mol-1 K-1 and 760 mm Hg = 1 atm.) (CBSE Delhi 2010)
Answer:
(i) (a) Mole fraction is the ratio of number of moles of one component to the total number of motes In a mixture. For example, in a binary mixture containing n1 and n2 moles of two components, Mole fraction of one component,
x1 = \(\frac{n_{1}}{n_{1}+n_{2}}\)
Mote fraction of second component,
x2 = \(\frac{n_{2}}{n_{1}+n_{2}}\)
(b) van’t Hoff factor is the ratio of the normal molar mass to the observed or abnormal molar mass of a solute in a solution due to association or dissociation.
Class 12 Chemistry Important Questions Chapter 2 Solution 17

(ii) Osmotic pressure,
Class 12 Chemistry Important Questions Chapter 2 Solution 19

Question 23.
(i) Differentiate between molarity and molality of a solution. How does a change in temperature influence their values?
(ii) Calculate the freezing point of an aqueous solution contaning 10.50 g of MgBr2 in 200 g of water (Molar mass of MgBr2 = 184 g mol-1, = for water = 1.86 K kg mol-1). (CBSE Delhi 2011)
Answer:
(i) Molality is the number of moles of solute per 1000 g of solvent, whereas molarity is the number of moles of solute per 1000 ml of the solution. Molality is represented as m, whereas molarity is represented as M.

Molarity changes with change in temperature because of change in volume. On the other hand, there is no effect of temperature on the molality of the solution.

(if) Moles of MgBr2
= \(\frac{10.50}{184}\)
= 0.0571 mol
Mass of water = 200 g
Molality = \(\frac{0.0571}{200}\) × 1000
= 0.2855 m
MgBr2 ionises as:
MgBr2 → Mg2+ + 2Br
Assuming complete dissociation of MgBr2,
i = 3
Freezing point depression
ΔTf = i × Kf × m
= 3 × 1.86 × 0.2855
= 1.59
Freezing point = 0 – 1.59°C
= – 1.59°C

Question 24.
(i) Define the terms osmosis and osmotic pressure. Is the osmotic pressure of a solution a colligative property? Explain.
(ii) Calculate the boiling point of a solution prepared by adding 15.00 g of NaCl to 250.0 g of water. (Kb for water = 0.512 K kg mol-1, molar mass of NaCl = 58.44 g mol-1) (CBSE Delhi 2011)
Answer:
(i) Osmosis is the flow of solvent from solution of lower concentration to higher concentration through a semi- permeable membrane.

Osmotic pressure is the excess pressure which must be applied to a solution to prevent the passage of solvent through a semipermeable memberane.

It has been found experimentally that for n moles of the solute dissolved in V litres of the solution, the osmotic pressure (π) at temperature T is
πV = nRT
where R is a gas constant.
or π = \(\frac{n}{V}\) RT
= C RT
where C is the molar concentration of the solution.
For a solution at given tempeature, both R and T are constant so that
π ∝ C
Thus, osmotic pressure depends upon the molar concentration of solution and therefore, is a colligative property.

(ii) ΔTb = \(\frac{i \mathrm{~K}_{b} \times 1000 \times \mathrm{W}_{2}}{\mathrm{~W}_{1} \times \mathrm{M}_{2}}\)
NaCl dissociates as:
NaCl → Na+ + Cl
∴ i = 2
W2 = 15.0 g, W1 = 250.0 g,
M2 = 58.44 g mol-1
Kb = 0.512 K kg mol-1 .
∴ ΔTb = \(\frac{2 \times 0.512 \times 1000 \times 15.0}{250.0 \times 58.44}\)
= 1.05°C
∴ Boiling point of solution = 100 + 1.05
= 101.5°C

Question 25.
(a) A 5% solution (by mass) of cane sugar in water has a freezing point of 271 K. Calculate the freezing point of 5% solution (by mass) of glucose in water. The freezing point of pure water is 273.15 K.
(b) Why is osmotic pressure of 1 M KCl higher than 1 M urea solution?
(c) What type of liquids form ideal solutions?
OR
(a) 1.0 g of a non-electrolyte solute dissolved in 50 g of benzene lowered the freezing point of benzene by 0.40 K. The freezing point depression constant of benzene is 5.12 K kg mol-1. Find the molar mass of the solute.
(b) What is the significance of Henry’s law constant, KH?
(c) What leads to anoxia? (CBSE 2019C)
Answer:
(a)
Class 12 Chemistry Important Questions Chapter 2 Solution 19
(b) On dissolving in water KCl dissociates into K+ and Cl ions but urea does not dissociate into ions.

(c) Ideal solutions: An ideal solution may be defined as the solution which obeys Raoult’s law exactly over the entire range of concentration.
Such solutions are formed by mixing the two components which are identical in molecular size, in structure and have almost identical intermolecular forces. In these solutions, the intermolecular interactions between the components (A – B attractions) are of same magnitude as the intermolecular interactions in pure components (A – A and B – B attractions).

The ideal solutions have also the following characteristics:
1. Heat change on mixing is zero. Since there is no change in magnitude of the attractive forces in the two components present, the heat change on mixing, i.e. ΔmixingH in such solutions must be zero.

(ii) Volume change on mixing is zero. In ideal solutions, the volume of the solution is the sum of the volumes of the components before mixing, i.e. there is no change in volume on mixing or ΔmixingV is zero.

For example, when we mix 100 cm3 of benzene with 100 cm3 of toluene, the volume of the solution is found to be exactly 200 cm3. Therefore, there is no change in volume on mixing, i.e. ΔmixingV = 0. It has been noticed that the solutions generally tend to become ideal when they are dilute.

Examples of ideal solutions: In fact, ideal solutions are quite rare but some solutions are nearly ideal in behaviour at least when they are very dilute. A few examples of ideal solutions are:

  • Benzene and toluene
  • n-hexane and n-heptane
  • Bromoethane and iodoethane
  • Chlorobenzene and bromobenzene.

OR

(a)
Class 12 Chemistry Important Questions Chapter 2 Solution 20

(b) (i) Henry’s law constant, KH depends upon the nature of the gas.
(ii) Higher the value of KH at a particular pressure, the lower is the solubility of the gas in the liquid. (∵ x = \(\frac{1}{\mathrm{~K}_{\mathrm{H}}}\) . p)

(iii) The value of KH increases with increase in temperature indicating that the solubility of gases decreases with increase of temperature. This is the reason that aquatic species are more comfortable in cold water rather than warm water.

(c) At high altitudes, the partial pressure of oxygen is less than that at the ground level. This leads to low concentration of oxygen in the blood and the tissues of the people living at high altitudes. As a result of low oxygen in the blood, the people become weak and unable to think clearly. These are the symptoms of a condition known as anoxia.

Question 26.
(i) State Raoutt’s law for a solution containing volatile components. How does Raoult’s law become a special case of Henry’s law?
(ii) 1.00 g of non-electrolyte solute dissolved in 50 g of benzene lowered the freezing point of benzene by 0.40 K. Find the molar mass of the solute. (Kf for benzene = 512 K kg mol-1)
OR
(i) Define the following terms:
(a) Ideal solution
(b) Azeotrope
(c) Osmotic pressure
(ii) A solution of glucose (C6H12O6) in
water is labelled as 10% by weight. What would be the molality of the solution? (CBSE 2013)
(Molar mass of glucose = 180 g mol-1)
Answer:
(i) Raoult’s law states that at a given temperature, for a solution of volatile liquids, the partial pressure of each component in solution is equal to the product of the vapour pressure of the pure component and its mole fraction. For example, for a binary solution of two volatile liquids A and B having mole fractions xA and xB,
PA = P°A XA and PB = P°B XB
where pA and pB are the vapour pressures of the components in solutions and P°A and P°B are vapour pressure of pure components.
According to Henry’s law for a gas dissolved in a liquid, the pressure of the gas is directly proportional to mole fraction, i.e.
p = KHx
where KH is a proportionality constant known as Henry’s constant.
But Raoult’s law states that
p = p°x
∴ KH = p°
This means that Raoult’s law is a special case of Henry’s law.

(ii) Molar mass of solute,
MB = \(\frac{K_{f} \times W_{B} \times 1000}{W_{A} \times \Delta T_{f}}\)
WB = 1.0g
WA = 50.0 g,
ΔTf = 0.40 K
Kf = 5.12 K kg mol-1
MB = \(\frac{5.12 \times 1.0 \times 1000}{50 \times 0.40}\)
= 256 g/mol

OR

(i) (a) Ideal solution. A solution which obeys Raoult’s law exactly over the entire range of concentration is called ideal solution.

(b) Azeotrope. The solutions or liquid mixtures which boil at constant temperature and can distil unchanged in composition are called azeotropes.

(c) Osmotic pressure. The excess pressure which must be applied to a solution to prevent the passage of solvent into it through a semipermeable membrane is called osmotic pressure.

(ii) 10% by weight means that 10 g of glucose is present in 100 g of solution.
Mass of solvent = 100 – 10 = 90 g
Moles of glucose = \(\frac{10}{180}\) = 0.0556
Molality = \(\frac{0.0556}{90}\) × 1000
= 0.618 m

Question 27.
(i) Define the following terms:
(a) Molarity
(b) Molal elevation constant (Kb)
(ii) A solution containing 15 g urea
(molar mass = 60 g mol-1) per litre of solution in water has the same osmotic pressure (isotonic) as a solution of glucose (molar mass = 180 g mol-1) in water. Calculate the mass of glucose present in one litre of its solution. (CBSE 2014)
OR
(i) What type of deviation is shown by a mixture of ethanol and acetone? Give reason.
(ii) A solution of glucose (molar mass = 180 g mol-1) in water is labelled as 10% (by mass). What would be the molality and molarity of the solution?
(Density of solution = 1.2 g mL-1)
Answer:
(i) (a) Molarity is defined as number of moles of solute dissolved per litre of solution.
Class 12 Chemistry Important Questions Chapter 2 Solution 21
Its unit is mol L-1 or M.

(b) Molal elevation constant Kb is the elevation in boiling point for 1 molal solution.
(ii) For isotonic solutions,
π (urea) = π (glucose)
Class 12 Chemistry Important Questions Chapter 2 Solution 22

OR

(i) Mixture of ethanol and acetone shows positive deviations from Raoult’s law. This is because in ethanol, the molecules are held together due to hydrogen bonding as:
Class 12 Chemistry Important Questions Chapter 2 Solution 23
When acetone is added to ethanol, there are weaker interactions between acetone and ethanol than ethanol-ethanol interactions. Some molecules of acetone occupy spaces between ethanol molecules and consequently, some hydrogen bonds in alcohol molecules break and attractive forces between ethanol molecules are weakened.

Therefore, the escaping tendency of ethanol and acetone molecules from solution increases. Thus, the vapour pressure of the solution is greater than the vapour pressure as expected according to Raoult’s law.

(ii) WB = 10 g, wt. of solvent = 90 g
MB = 180 g mol-1
Class 12 Chemistry Important Questions Chapter 2 Solution 24
Class 12 Chemistry Important Questions Chapter 2 Solution 25

Question 28.
(i) Calculate the freezing point of solution when 1.9 g of MgCl2 (M = 95 g mol-1) was dissolved in 50 g of water, assuming MgCl2 undergoes complete ionisation.
(Kf for water = 1.86 K kg mol-1)
(ii) (a) Out of 1 M glucose and 2 M glucose, which one has a higher boiling point and why?
(b) What happens when the external pressure applied becomes more than the osmotic pressure of solution? (CBSE Delhi 2016)
OR
(i) When 2.56 g of sulphur was dissolved in 100 g of CS2, the freezing point lowered by 0.383 K. Calculate the formula of sulphur (Sx).
(Kf for CS2 = 3.83 K kg mol-1, Atomic mass of sulphur = 32 g mol-1)
(ii) Blood cells are isotonic with 0.9% sodium chloride solution. What happens if we place blood cells in a solution containing
(a) 1.2% sodium chloride solution?
(b) 0.4% sodium chloride solution?
Answer:
(i) ΔTf = \(\frac{i \mathrm{~K}_{f} \times \mathrm{w}_{\mathrm{B}} \times 1000}{M_{\mathrm{B}} \times \mathrm{w}_{\mathrm{A}}}\)
wB = 1.9 g, wA = 50 g, MB = 95 g mol-1
Kf = 1.86 K kg mol-1
MgCl2 ⇌ Mg2+ + 2Cl
i = 3
ΔTf = \(\frac{3 \times 1.86 \times 1.9 \times 1000}{95 \times 50}\)
= 2.232 K
Freezing point of solution
= 273 – 2.232 = 270.768 K

(ii) (a) The elevation in boiling point is a colligative property and depends upon the number of moles of solute added. Higher the concentration of solute added, higher will be the elevation in boiling point. Thus, 2 M glucose solution has higher boiling point than 1 M glucose solution.

(b) When the external pressure applied becomes more than the osmotic pressure of the solution, then the solvent molecules from the solution pass through the semipermeable membrane to the solvent side. This process is called reverse osmosis.
OR
(i) MB = \(\frac{\mathrm{K}_{f} \times 1000 \times \mathrm{W}_{\mathrm{B}}}{\mathrm{W}_{\mathrm{A}} \times \Delta \mathrm{T}_{f}}\)
WB = 2.56 g, WA = 100 g, ΔTf = 0.383 Kf = 3.83 K kg mol-1
Let the molecular formula of sulphur
= Sx
32 × x = 256
x = \(\frac{256}{32}\) = 8
∴ Molecular formula = S8

(ii) (a) 1.2% sodium chloride solution is hypertonic with respect to 0.9% sodium chloride solution or blood cells. When red blood cells are placed in this solution, water flows out of the cell and they shrink due to loss of water by osmosis.

(b) 0.4% sodium chloride solution is hypertonic with respect to 0.9% sodium chloride solution or blood cells. When red blood cells are placed in this solution, water flows into the cells and they swell.

Question 29.
A 4% solutioin (w/w) of sucrose (M = 342 g mol-1) in water has a freezing point of 271.15 K. Calculate the freezing point of 5% glucose (M = 180 g mol-1) in water.
(Given: Freezing point of pure water = 273.15 K)
Answer:
In case of sucrose:
ΔTf = (273.15 – 271.15) K = 2.00 K
Molar mass of sucrose (C12H22O11)
= (12 × 12) + (22 × 1) + (11 × 16) = 342 g mol-1
4% solution (w/w) of sucrose in water means 4 g of cane sugar in (100 – 4) g = 96 g of water.
Number of moles in 4 g sucrose in water
= 4/342 mol or 0.01169 mol
Therefore, molality of the solution,
m = 0.011696 mol / 0.096 kg
Or
m = 0.1217 mol kg-1
Now applying the relation,
ΔTf = Kf × m
⇒ Kf = ΔTf / m
⇒ 2.00 K/0.1217 mol kg-1
= 16.4338 K kg mol-1
Molar mass of glucose (C6H12O6) = (6 × 12) + (12 × 1) + (6 × 16) = 180 g mol-1
5% glucose in water means 5 g of glucose is present in (100 – 5) g = 95 g of water.
∴ Number of moles of glucose = 5/180 mol
= 0.0278 mol
Therefore, molality of the solution, m = 0.0278 mol / 0.095 kg
= 0.2926 mol kg-1
Applying the relation, ΔTf = Kf × m
ΔTf = (16.4338 K kg mol-1) × (0.2926 mol kg-1 )
= 4.81 K (approx.)
Hence, the freezing point of 5% glucose solution is (273.15 – 4.81) K = 268.34 K.

Current Electricity Class 12 Important Extra Questions Physics Chapter 3

Here we are providing Class 12 Physics Important Extra Questions and Answers Chapter 3 Current Electricity. Important Questions for Class 12 Physics with Answers are the best resource for students which helps in Class 12 board exams.

Class 12 Physics Chapter 3 Important Extra Questions Current Electricity

Current Electricity Important Extra Questions Very Short Answer Type

Question 1.
A wire or resistivity ρ is stretched to double its length. What will be its new resistivity?
Answer:
The resistivity remains the same as it does not depend upon the length of the wire.

Question 2.
What is the effect of temperature on the relaxation time of electrons in a metal?
Answer:
The relaxation time of electrons decreases with the rise in temperature of the metal.

Question 3.
Which physical quantity does the voltage versus current graph for a metallic conductor depict? Give its SI unit.
Answer:
It represents resistance. It is measured in ohm.

Question 4.
Define drift velocity of electrons.
Answer:
The mean velocity acquired by electrons in a conductor when an external electric field is applied to it.

Question 5.
A resistance R is connected across a cell of emf ε and internal resistance r. A potentiometer now measures the potential difference between the terminals, of the cell as V., Write the expression for ‘r’ in terms of ε, V and R. (CBSE Delhi 2011)
Answer:
The required relation is r = \(\left(\frac{\varepsilon}{V}-1\right)\)R

Question 6.
How is the drift velocity in a conductor affected by the rise in temperature? (CBSE Delhi 2019)
Answer:
It decreases.

Question 7.
Two students A and B were asked to pick a resistor of 15 kΩ from a collection of carbon resistors. A picked a resistor with bands of colours brown, green, orange, while B chose a resistor with bands of black, green, red. Who picked the correct resistor? (CBSE AI 2013C)
Answer:
A

Question 8.
Define the term ‘Mobility’ of charge carriers in a conductor. Write its S.l. unit. (CBSE Delhi 2014, AI 2015)
Answer:
Mobility of charge carriers in a conductor is defined as the magnitude of their drift velocity per unit applied electric field. Its SI unit is m2 V-1 s-1.

Question 9.
How does the mobility of electrons in a conductor change, if the potential difference applied across the conductor is doubled, keeping the length and temperature of the conductor constant? (CBSE Delhi 2019)
Answer:
No change.

Question 10.
Graph showing the variation of current versus voltage for a material GaAs is shown in the figure. Identify the region of
(i) negative resistance (ii) where Ohm’s
Class 12 Physics Important Questions Chapter 3 Current Electricity 1
Answer:
(i) DE (ii) AB

Question 11.
Define mobility of a charge carrier. What is its relation with relaxation time? (CBSEAI 2016)
Answer:
It is defined as the drift velocity per unit electric field. The relation is μ = \(\frac{-e \tau}{m}\).

Question 12.
Nichrome and copper wires of the same length and same radius are connected in series. Current l is passed through them. Which wire gets heated up more? Justify your answer. (CBSEAI 2017)
Answer:
Nichrome, as it has more resistivity.

Question 13.
When a potential difference is applied across the ends of a conductor, how is the drift velocity of the electrons related to the relaxation time? (CBSE Delhi 2019)
Answer:
Drift velocity is directly proportional to the relaxation time.
Vd = \(\frac{e E}{m} \tau\)

Question 14.
Two bulbs are marked 60 W, 220 V and 100 W, 220 V. These are connected in parallel to 220 V mains. Which one out of the two will glow brighter?
Answer:
In parallel combination, the bulb having, more power glows more. Therefore the bulb marked 100 W, 220 V glows brighter.

Question 15.
A heater joined in parallel with a 60 W bulb is connected to the mains. If the 60 W bulb is replaced by a 100 W bulb, will the rate of heat produced by the heater be more, less or remain the same?
Answer:
The rate of heat produced in the heater will be the same as the two are connected in parallel.

Question 16.
Two conductors, one having resistance R and another 2R, are connected in turn across a dc source. If the rate of heat produced in the two conductors is Q1 and Q2 respectively, what is the value of Q1/ Q2?
Answer:
We know that Q = \(\frac{V^{2}}{R}\)t, therefore
\(\frac{Q_{1}}{Q_{2}}=\frac{R_{2}}{R_{1}}=\frac{2 R}{R}\) = 2

Question 17.
When electrons drift in metal from lower to higher potential, does it mean that all the free electrons of the metal are moving in the same direction? (CBSE Delhi 2012)
Answer:
No.

Question 18.
How does one explain the increase in resistivity of metal with an increase in temperature? (CBSE AI 2014C)
Answer:
With the increase in temperature, the average relaxation time decreases; this causes an increase in resistivity.

Question 19.
A carbon resistor is marked in red, yellow and orange bands. What is the approximate resistance of the resistor?
Answer:
24 × 103  ohm ± 20%

Question 20.
If potential difference V applied across a conductor is increased to 2 V, how will the drift velocity of the electrons change?
Answer:
The drift velocity is given by the expression Vd = \(\frac{e V}{m L}\)τ Therefore if the potential is doubled, drift velocity is also doubled.

Question 21.
What is the largest voltage you can safely put across a resistor marked 98 ohm – 0.5 W?
Answer:
Using the expression
V = \(\sqrt{P R}=\sqrt{0.5 \times 98}\) = 7 V

Question 22.
Two wires A and B are of the same metal, have the same area of cross-section and have their lengths in the ratio 2:1. What will be the ratio of currents flowing through them respectively, when the same potential difference is applied across the length of each of them?
Answer:
\(\frac{I_{\mathrm{A}}}{I_{\mathrm{B}}}=\frac{R_{\mathrm{B}}}{R_{\mathrm{A}}}=\frac{l_{\mathrm{A}}}{l_{\mathrm{B}}}=\frac{2}{1}\)

Question 23.
How does the heat produce in a resistor depend on its resistance when
(i) a constant current is passed through it
Answer:
For l = constant, heat produced H ∝ R

(ii) a constant potential difference is applied across its ends?
Answer:
For constant potential difference V, the heat produced, H ∝ \(\frac{1}{R}\)

Question 24.
Two wires of equal length, one of copper and the other of manganin have the same resistance. Which wire is thicker? (CBSE AI 2012)
Answer:
Manganin.

Question 25.
Two identical cells, each of emf E, having negligible internal resistance, are connected in parallel with each other across an external resistance R. What is the current through this resistance? (CBSE AI 2013)
Answer:
The current is l = E/R

Question 26.
Define temperature coefficient of resistivity. (CBSE Sample Paper 2018-2019)
Answer:
It is defined as the fractional change in resistivity per unit change in temperature.

Question 27.
A cell of emf E and internal resistance r is connected across an external resistance R. Plot a graph showing the variation of P.D. across R, versus R. (NCERT Exemplar)
Answer:
The graph is as shown.
Class 12 Physics Important Questions Chapter 3 Current Electricity 2

Current Electricity Important Extra Questions Short Answer Type

Question 1.
Why is a potentiometer preferred over a voltmeter for determining the emf of a cell? (CBSE Delhi 2016C)
Answer:
The potentiometer is based on the null method or it does not draw any (net) current from the cell and measures emf However, the voltmeter draws some current from the cell when connected across it, hence measures terminal voltage.

Question 2.
The figure shows the V – l graph for a parallel and series combination of two resistors A and B. Which line represents the parallel combination?
Class 12 Physics Important Questions Chapter 3 Current Electricity 3
Answer:
For the same potential, the current is less in series combination than parallel combination. Therefore from the graph, it is apparent that the same potential current is less in A. Therefore B represents the parallel combination.
As, R = \(\frac{V}{l}\)

The slope of B > Slope of A

Question 3.
V – l graph for a given metallic wire at two temperatures is shown. Which of these is at a higher temperature?
Class 12 Physics Important Questions Chapter 3 Current Electricity 4
Answer:
At higher temperature resistance of a metallic wire is more or its conductance is low. Hence, graph (2) is at a higher temperature, i.e. T2 > T1.

Question 4.
In an experiment on a metre bridge, if the balancing length AC is ‘x’, what would be its value, when the radius of the metre bridge wire AB is doubled? Justify your answer. (CBSE AI 2011C)
Class 12 Physics Important Questions Chapter 3 Current Electricity 5
Answer:
In a metre bridge, at the balance point we have
\(\frac{R_{1}}{R_{2}}=\frac{x}{100-x}\)

As R1 and R2 remain the same, x will also remain the same. It does not depend upon the diameter of the wire.

Question 5.
The emf of a cell is always greater than its terminal voltage. Why? Give reason. (CBSE Delhi 2013)
Answer:
When current passes through a cell, there is a drop in potential across it due to its internal resistance. This is called the lost volt. Thus terminal voltage is less than the emf of the cell.

Question 6.
Draw a graph showing the variation of resistivity with temperature for nichrome. Which property of nichrome is used to make standard resistance coils? (CBSEAI 2013C)
Answer:
The graph is as shown.
Class 12 Physics Important Questions Chapter 3 Current Electricity 6
The property has a low-temperature coefficient of resistance.

Question 7.
Define the term ‘mobility’ for a charge carrier and state its SI unit.
Name the mobile charge carriers in
(i) an electrolyte,
(ii) a semiconductor and
(iii) an ionised gas. (CBSE Al 2015)
Answer:
Mobility is defined as the ratio of the drift velocity of the charge to the applied electric field.
(i) Anions and cations.
(ii) Electrons and holes
(iii) Free electrons.

Question 8.
Define the term current density of a metallic conductor. Deduce the relation connecting current density (J) and the conductivity (a) of the conductor, when an electric field E is applied to it. (CBSE AI 2015)
Answer:
Current density is defined as the current flowing per unit area of the conductor.

Mathematically current density is given by the expression J = \(\frac{l}{A}\)

But l = V/R and R = \(\frac{ρl}{A}\) = \(\frac{L}{σA}\). Substituting in the above relation, we have

J = \(\frac{l}{A}\) = \(\frac{V}{AL}\) × σA= \(\frac{V}{L}\) × σ = Eσ

Question 9.
(a) Define the terms ‘drift velocity’ and ‘relaxation time’ giving their physical significance.
Answer:
Drift Velocity: It is the average velocity of the free electrons with which they get drifted towards the positive terminal under the influence of the external field.

Significance: The net current flowing through any cross-section is controlled by drift velocity and there is no transport of charges in a direction perpendicular to the applied field. Relaxation Time (T): The average time between successive collisions of electrons or ions in a conductor is called the relaxation time.

Significance: It determines the drift velocity acquired by the electrons under the given applied electric force and also determines the electrical conductivity of a conductor at different temperatures.

(b) A conductor of length L is connected across a dc source of emf E. If the conductor is replaced by another of the same material and area of cross-section but of length 5L, by what factor will the drift velocity change? (CBSE2019C)
Answer:
In the first case:
Vd= \(\frac{e V}{m L}\)τ

In the second case:
Class 12 Physics Important Questions Chapter 3 Current Electricity 7
Thus we find that the drift velocity becomes \(\frac{1}{5}\) of its original value.

Question 10.
A cell of emf ‘E’ and internal resistance ‘r’ is connected across a variable resistor. ‘R’. Plot a graph showing the variation of terminal voltage ‘ V’ of the cell versus the current ‘l’. Using the plot, show how the emf of the cell and its internal resistance can be determined. (CBSE AI 2014)
Answer:
The graph is as shown.
Class 12 Physics Important Questions Chapter 3 Current Electricity 8
For l = 0,V= E
The internal resistance can be found by using the expression
V = E – lr

For V = 0
E = lr
r = E/l

Question 11.
Two electric bulbs P and Q have their resistances in the ratio of 1: 2. They are connected in series across a battery. Find the ratio of the power dissipation in these bulbs. (CBSE AI, Delhi 2018)
Answer:
Given \(\frac{R_{\mathrm{p}}}{R_{\mathrm{Q}}}\) = \(\frac{1}{2}\)

Power dissipated \(\frac{P_{\mathrm{p}}}{P_{\mathrm{Q}}}=\frac{I^{2} R_{\mathrm{p}}}{I^{2} R_{\mathrm{Q}}}=\frac{1}{2}\)

Question 12.
A 10 V cell of negligible Internal resistance Is connected In parallel across a battery of emf 200 V and Internal resIstance 38 š as shown in the figure. Find the value of current in the circuit. (CBSE AI, Delhi 2018)
Class 12 Physics Important Questions Chapter 3 Current Electricity 9
Answer:
Given ε1 = 10 V, r1 = 0, ε2 = 200 V, r2 = 38 Ω
The two cells send current in the opposite direction; therefore, net emf of the combination
E = 200 – 10 = 190V

Hence current in the circuit
l = \(\frac{E}{R}=\frac{190}{38}\) = 5 A

Question 13.
In a potentiometer arrangement for determining the emf of a cell, the balance point of the cell In an open circuit is 350 cm. When the resistance of 9 Ω Is used In the external circuit of the cell, the balance point shifts to 300 cm. Determine the internal resistance of the cell. (CBSE AI, Delhi 2018)
Answer:
Given L1 = 350 cm, L2 – 300 cm, R = 9 Ω, r = ? Using the expression
r = \(\left(\frac{L_{1}-L_{2}}{L_{2}}\right) R=\left(\frac{350-300}{300}\right)\) × 9 = 1.5 Ω

Question 14.
TWo bulbs are rated (P1 V) and (P2, V). If they are connected (i) in series and (ii) in parallel across a supply V, find the power dissipated in the two combinations in terms of P1 and P2. (CBSE Delhi 2019)
Answer:
Resistances of the two bulbs R1 = \(\frac{V^{2}}{P_{1}}\) and R2 = \(\frac{V^{2}}{P_{2}}\)

(i) Net resistance in series
Rs = R1 + R2 = \(\frac{V^{2}}{P_{1}}+\frac{V^{2}}{P_{2}}=V^{2}\left(\frac{P_{1}+P_{2}}{P_{1} P_{2}}\right)\)

(ii) Net resistance in parallel
Class 12 Physics Important Questions Chapter 3 Current Electricity 10
Question 15.
What is the advantage of using thick metallic strips to join wires in a potentiometer? (NCERT Exemplar)
Answer:
The metal strips have low resistance and need not be counted in the potentiometer Length l of the null point. One measures only their lengths along with the straight segments (of lengths 1 metre each). This is easily done with the help of centimetre rulings or metre ruler and leads to accurate measurements.

Question 16.
AB is a potentiometer wire (figure). If the value of R is increased, in which direction will the balance point J shift? (NCERT Exemplar)
Class 12 Physics Important Questions Chapter 3 Current Electricity 11
Answer:
If R is increased, the current through the wire will decrease. This will decrease the potential gradient across the potentiometer wire (k = V/L = lpRp/L). Hence more length of the wire will be required to balance the same cell. Therefore J will shift towards B.

Question 17.
While doing an experiment with a potentiometer (figure) it was found that the deflection is one-sided and
(i) the deflection decreased while moving from one end A of the wire to the end B;
(ii) the deflection increased while the jockey was moved towards the end B.
(iii) Which terminal + or -ve of the cell E1 is connected at X in case (i) and how is E1 related to E?
(iv) Which terminal of the cell E1 is connected at X in case (ii)? (NCERT Exemplar)
Class 12 Physics Important Questions Chapter 3 Current Electricity 12
Answer:
(i) Positive terminal of E1 is connected at Xand E1 > E.
(ii) Negative terminal of E1 is connected at X.

Question 18.
The circuit in the figure shows two cells connected in opposition to each other. Cell E1 is of emf 6 V and internal resistance 2 Ω; the cell E2 is of emf 4 V and internal resistance 8 Ω. Find the potential difference between the points A and B. (NCERT Exemplar)
Class 12 Physics Important Questions Chapter 3 Current Electricity 13
Answer:
The cells are connected in the opposite direction, therefore net emf in the circuit is
E = E1 – E2 = 6 – 4 = 2 V

Hence current in the circuit is
l = \(\frac{E}{R+r}\) = \(\frac{2}{10}\) = 0.2 A

P.D. across E1 = 6 – 0.2 × 2 = 5.6 V
P.D. across E2 = VAB = 4 + 0.2 × 8 = 5.6 V
Point B is at a higher potential than A

Current Electricity Important Extra Questions Long Answer Type

Question 1.
Explain the term ‘drift velocity’ of electrons in a conductor. Hence obtain the expression for the current through a conductor in terms of ‘drift velocity’. (CBSE AI 2013, 2013C)
Answer:
Drift velocity (Vd) is defined as the average velocity with which the free electrons get drifted inside a conductor under the effect of the electric field, opposite to the direction of the field.

Let n be the electrons per unit volume in the conductor. Here n is called the number density of electrons. Assume that all electrons move with the same drift velocity Vd. In a time interval dt, each electron moves a distance vdt. Now the volume of the cylinder covered by the electrons in time dt is
V = A vddt …(1)

and the number of electrons in this volume is
N = nV = nA vddt …(2)

If e is the charge on the electron, then charge flowing through the conductor in small time dt is
dQ = e(nA vddt) …(3)

Hence the current through the conductor is
l = \(\frac{dQ}{dt}\) = nAevd

Question 2.
Draw a plot showing the variation of resistivity of an (i) conductor and (ii) semiconductor, with the increase in temperature.
How does one explain this behaviour in terms of the number density of charge carriers and the relaxation time? (CBSE Delhi 2014C)
Answer:
The plots are as shown.
Class 12 Physics Important Questions Chapter 3 Current Electricity 14
Class 12 Physics Important Questions Chapter 3 Current Electricity 15
With a rise in temperature the average relaxation time for a conductor decreases and resistivity increases, while for a semiconductor the number density of charge carriers increases, hence the resistivity decreases.

Question 3.
State the two Kirchhoff’s rules used in electric networks. How are these rules justified? (CBSE Delhi 2015)
Answer:
The two rules are

Kirchhoff’s junction rule: The algebraic sum of currents meeting at a junction is zero.
Kirchhoff’s loop rule: The algebraic sum of changes in potential around any closed loop involving resistors and cells in the loop is zero.

The two rules are justified as they are based on the law of conservation of charge and law of conservation of energy respectively.

Question 4.
(a) Deduce the relation between current l flowing through a conductor and drift velocity \(\vec{v}_{\mathrm{d}}\) of the electrons.
(b) Figure shows a plot of current ‘l’ flowing through the cross-section of a wire versus the time ‘t’. Use the plot to find the charge flowing in 10 s through the wire. (CBSE AI 2015C, 2016C)
Class 12 Physics Important Questions Chapter 3 Current Electricity 16
Answer:
Suppose there are n electrons per unit volume, where n is called the number density of electrons. Assume that all electrons move with the same drift velocity Vd. In a time interval dt, each electron moves a distance vddt. Now the volume of the cylinder covered by the electrons in time dt is
V = A vddt ….(1)

and the number of electrons in this volume is
N = nV=nA vddt …(2)

If e is the charge on the electron, then charge flowing through the conductor in small time dt is
dQ= e(nA vddt) …(3)

Hence the current through the conductor is
l = \(\frac{dQ}{dt}\) = vdenA

The area under the l – t curve gives the value of the charge
Q = 1/2 × 5 × 5 + (10 – 5) × 5 = 12.5 + 25
= 37.5 C

Question 5.
Answer the following:
(a) Why are the connections between the resistors in a metre bridge made of thick copper strips?
Answer:
The metal strips have low resistance;
hence their resistance does not come into play while calculating the unknown resistance.

(b) Why is it generally preferred to obtain the balance point in the middle of the metre bridge wire?
Answer:
It is done to reduce the index correction.

(c) Which material is used for the metre bridge wire and why? (CBSE Al 2014)
Answer:
Alloys are used due to their high resistivity.

Question 6.
(a) State the underlying principle of a potentiometer. Why is it necessary to (i) use a long wire, (ii) have a uniform area of cross-section of the wire and (iii) use a driving cell whose emf is taken to be greater than the EMFs of the primary cells?
Answer:
Principle: It is based on the principle that if a wire of uniform area of cross-section carries a constant current, the potential drop across any portion of the wire is directly proportional to the length of that portion of the wire.

The diagram is as shown.
First, the key K is inserted. This brings the cell of emf E1 in the circuit. The jockey is moved on the wire to obtain a balance point, i.e. a point on the wire where the galvanometer gives zero deflection. Let the balancing length be L1. Therefore by the potentiometer principle, we have
E1 ∝ L1 …(1)

Now, the key K2 is inserted. This brings the cell of emf E2 into the circuit. The jockey is again moved on the wire to obtain the balance point. Let the balancing length be L2. Then by potentiometer principle, we have
E2 ∝ L2 …(2)
Class 12 Physics Important Questions Chapter 3 Current Electricity 37
Dividing equations (1) by (2) we have
\(\frac{E_{1}}{E_{2}}=\frac{L_{1}}{L_{2}}\) …. (3)

Knowing the values of L1 and L2, the EMFs can be compared.

  1. The least count of the potentiometer is given by k = V/l, where l is the length of the potentiometer wire. The larger the value of l, the smaller is the least count. Hence a long wire is used so that there is more accuracy.
  2. If the area of cross-section is not uniform, the value of the potential ‘ gradient will not be the same along
    the length of the wire.
  3. The balance point will be obtained on the wire.

(b) In a potentiometer experiment, if the area of the cross-section of the wire increases uniformly from one end to the other, draw a graph showing how potential gradient would vary as the length of the wire increases from one end. (CBSE AI 2014C)
Answer:
k = \(\frac{V}{l}\) = \(\frac{lR}{l}\)

⇒ k ∝ \(\frac{1}{l}\)
Class 12 Physics Important Questions Chapter 3 Current Electricity 17

Question 7.
Plot a graph showing the variation of current density (j) versus the electric field (E) for two conductors of different materials. What information from this plot regarding the properties of the conducting material, can be obtained which can be used to select suitable materials for use in making (i) standard resistance and (ii) connecting wires in electric circuits?
Electron drift speed is estimated to be of the order of mm s-1. Yet large current of the order of few amperes can be set up in the wire. Explain briefly. (CBSEAI 2015)
Answer:
We know that J = σE
Therefore the graph between J and E will be a straight line passing through the origin.

This is as shown.
Class 12 Physics Important Questions Chapter 3 Current Electricity 18
The slope of the graph = conductivity (σ)

Hence materiaL with Less slope (smaller conductivity) is used for making standard resistors and materiaL with greater slope (higher conductivity) for making connecting wires.

A large current can be set up in the wire because the electron number density is enormous, 1029 m-3.

Question 8.
The reading of the (ideal) ammeter, In the circuit shown here, equals:
Class 12 Physics Important Questions Chapter 3 Current Electricity 19
(i) l when key K1 is closed but key K2 is open.
Answer:
(i) Current l when K2 is open
l = \(\frac{ε}{R+X}\)

(ii) l/2 when both keys K1 and K2 are closed.
Find the expression for the resistance of X In terms of the resistances of R and S. (CBSE Delhi 2016C)
Answer:
Let current be l when both K1 and K2 are closed
Class 12 Physics Important Questions Chapter 3 Current Electricity 20

Current through X
Class 12 Physics Important Questions Chapter 3 Current Electricity 21

Question 9.
Define the current sensitivity of a galvanometer. Write Its S.I. unit. The figure shows two circuits each having a galvanometer and a battery of 3 V. When the galvanometers in each arrangement do not show any deflection, obtain the ratio R1/R2. (CBSE AI 2013)
Class 12 Physics Important Questions Chapter 3 Current Electricity 22
Answer:
The current sensitivity of a galvanometer is defined as the deflection produced in the galvanometer per unit current passing through It. It is measured in div per ampere. In both cases the Wheatstone bridge is in the balanced state. Therefore we have
\(\frac{4}{R_{1}}=\frac{6}{9}\) Or R1 = 6 ohm

\(\frac{6}{12}=\frac{R_{2}}{8}\) Or R2 = 4 ohm

Therefore \(\frac{R_{1}}{R_{2}}=\frac{6}{4}=\frac{3}{2}\)

Question 10.
The following circuit shows the use of a potentiometer to measure the internal resistance of a cell, (i) When the key K is open, how does the balance point change, if the current from the driver cell decreases? (ii) When the key K is closed, how does the balance point change if R is increased, keeping the current from the driver cell constant?
Class 12 Physics Important Questions Chapter 3 Current Electricity 23
Answer:
(i) When the key K is open, a decrease in the current from the driver cell decreases the potential drop across the potentiometer wire. Therefore to balance the same emf again, more length of the wire will be required. Thus the balance point will shift towards point B.
(ii) When key K is closed and R is increased, it increases the terminal potential difference of the cell. Thus to balance the new terminal potential difference, more length of the wire will be required. Thus the balance point will shift towards point B.

Question 11.
(a) State, with the help of a circuit diagram, the working principle of a metre bridge. Obtain the expression used for determining the unknown resistance.
Answer:
(a) The experiment is based on the Wheatstone bridge principle.
Class 12 Physics Important Questions Chapter 3 Current Electricity 24
The connections are made as shown in the figure. A resistance R is introduced from the resistance box and the key K is closed. The jockey is moved on the wire to the point where there is no deflection in the galvanometer. In such case points, B and D are at the same potential. Point B is called the “null” point.

Let in this position AB = L cm and BC = (100 – L) cm. Therefore resistance of AB, i.e.
P ∝ L
and resistance of BC, i.e. Q ∝ (100 – L)

hence
\(\frac{P}{Q}=\frac{L}{100-L}\) …..(1)

In the balanced state by the Wheatstone bridge Principle we have
\(\frac{P}{Q}=\frac{R}{X}\) … (2)

Substituting equation (1) in equation (2) we have
\(\frac{R}{x}=\frac{L}{100-L}\) ….(3)

rewriting equation (3) we have
X = \(\left(\frac{100-L}{L}\right)\)R

(b) What happens if the galvanometer and cell are interchanged at the balance point of the bridge?
Answer:
There is no change in the position of the balance point if the galvanometer and the cell are interchanged.

(c) Why is it considered important to obtain the balance point near the mid-point of the wire? (CBSE Delhi 2011C)
Answer:
It is important to get the balance point near the mid-point of the wire because then the resistances in the four arms of the bridge are of the same order. The sensitivity of the bridge is maximum and the resistance is determined most accurately.

Question 12.
(a) Which material is used for potentiometer wire and why?
Answer:
The potentiometer wire is usually of constantan or manganin.
The material of the wire should have

  • high specific resistance and
  • low-temperature coefficient of resistance.

(b) How can the sensitivity of a potentiometer be increased? (CBSE Delhi 2011C)
Answer:
For greater sensitivity of the measurement, the fall of potential per cm should be less. The smaller the value of K, the greater will be the balancing length and the greater will be the accuracy of the measurement. For this, a wire of longer length should be taken or the current in the wire should be less.

Question 13.
Write two possible causes for one-sided deflection in a potentiometer experiment. (CBSE Delhi 2013)
Answer:

  1. The Emf of the auxiliary battery may be less than the emf of the test cell.
  2. The positive terminal of the test cell and the auxiliary cell may not be connected to the same point.

Question 14.
(a) Derive a relation between the internal resistance, emf and terminal potential difference of a cell from which current l is drawn. Draw V vs l graph for a cell and explain its significance.
Answer:
Consider the circuit shown.
Class 12 Physics Important Questions Chapter 3 Current Electricity 25
By Kirchhoff’s rules we have
E – lR – rl = 0
E – V – lr = 0
E = V + lr

The V-l graph is as shown.
Class 12 Physics Important Questions Chapter 3 Current Electricity 26
Significance of Graph: To find emf and internal resistance of the cell.

(b) A voltmeter of resistance 998 0 is connected across a cell of emf 2 V and internal resistance 2Q. Find the potential difference across the voltmeter and also across the terminals of the cell. Estimate the percentage error in the reading of the voltmeter.
Answer:
The diagram is as shown.
Class 12 Physics Important Questions Chapter 3 Current Electricity 27
V= E – lr
998 × l = 2 – 2l
1000 l = 2
l = 0.002 A

Therefore,
V= 0.002 × 998= 1.996 V

Percentage error
\(\frac{2-1.996}{2}\) × 100 = \(\frac{0.004}{2}\) = 0.2%

Question 15.
Two cells of the same emf E but internal resistance r1 and r2 are connected in series to an external resistor R (figure). What should be the value of R so that the potential difference across the terminals of the first cell becomes zero? (NCERT Exemplar)
Class 12 Physics Important Questions Chapter 3 Current Electricity 28
Answer:
Since the cells are connected in series,
total emf is
ET = E + E = 2E

Now current in the circuit Is
l = \(\frac{2 E}{R+r_{1}+r_{2}}\)

For terminal potential difference across the first cell to be zero we have
Class 12 Physics Important Questions Chapter 3 Current Electricity 29

Question 16.
Two cells of EMFs ε1 and ε2 and Internal resistances r1 and r2 respectively are connected in parallel. Obtain expressions for the equivalent
(i) resistance and
(ii) emf of the combination (CBSE Delhi 2018C, 2019C)
Answer:
Class 12 Physics Important Questions Chapter 3 Current Electricity 30
Class 12 Physics Important Questions Chapter 3 Current Electricity 31
Class 12 Physics Important Questions Chapter 3 Current Electricity 32

Question 17.
Using Kirchhoff’s rules, calculate the potential difference between B and D In the circuit diagram as shown in the figure. (CBSE Delhi 2018C)
Class 12 Physics Important Questions Chapter 3 Current Electricity 33
Answer:
Using Kirchhoff’s voLtage ruLe, we have:
For Loop DABD
l1 × 1 + (1) + (-2) + 2l1 + 2(l1 + l2) = 0
Or 5l1 + 2l2 = 1 …. (i)

For Loop DCBD
l2 × 3 + (3) + (-1) + l2 + 2(l1 + l2) = 0
Or 2l1 + 6 l2 = -2 …. (ii)
Class 12 Physics Important Questions Chapter 3 Current Electricity 34
Solving (i) and (ii), we get
l1 = \(\frac{5}{13}\)A

l2 = \(\frac{-6}{13}\)A

∴ Current through DB = l1 + l2 = \(\frac{-1}{13}\)A
∴ P.D. between B and D = 0.154 V

Question 18.
Define the term resistivity of a conductor. Give its SI unit. Show that the resistance R of a conductor Is given by \(\frac{m L}{n e^{2} A \tau}\)where the symbols have their usual meaning.
Answer:
The resistivity of a conductor is the resistance of the conductor of unit length and unit cross-sectional area.

Let Vd be the drift velocity of the electrons, then its relation with the electric field is
Vd = \(-\frac{e E}{m}\)τ …..(1)

Let V be the potential difference applied across the two ends of a conductor of length L and area of cross-section A, then
E = \(\frac{-V}{L}\) …..(2)

Substituting equation (1) in (2) we have
Vd = \(\frac{\mathrm{eV}}{\mathrm{mL}}\)τ ….(3)

Also l = neAVd ….(4)
Substituting equation (3) in equation (4),
we have

l = neA\(\left[\frac{e V}{m L} \tau\right]=\left[\frac{n e^{2} A \tau}{m L}\right]\)V ….(5)

Comparing with Ohm’s “Law”, i.e
l = \(\frac{V}{R}\) …. (6)

we have
R = \(\left[\frac{m L}{n e^{2} A \tau}\right]\) ….(7)

Question 19.
The given figure shows a network of resistances R1, R2, R3 and R4.
Class 12 Physics Important Questions Chapter 3 Current Electricity 35
Using Kirchhoff’s laws, establish the balance condition for the network. (CBSEAI 2015)
Answer:
Consider the diagram as shown below.
Class 12 Physics Important Questions Chapter 3 Current Electricity 36
Now applying Kirchhoff’s Loop rule to the closed Loop ABDA, we have
– l1R1 – lgG + (l – l1) R3 = 0 ….(1)

Again applying Kirchhoff’s Loop rule to closed-loop BCDB, we have
– (l1 – lg)R2 + (l – l1 + lg)R4 + lgG = 0 …(2)

The values of R1, R2, R3 and R4 are so adjusted that the galvanometer gives zero deflection. This means that both B and D will be at the same potential and hence no current will flow through the galvanometer,

i.e. lg = 0. In this situation, the Wheatstone bridge is said to be balanced. Putting lg = 0 in equations (1) and (2) we have
– l1R1 + (l – l1) R3 = 0
and
-l1R2 + (l – l1)R4 = 0 …(4)

Rewriting the above two equations we have
– l1R1 = (l – l1) R3 ….(5)
and
– l1R2 + (l – l1)R4 ….(6)

Dividing the above equations we have
\(\frac{R_{1}}{R_{2}}=\frac{R_{3}}{R_{4}}\) … (7)

The above expression gives the condition for the balance of a Wheatstone bridge.

Question 20.
Draw a circuit diagram of a potentiometer. State its working principle. Derive the necessary formula to describe how it is used to compare the EMFs of the two cells. (CBSE AI 2015C)
Answer:
PRINCIPLE: It is based on the principle that if a wire of uniform area of cross-section carries a constant current, the potential drop across any portion of the wire is directly proportional to the length of that portion of the wire.

The diagram is as shown.
First, the key K is inserted. This brings the cell of emf E1 into the circuit. The jockey is moved on the wire to obtain a balance point, i.e. a point on the wire where the galvanometer gives zero deflection. Let the balancing length be L1. Therefore by the potentiometer principle, we have
E1 ∝ L1 …(1)

Now, the key K2 is inserted. This brings the cell of emf E2 into the circuit. The jockey is again moved on the wire to obtain the balance point. Let the balancing length be L2. Then by potentiometer principle, we have
E2 ∝ L2 …(2)
Class 12 Physics Important Questions Chapter 3 Current Electricity 37
Dividing equations (1) by (2) we have
\(\frac{E_{1}}{E_{2}}=\frac{L_{1}}{L_{2}}\) …. (3)

Knowing the values of L1 and L2, the EMFs can be compared.

Question 21.
(i) Define the term ‘conductivity’ of a metallic wire. Write its SI unit.
Answer:
The property of a material that allows a flow of electrons between two points of the material when a potential difference is applied between these two points is called the conductivity of a wire. SI unit of conductivity: siemens per metre.
Class 12 Physics Important Questions Chapter 3 Current Electricity 38
(ii) Using the concept of free electrons in a conductor, derive the expression for the conductivity of a wire in terms of number density and relaxation time. Hence obtain the relation between current density and the applied electric field E. (CBSE At 2018, Delhi 2018)
Answer:
Drift velocity of electrons in a conductor is given as
Vd = eEτ/m …(1)

Small distance covered in time
Δt = VdΔt

Amount of charge passing through the area A in time Δt, q = lΔt
Δt = neAVdΔt
or l = neAVd …(2)
where
n → Number of free electrons per unit volume or number density

Now from equations (1) and (2), we get
l = ne2AτE/m …(3)

Since resistivity of a conductor is given as
ρ = m/ne2τ

Now, we know that the conductivity of a conductor is mathematically defined as the reciprocal of resistivity of the conductor. Thus,
σ = \(\frac{1}{ρ}\) …(4)

where σ = conductivity of the conductor. Thus, from equations (3) and (4), we get
σ = ne2τ/m ….(5)

Now, from equations (3) and (5), we have
lA = σE …(6)
and current density is given as
J = lA
Thus, J = σE

Question 22.
(a) You are required to select a carbon resistor of resistance of 56 kΩ ± 10% from a shopkeeper. What would be the sequence of colour bands required to code the desired resistor?
Answer:
Number 5 corresponds to green, No. 6 corresponds to blue, 103 corresponds to orange and 10% corresponds to silver.
∴ The sequence of Colours is
Green, blue, orange, silver

(b) Write two characteristic properties of the material of a metre bridge wire.
Answer:
Metre bridge wire must have

  • High resistivity
  • Low-temperature coefficient of resistivity

(c) What precautions do you take to minimise the error in finding the unknown resistance of the given wire? (CBSE2019C)
Answer:
To minimise the error in determining the resistance of a wire, the

  • The wire should be of uniform thickness
  • The balance point should be near the midpoint of the wire

Question 23.
The diagram below shows a potentiometer set-up. On touching the jockey near the end X of the potentiometer wire, the galvanometer pointer deflects to left. On touching the jockey near to end Y of the potentiometer, the galvanometer pointer again deflects to left but now by a larger amount. Identify the fault in the circuit and explain, using appropriate equations or otherwise, how it leads to such a one¬sided deflection. (CBSE Sample Paper 2018-19)
Class 12 Physics Important Questions Chapter 3 Current Electricity 39
Or
The following circuit was set up in a metre bridge experiment to determine the value X of unknown resistance.
Class 12 Physics Important Questions Chapter 3 Current Electricity 40
(i) Write the formula to be used for finding X from the observations. 39.5 cm from end A, when the resistor Y is 12.5 Ω. Determine the resistance of X. Why are the connections between resistors in a Wheatstone or metre bridge made of thick copper strips?
(ii) If the resistance R is increased, what will happen to balance length?
Answer:
The positive of E1 is not connected to terminal X.
In Loop XGNX,
E1 – VG + E = 0
VG = E1 + EXN
VG = E1 + kl

So, VG (or deflection) Will be maximum when l is maximum, i.e. when Jockey Is touched near the end Y. Also, VG (or deflection) Will, be minimum when l is minimum, i.e. when a jockey is touched near end X.
Or
(i) X = (100 – l) R/l
(ii) The balancing Length wilt increase.

Question 24.
(i) In a metre bridge as shown, the balance point is found to be at 39.5 cm from the end A, when the resistor Y is 12.5. Determine the resistance of X. Why are the connections between resistors In a Wheatstone or metre bridge made of thick copper strips?
(ii) Determine the balance point of the bridge above if X and Y are interchanged.
(iii) What happens if the galvanometer and cell are interchanged at the balance point of the bridge? Would the galvanometer show any current? (NCERT)
Class 12 Physics Important Questions Chapter 3 Current Electricity 41
Answer:
(i) Given L1 = 39.5 cm and L2 =100 – 39.5 = 60.5 cm, Y=12.5Q, X=?
Using the Wheatstone bridge principle we have
\(\frac{39.5}{60.5}=\frac{X}{12.5}\) or X = 8.2 Ω

The connections between resistors in a Wheatstone or metre bridge are made of thick copper strips to minimise the resistance of the connection which are not accounted for in the bridge formula.

(ii) If X and Y are interchanged, then
\(\frac{L}{(100-L)}=\frac{12.5}{8.2}\); solving for L we have
L = 60.4 cm from point A.

(iii) When the galvanometer and cell are interchanged, the condition for the balance of the bridge remains satisfied. Hence galvanometer will not show any current.

Question 25.
The figure below shows a potentiometer with a cell of 2.0 V and internal resistance of 0. 40 Ω maintaining a potential drop across the resistor wire AB. A standard cell that maintains a constant emf of 1.02 V (for very moderate currents up to a few mA) gives a balance point at 67.3 cm length of the wire. To ensure very low currents drawn from the standard cell, very high resistance of 600 kΩ is put in series with it, which is shorted close to the balance point. The standard cell is then replaced by a cell of unknown emf e and the balance point found similarly, turns out to be at 82.3 cm length of the wire.
1. What is the value of e?
2. What purpose does the high resistance of 600 kΩ have?
3. Is the balance point affected by this high resistance?
4. Is the balance point affected by internal resistance?
5. Would the method work in the above situation if the driver cell of the potentiometer had an emf of 1.0 V instead of 2.0 V?
6. Would the circuit work well for determining an extremely small emf, say of the order of a few mV (such as the typical emf of a thermo-couple)? If not, how will you modify the circuit?
Class 12 Physics Important Questions Chapter 3 Current Electricity 42
Answer:
1. Given ε1 = 1.02 V, L1 = 67.3 cm, L2 = 82.3 cm, ε2 = ?
By potentiometer principle we have
Class 12 Physics Important Questions Chapter 3 Current Electricity 43
2. This resistance reduces the current through the galvanometer when the movable contact (a jockey) is far away from the balance point. This, in turn, protects the galvanometer from the damage likely to be caused by the high current.
3. There is no effect of this resistance on the balance point.
4. There is no effect.
5. In case, the driving emf is smaller than the emf to be measured, the balance point cannot be found on the potentiometer wire.
6. In such a case, the balance point will be very close to the end giving a very large error in the measurement of e. If resistance is placed in series with the wire AB such that the potential drop across AB is only slightly larger than the emf to be measured, the balance point will be found on a larger length. This will make the error very small.

Numerical Problems:

Formulae for solving numerical problems.

  • The mobility of electrons is given by μ = \(\frac{V_{d}}{E}=\frac{e \tau}{m}\)
  • By Ohm’s law, l = \(\frac{V}{R}\) and J = σE
  • The current density is J = \(\frac{l}{A}\) = nevd
  • Theresistanceofawireis R = ρ\(\frac{L}{A}\) = \(\left[\frac{m L}{n e^{2} A \tau}\right]\)
  • The resistivity of a wire is ρ = \(\frac{m}{n e^{2} \tau}\)
  • The resistance of a wire at t°C is R = R0 (1 + αt)
  • In parallel combination \(\frac{1}{R_{p}}=\frac{1}{R_{1}}+\frac{1}{R_{2}}+\frac{1}{R_{3}}\)
  • In series combination Rs = R1 + R2 + R3 + ……..
  • Ratio of resistances in series and parallel \(\frac{R_{\mathrm{s}}}{R_{\mathrm{p}}}\) = n2
  • The Wheatstone bridge principle is \(\frac{P}{Q}=\frac{R}{S}\)
  • V = E – lr, where V is the terminal potential difference, E is emf and r is the internal resistance of the cell.
  • The internal resistance of a cell is r = \(\frac{(E-V) R}{V}=\frac{\left(L_{1}-L_{2}\right) R}{L_{2}}\)

Question 1.
A cell of emf ‘E’ and internal resistance ‘r’ is connected across a variable load resistor R. Draw the plots of the terminal voltage V versus (i) R and (ii) the current l.
It is found that when R = 4 Ω the current is 1 A and when R is increased to 9 Ω, the current reduces to 0.5 A. Find the values of the emf E and internal resistance r. (CBSE Delhi 2015)
Answer:
The plots are as shown
Class 12 Physics Important Questions Chapter 3 Current Electricity 44
Here l1 = 1.0 A, R1 =4 ohm, l2 = 0.5 A, R2 =9 ohm
Using the equation l = \(\frac{E}{(R+r)}\) Or E = l(R + r)

we have
1.0 × (4 + r) = 0.5 × (9 + r)

Solving the above equation for r we have r = 1 ohm
Also E = 0.5 (9 + 1) = 5 V

Question 2.
A wire of resistance R, length l and area of cross-section A is cut into two parts, having their lengths in the ratio 1:2. The shorter wire is now stretched till its length becomes equal to that of the longer wire. If they are now connected in parallel, find the net resistance of the combination. (CBSE Al 2019)
Answer:
Since the wires are cut in the ratio of 1:2 therefore,
Resistance of the shorter wire R1 = \(\frac{R}{3}\) and

Resistance of the longer wire R2 = \(\frac{2R}{3}\)

Since the shorter wire is stretched to make it equal to the longer wire therefore, it is stretched by n = 2 times its length. Hence New resistance of the shorter wire
Class 12 Physics Important Questions Chapter 3 Current Electricity 45
Question 3.
In the figure, a long uniform potentiometer wire AB is having a constant potential gradient along its length. The null points for the two primary cells of EMFs ε1 and ε2 connected in the manner shown are obtained at a distance of 120 cm and 300 cm from the end A. Find (i) ε12 and (ii) position of null point for the cell ε1. How is the sensitivity of a potentiometer increased? (CBSE Delhi 2012)
Class 12 Physics Important Questions Chapter 3 Current Electricity 46
Answer:
From the diagram we have
\(\frac{\varepsilon_{1}-\varepsilon_{2}}{\varepsilon_{1}+\varepsilon_{2}}=\frac{120}{300}=\frac{2}{5}\)
Or
1 – 5ε2 = 2ε1 + 2ε2

Solving we have
\(\frac{\varepsilon_{1}}{\varepsilon_{2}}=\frac{7}{3}\) ….(1)

Also let L be the balancing length for cell of emf ε1, then
\(\frac{\varepsilon_{1}}{\varepsilon_{1}+\varepsilon_{2}}=\frac{L}{300}\)

Using equation (1) we have
\(\frac{\varepsilon_{1}}{\varepsilon_{1}+\frac{3}{7} \varepsilon_{1}}=\frac{L}{300}\)

Solving for L we have L = 210 cm
The sensitivity of a potentiometer can be increased by increasing the length of the potentiometer wire.

Question 4.
The network PQRS, shown in the circuit diagram, has batteries of 4 V and 5 V and negligible internal resistance. A milli- ammeter of 20 Ω resistance is connected between P and R. Calculate the reading in the milliammeter. (CBSE AI 2012C)
Class 12 Physics Important Questions Chapter 3 Current Electricity 47
Answer:
Using Kirchhoff’s junction rule to distribute current we have
Class 12 Physics Important Questions Chapter 3 Current Electricity 48
Consider the loop SRPS, by Kirchhoff’s loop rule we have
200 l2 + 20 (l1 + l2 ) – 5 = 0 …(1)
Or
220 l2 + 20 l1 = 5 …(2)

Consider the loop PRQP, by Kirchhoff’s loop rule we have
– 60 l1 + 4 – 20 (l1 + l2) = 0 …(3)
80 l1 + 20 l2 =4 …(4)

Multiplying equation (2) by (4) we have
880 l2 + 80 l1 = 20 …(5)

Subtracting equation (4) from equation (5)
we have
860 l2 = 16 or l2 = 4/215 A

Substituting in equation (4) we have
l1 = \(\frac{39}{860}\)A

Therefore reading of the milliammeter is
l1+ l2 = \(\frac{4}{215}+\frac{39}{860}\) = 0.063 A = 63 mA

Question 5.
A set of ‘n’ identical resistors, each of resistance ‘R’ when connected in series have an effective resistance ‘X’. When they are connected in parallel, their effective resistance becomes ‘Y’. Find out the product of X and Y. (CBSEAI2019) Answer:
In series
Rs = R1 + R2 + R3 + ……
Rs = X = R + R + R + …. upto n
X=nR

In Parallel
Class 12 Physics Important Questions Chapter 3 Current Electricity 49

Question 6.
In the following circuit, a metre bridge is shown in its balanced state. The metre bridge wire has a resistance of 1 ohm per centimetre. Calculate the value of the unknown resistance X and the current drawn from the battery of negligible internal resistance.
Class 12 Physics Important Questions Chapter 3 Current Electricity 50
Answer:
Using the Wheatstone bridge principle we have
\(\frac{40}{60}=\frac{X}{3}\)
or X = 2 Ω

Now total resistance of the combination is
R = \(\frac{5 \times 100}{5+100}=\frac{500}{105}\) = 4.76 Ω

Current drawn is
l = V/R = 6/4.76 = 1.26 A

Question 7.
Calculate the electrical conductivity of the material of a conductor of length 3 m, area of cross-section 0.02 mm2 having a resistance of 2 ohms.
Answer:
Given L = 3 m,
A = 0.02 mm2 = 0.02 × 10-6 m2
R = 2 ohm.

Using the equation
R = \(\frac{ρL}{A}\)
Or
ρ = \(\frac{RA}{L}\)

σ = \(\frac{L}{AR}\) = \(\frac{3}{0.02 \times 10^{-6} \times 2}\) = 7.5 × 107 Sm-1

Question 8.
A potential difference of 2 volts is applied between points A and B has shown in the network drawn in the figure. Calculate (i) equivalent resistance of the network across the points A and B and (ii) the magnitudes of currents in the arms AFCEB and AFDEB.
Class 12 Physics Important Questions Chapter 3 Current Electricity 51
Answer:
The circuit can be redrawn as shown below.
Class 12 Physics Important Questions Chapter 3 Current Electricity 52
As seen the circuit is a balanced Wheatstone bridge; therefore the resistance in the arm CD is superfluous.
(i) Resistance of arm FCE = 2 + 2 = 4 Ω
Resistance of arm FDE = 2 + 2 = 4 Ω
Hence net resistance of the circuit between A and B is
R = \(\frac{4 \times 4}{4+4}=\frac{16}{8}\) = 2 Ω

(ii) current in the arm AFCEB
l = V/R = 2/4 = 0.5 A

Current in the arm AFDEB
l = V/R = 2/4 = 0.5 A

Question 9.
A cell of emf E and internal resistance ‘r’ gives a current of 0.8 A with an external resistor of 24 ohms and a current of 0.5 A with an external resistor of 40 ohms.
Calculate
(i) emf E and
(ii) internal resistance ‘r’ of the cell.
Answer:
Given l1 = 0.8 A, R1 = 24 ohm l2 = 0.5 A, R2 = 40 ohm
Using the equation
E = l(R + r) we have
0.8 × (24 + r) = 0.5 × (40 + r)

Solving for r we have r = 2.67 ohm
Also E = 0.5( 40 + 2.67) = 21.3 V

Question 10.
In the circuit diagram of the metre bridge given below, the balance point is found to be at 40 cm from A. The resistance of X is unknown and Y is 10 ohms.
(i) Calculate the value of X;
(ii) if the positions of X and Y are interchanged in the bridge, find the position of the new balance point from A; and
(iii) if the galvanometer and the cell are interchanged at the balance point, would the galvanometer show any current.
Class 12 Physics Important Questions Chapter 3 Current Electricity 53
Answer:
(i) Using the Wheatstone bridge principle we have
\(\frac{40}{60}=\frac{X}{10}\)
Or
X = 6.67 Ω

(ii) If X and Y are interchanged then
\(\frac{L}{(100-L)}=\frac{10}{6.67}\) solving for L we have
L = 59.9cm

(iii) The ga(vanometer will not show any current.

Question 11.
The length of a potentiometer wire is 600 cm and it carries a current of 40 mA. For a cell of emf 2.0 V and internal resistance 10 ohms, the null point is found to be at 500 cm. If a voltmeter is connected across the cell, the balancing length is decreased by 10 cm. Find (i) the resistance of the whole wire, (ii) reading of the voltmeter and (iii) resistance of the voltmeter.
Answer:
Here total length of potentiometer wire L = 600 cm, current flowing
l = 40 mA = 0.04 A,
Emf of cell E = 2 V,

Internal resistance of cell r = 10 Ω, balancing length for cell l = 500 cm
(i) Since ε = kl
k = \(\frac{\varepsilon}{l}=\frac{2}{500}\) , V = kl

∴ V = \(\frac{2}{500}\) × 600 = 2.4 V

Therefore resistance of the potentiometer wire =\(\frac{V}{l}=\frac{2.4}{0.04}\) = 60 Ω.

(ii) With voltmeter connected across the cell, balancing Length
L’ = l – 10 = 500 – 10 = 490cm

Therefore, potential difference, i.e. reading of voltmeter,
= \(\frac{L^{\prime}}{L} \times V=\frac{490}{600}\) × 2.4 = 1.96 V

(iii) Let resistance of the voltmeter be R,
R = \(\frac{V}{l}=\frac{1.96}{0.04}\) = 49 Ω
R = 49 ohm

Question 12.
Find the value of the unknown resistance X in the following circuit, if no current flows through the section AO. Also, calculate the current drawn by the circuit from the battery of emf 6 V and negligible internal resistance.
Class 12 Physics Important Questions Chapter 3 Current Electricity 54
Answer:
If no current flows through the section AO, the given circuit is an example of a balanced Wheatstone bridge. The circuit can be redrawn as
Class 12 Physics Important Questions Chapter 3 Current Electricity 55
Then \(\frac{2}{4}=\frac{3}{X}\)
Or
X = \(\frac{3 \times 4}{2}\) = 6 Ω

Now 2 Ω and 4 Ω are in series and 3 Ω and 6 Ω are also in series; so the circuit becomes
Class 12 Physics Important Questions Chapter 3 Current Electricity 56
Hence total resistance of the circuit
R = 2.4 + \(\left(\frac{9 \times 6}{15}\right)\) = 6 Ω

Hence current drawn from the battery
l = V/R = 6/6 = 1 A

Question 13.
In the given circuit, calculate the value of current in a 4.5-ohm resistor and indicate its direction. Also, calculate the potential difference across each cell.
Class 12 Physics Important Questions Chapter 3 Current Electricity 57
Answer:
The effective resistance of 3 ohms and 6-ohm resistors in parallel is
R = \(\frac{3 \times 6}{3+6}\) =2Q

Hence the resistance of the entire circuit
R = 2 + 4.5 + 0.5 + 1 = 8 ohm

Effective emf of the circuit E = 8 – 4 = 4 V.

Therefore current through the circuit and hence through the 4.5-ohm resistor is
l = E/R = 4/8 = 0.5 A.

The direction of the current is from cell E2 towards cell E1.

The potential difference across 8 V battery
V = E – lr = 8 – 0.5 × 1 = 7.5 V

The potential difference across 4 V battery
V = E + lr = 4 + o.5 × 0.5 = 4.25 V

Question 14.
Potentiometer wire PQ of 1-metre length is connected to a standard cell E1. Another cell, E2 of emf 1.02 V, is connected as shown In the circuit diagram with a resistance ‘r’ and a switch, S. with the switch open, the null position is obtained at a distance of 51 cm from P.
Calculate (i) the potential gradient of the potentiometer wire and
(ii) the emf of the cell E1.
(iii) When switch S is closed, will the null point move towards P or towards Q? Give a reason for your answer.
Class 12 Physics Important Questions Chapter 3 Current Electricity 58
Answer:
Here E2 = 1.02V and with switch open L = 51 cm

(i) Potential gradient k = E/L
= 1.02 /51 = 0.02 V cm-1

(ii) As total length of potentiometer wire L = 1 m = 100 cm
Therefore E1 = kL = 0.02 × 100 = 2 V

(iii) When switch S is closed, the null point will remain unaffected because cell E2 is even now in an open circuit and no current is being drawn from it.

Question 15.
Three identical resistors when connected in series to a dc source dissipate a power of X watt. If these resistors are connected in parallel to the same dc source, what will be the power dissipation in this case?
Answer:
Given Ps = X, Rs = 3R, Rp = R/3

Power in series Ps = \(\frac{V^{2}}{R_{s}}\) or X = \(\frac{V^{2}}{3 R}\) or 3X = \(\frac{V^{2}}{R}\)

When resistors are connected In parallel, we have
Pp = \(\frac{V^{2}}{R_{p}}=\frac{V^{2}}{R / 3}=\frac{3 V^{2}}{R}\) = 3 × 3X = 9X

Question 16.
A heater coil is rated 100W, 200V. It is cut into two Identical parts. Both parts are connected In parallel, to the same source of 200 V. Calculate the energy liberated per second in the new combination.
Answer:
The resistance of the coil
R = \(\frac{V^{2}}{P}=\frac{(200)^{2}}{100}\) = 400 Ω

When the coil is cut into two equal halves, the resistance of each half becomes 200 ohms.

When these two parts are connected in parallel, the resultant resistance is
Rp = \(\frac{200 \times 200}{200+200}\) = 100 Ω

Now energy Liberated
H = \(\frac{V^{2}}{R_{\mathrm{p}}}=\frac{(200)^{2}}{100}\) = 400 Ω

Question 17.
AB is a 1 m long uniform wire of 10 Ω resistance. The other data are as shown in the circuit diagram given in the figure below. Calculate (i) potential gradient along with AB and (ii) length AO of the wire, when the galvanometer shows no deflection.
Class 12 Physics Important Questions Chapter 3 Current Electricity 59
Answer:
Emf of battery E1 = 2 V.
Resistance of potentiometer R = 10 Ω,
Resistance joined in series R1 = 15 Ω and
Length of potentiometer wire L = 1 m = 100 cm
(i) Potential gradient
k = \(\frac{E_{1} R}{\left(R+R_{1}\right) L}=\frac{2 \times 10}{(10+15) \times 100}\) = 0.008 Vcm-1

(ii) Current through 0.3 Ω resistance due
to cell E1, l = \(\frac{1.5}{1.2+0.3}\) = 1 A

Potential difference across 0.3 Ω resistance = l × 0.3 = l × 0.3 = 0.3 V

∴ Length AO = \(\frac{\text { Potential difference }}{\text { Potential gradient }}\) = 37.5 cm

Question 18.
In a potentiometer, a standard cell of emf 5V and of negligible resistance maintains a steady current through the potentiometer wire of length 5 m. Two primary cells of EMFs E1 and E2 are joined in series with (a) the same polarity and (b) opposite polarity. The combination Is connected through a galvanometer and a jockey to the potentiometer. The balancing lengths In the two cases are found to be 350 cm and 50 cm, respectively.
(i) Draw the necessary circuit diagram.
(ii) Find the value of the EMFs of the two cells.
Answer:
(i) The circuit diagram is as shown below.
Class 12 Physics Important Questions Chapter 3 Current Electricity 60
(ii) With cells E1 and E2 joined in series with the same polarity, the resultant emf
E = E1 + E2 and

Balancing Length L = 350 cm.
With celLs joined in series with opposite polarity, the resuLtant emf
E’ = E1 – E2 and

Balancing Length L = 50 cm.

Moreover, the potentiaL gradient

k = \(\frac{V}{L}=\frac{5 \mathrm{~V}}{5 \mathrm{~m}}=\frac{5 \mathrm{~V}}{500 \mathrm{~cm}}\) = 0.01 Vcm-1

Therefore
E1 + E2 = kL = 0.01 × 350 = 3.5 V and
E1 – E2 = kL = 0.01 × 50 = 0.5 V

Solving for the two EMFs we get E1 = 2V and E2 = 1.5 V

Question 19.
Using Kirchhoff’s rules, calculate the current through the 40 Q and 200 resistors in the following circuit:
Class 12 Physics Important Questions Chapter 3 Current Electricity 61
Or
What is the end error in a metre bridge? How is it overcome? The resistances in the two arms of the metre bridge are R = 5 Ω and S respectively. When the resistance S is shunted with equal resistance, the new balance length found to be 1.5 L1, where L1 is the initial balancing length. Calculate the value of S. (CBSE Delhi 2019)
Class 12 Physics Important Questions Chapter 3 Current Electricity 62
Answer:
The distribution of current is as shown
Class 12 Physics Important Questions Chapter 3 Current Electricity 63
In loop ABCDA
+ 80 – 20 l2 + 40 l1 = 0
4 = l2 – 2 l1

In loop DCFED
– 40 l1 – 10(l1 + l2) + 40 = 0
-50 l1 – 10 l2 + 40 = 0
5 l1 + l2 = 4

Solving these two equations
l1 = 0 A and
l2 = 4 A
Or
The end error, in a meter bridge, is the error arising due to
(i) Ends of the wire not coinciding with the 0 cm/100 cm mark on the meter scale.
(ii) Presence of contact resistance at the joints of the meter bridge wire with the metallic strips.

It can be reduced/overcome by finding balance length with two interchanged positions of R and S and taking the average value of ‘S’ from these two readings.

For a metre bridge, we have
\(\frac{R}{S}=\frac{L}{100-L}\)

For the two given conditions, we have
Class 12 Physics Important Questions Chapter 3 Current Electricity 64
Putting this value in equation (1) we have S = 10 Ω.

Question 20.
A 10 m long wire of uniform cross-section and 20-ohm resistance is used in a potentiometer. The wire is connected in series with a battery of 5 V along with an external resistance of 480 ohms. If an unknown emf E is balanced at 6.0 m length of the wire, calculate:
(i) the potential gradient of the potentiometer wire
(ii) the value of unknown emf E.
Answer:
Total resistance of the circuit
R = 20 + 480 = 500 ohm

Therefore current through the potentiometer
l = \(\frac{V}{R}=\frac{5}{500}\) = 0.01 A

Now potential drop across the potentiometer wire of 20 ohm = 20 × 0.01 = 0.2 V

(i) Potential gradient
\(\frac{V}{L}=\frac{0.2}{10}\) = 0.02 Vm-1

(ii) Unknown emf = balancing length × potential gradient = 6 × 0.02 = 0.12 V

Question 21.
In a potentiometer arrangement, a cell of emf 1.20 volt gives a balance point at 30 cm length of the wire. This cell is now replaced by another cell of unknown emf. If the ratio of the EMFs of the two cells is 1.5, calculate the difference in the balancing length of the potentiometer wire in the two cases.
Answer:
Given E1 = 1.20 V, L1 = 30 cm, E2 = ?,
E1/E2 = 1.5, L1 – L2 = ?

Now \(\frac{E_{1}}{E_{2}}=\frac{L_{1}}{L_{2}}\) or 1.5 = \(\frac{30}{L_{2}}\) or L2 = 20 cm

Therefore L1 – L2 = 30 – 20 = 10 cm

Question 22.
A uniform wire of resistance 12 Ω is cut into three pieces so that the ratio of the resistances R1: R2: R3 = 1: 2: 3 and the three pieces are connected to form a triangle across which a cell of emf 8 V and internal resistance 1 Ω is connected as shown. Calculate the current through each part of the circuit. (CBSE A! 2013C)
Class 12 Physics Important Questions Chapter 3 Current Electricity 65
Answer:
Value of the three resistances are
R1 = \(\frac{1}{6}\) × 12 = 2 Ω,
R2 = \(\frac{2}{6}\) × 12 = 4 Ω
and R3 = \(\frac{3}{6}\) × 12 = 6 Ω

Now R1 and R2 are connected in series, therefore we have
R = R1 + R2 = 2 + 4 = 6 Ω

Now R and R3 are connected in parallel, therefore net resistance
Rp = \(\frac{R R_{3}}{R+R_{3}}=\frac{6 \times 6}{6+6}\) = 3 Ω

Now Rp and the internal resistance of the cell are connected in series, therefore net resistance of the circuit is
RN = Rp + 1 = 3 + 1 = 4 Ω

Hence current in the circuit is
l = V/RN = 8/4 = 2 A

This is equally divided amongst R1, R2 and R3. Therefore current through all the three resistors is 1 A.

Question 23.
A battery of emf E and internal resistance r when connected across an external resistance of 12 ohms produces a current of 0.5 A. When connected across a resistance of 25 ohms it produces a current of 0.25 A. Determine the (i) emf and (ii) internal resistance of the cell. (CBSEAI2013C)
Answer:
Here l1 = 0.5 A, R1 =12 ohm, l2 = 0.25 A, R22 = 25 ohm

Using the equation l = \(\frac{E}{(R+r)}\) or E = l(R + r)

we have
0. 5 × (12 + 1) = 0.25 × (25 + r)

Solving the above equation for r we have
r = 1 ohm

Also E = 0.5 (12 + 1) = 6.5 V

Question 24.
The resistance of the platinum wire of a platinum resistance thermometer at the ice point is 5 Ω and at steam, the point is 5.23 Ω. When the thermometer is inserted into a hot bath, the resistance of the platinum wire is 5.795 Ω. Calculate the temperature of the bath. (NCERT)
Answer:
Ro = 5 Ω, R100 = 5.23 Ω, Rt = 5.795 Ω
Class 12 Physics Important Questions Chapter 3 Current Electricity 66

Question 25.
A battery of 10 V and negligible internal resistance is connected across the diagonally opposite corners of a cubical network consisting of 12 resistors each of resistance 1 Ω. Determine the equivalent resistance of the network and the current along each edge of the cube. (NCERT)
Class 12 Physics Important Questions Chapter 3 Current Electricity 67
Answer:
The distribution of current is as shown.

Next take a closed-loop, say, ABCC’EA and apply Kirchhoff’s second rule:
lR – (1/2)lR – lR + E = 0
where R is the resistance of each edge and E is the emf of the battery.
Thus E = 5lR/2

Now if R<sub>eq</sub> is the equivalent resistance, then
R = E/31 = 5lR/6l = 5/6 R

Now current in the circuit is 3l × 5/6 R = 10 or l = 4 A.

Hence the other currents can also be found.

Question 26.
Determine the current in each branch of the network shown. (NCERT)
Class 12 Physics Important Questions Chapter 3 Current Electricity 68
Answer:
Each branch of the network is assigned an unknown current to be determined by the application of Kirchhoff’s rules. To reduce the number of unknowns at the outset, the first rule of Kirchhoff is used at every junction to assign the unknown current in each branch. We then have three unknowns l1, l2 and l3 which can be found by applying the second rule of Kirchhoff to three different closed loops.

Kirchhoff’s second rule for the closed loop ADCA gives,
10 – 4(l1 – l2) + 2(l2 + l3 – l1) – l1 = 0 …(1)
that is, 7 l1 – 6l2 – 2l3 = 10

For the closed loop ABCA, we get
10 – 4l2 – 2 (l2 + l3) – l1 = 0 …(2)

That is, l1 + 6l2 + 2l3 = 10

For the closed loop BCDEB, we get
5 – 2(l2 + l3) – 2(l2 + l3– l1) = 0 ….(3)

That is 2 l1 – 4l2 – 4l3 = – 5

Equations (1), (2) and (3) are three simultaneous equations in three unknowns. These can be solved by the usual method to give
l1 = 2.5 A, l2 = 5/8 A, l3 = 15/8 A

The currents in the various branches of the network are
AB = 5/8 A, CA = 5/2 A, DEB = 15/8 A, AD = 15/8 A, CD = 0 A, BC = 5/2 A

Question 27.
In a metre bridge, the null point is found at a distance of 33.7 cm from A. If now resistance of 12 Ω is connected in parallel with 5, the null point occurs at 51.9 cm. Determine the values of R and S. (NCERT)
Answer:
From the first balance point we get
\(\frac{R}{S}=\frac{33.7}{66.3}\)

After S is connected in parallel with a resistance of 12 Ω, the resistance across the gap changes from S to Seq where and hence the new balance condition now gives
\(\frac{R}{S_{e q}}=\frac{51.9}{48.1}=\frac{R(S+12)}{12 S}\)

Substituting for R/S we have
\(\frac{51.9}{48.1}=\frac{(5+12)}{12} \times \frac{33.7}{66.3}\)
which gives S = 13.5 Ω and R = 6.86 Ω

Question 28.
In a potentiometer arrangement, a cell of emf 1.25 V gives a balance point at 35.0 cm length of the wire. If the cell is replaced by another cell and the balance point shifts to 63.0 cm, what is the emf of the second cell? (NCERT)
Answer:
Given ε1 = 1.25 V, L1 = 35.0 cm and L2 = 63.0 cm, ε2 = ?
ε2 = \(\frac{L_{2} \times \varepsilon_{1}}{L_{1}}=\frac{1.25 \times 63.0}{35.0}\) = 2.25 V

Question 29.
The figure below shows a potentiometer circuit for the comparison of two resistances. The balance point with a standard resistor R = 10.0 Ω is found to be 58.3 cm, while that with the unknown resistance X is 68.5 cm. Determine the value of X. What might you do if you failed to find a balance point with the given cell of emf ε? (NCERT)
Class 12 Physics Important Questions Chapter 3 Current Electricity 69
Answer:
Given R= 10.0 Ω, L1 = 58.3 cm, L2 = 68.5 cm, X = 1

Let k be the potential gradient along the wire AB, then
\(\frac{X}{R}=\frac{k L_{2}}{k L_{1}}\)
or
X = \(\frac{R \times L_{2}}{L_{1}}=\frac{10 \times 68.5}{58.3}\)
or
X= 11.75 Ω

If we fail to find a balance point with the given cell of emf e, it means the potential drop across R or X is greater than the potential drop across the potentiometer wire AB. Therefore to obtain the balance point on the wire, reduce the current in the circuit by putting a resistor in series with the circuit.

Question 30.
The figure below shows a 2.0 V potentiometer used for the determination of the internal resistance of a 1.5 V cell. The balance point of the cell in the open circuit is 76.3 cm. When a resistor of 9.5 Q is used in the external circuit of the cell, the balance point shifts to 64.8 cm length of the potentiometer wire. Determine the internal resistance of the cell. (NCERT)
Class 12 Physics Important Questions Chapter 3 Current Electricity 70
Answer:
Given 4 = 76.3 cm, ε = 1.5 V, R = 9.5 Ω, L2 = 64.8 cm
Internal resistance of a cell is given by the expression
r = \(\frac{\left(L_{1}-L_{2}\right) R}{L_{2}}\)
or
r = \(\frac{(76.3-64.8) \times 9.5}{64.8}\)
= 1.7 Ω